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Copper Nanoparticles Synthesized by Chemical Reduction with Medical Applications. [PDF]

Int J Mol Sci
Pricop A, Negrea A, Pascu B, Nemeş NS, Ciopec M, Negrea P, Ianăşi C, Svera P, Muntean D, Ivan A, Cristea IM.   +10 more
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Sulfurized metal borohydrides

Dalton Transactions, 2016
The reactions between metal borohydrides and elemental sulfur are investigatedin situduring thermal treatment and are found to be highly exothermic (up to 700 J g−1).
Paskevicius, Mark, Richter, B., Polanski, M., Thompson, S., Jensen, T.   +4 more
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Complex of aluminum borohydride with calcium borohydride

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1975
1. The reaction of Al(BH4)3 with the unsolvated Ca(BH4)2 gave the complex Ca(BH4)2·Al(BH4)3, which is stable at room temperature; its density and IR spectrum are given. 2. Ca(BH4)2·Al(BH4)3 decomposes completely into the component borohydrides when heated in vacuo or when treated with donor solvents.
L. V. Titov, E. R. Eremin
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Calcium Borohydride

Synthetic Communications, 1995
Calcium borohydride reduces both aliphatic and aromatic esters to alcohols completely in the presence of alkene catalysts. The intermediate borates formed during the reduction of aromatic esters are converted to aldehydes with aqueous NaOC1 in good yields.
S. Narasimhan, K. Ganeshwar Prasad, S. Madhavan   +2 more
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Borohydrides

ChemInform, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
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The reaction of aluminum borohydride with tetraethylammonium borohydride

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1970
1. A complex borohydridoaluminate, [(C2H5)4N][Al(BH4)4] has been prepared by the reaction of aluminium borohydride with tetraethylammonium borohydride at room temperature. Its IR spectrum and x-ray photograph have been investigated. 2. The complex decomposes with the evolution of H2, C2H6, (C2H5)3N, metallic aluminum, and boron over the ...
L. V. Titov, E. R. Eremin, L. A. Gavrilova, V. Ya. Rosolovskii   +3 more
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Tetrabutylammonium borohydride and its complex with aluminum borohydride

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1971
1. Tetrabutylammonium borohydride was obtained by the exchange reaction of tetrabutylammonium bromide with excess sodium borohydride in ether isopropyl alcohol or benzene medium. 2. Tetrabutylammonium borohydride aluminate, [(C4H9)4N] [Al(BH4)4], was synthesized by the reaction of the tetrabutylammonium and aluminum borohydrides.
L. V. Titov, L. A. Gavrilova, E. R. Eremin, S. S. Mishchenchuk, V. Ya. Rosolovskii   +4 more
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Carbene-Stabilized Beryllium Borohydride

Journal of the American Chemical Society, 2012
The reaction of N-heterocyclic carbene, L:, with BeCl(2) quantitatively yields L:BeCl(2)1 (L: = :C{N(2,6-Pr(i)(2)C(6)H(3))CH}(2)). The carbene-stabilized beryllium borohydride monomer L:Be(BH(4))(2)2 is prepared by the reaction of 1 with LiBH(4). Compound 3, prepared by the reaction of 2 with Na(2)[Fe(CO)(4)]·dioxane, represents an unusual "dual ...
Robert J, Gilliard, Mariham Y, Abraham, Yuzhong, Wang, Pingrong, Wei, Yaoming, Xie, Brandon, Quillian, Henry F, Schaefer, Paul V R, Schleyer, Gregory H, Robinson   +8 more
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Radical reactions of borohydrides

Org. Biomol. Chem., 2014
This review article focuses on state-of-the-art borohydride based radical reactions, also covering earlier work, kinetics and some DFT calculations with respect to the hydrogen transfer mechanism.
Takuji, Kawamoto, Ilhyong, Ryu
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Borohydride as Magnetic Superexchange Pathway in Late Lanthanide Borohydrides

European Journal of Inorganic Chemistry, 2019
The magnetic characteristics of a series of borohydride‐based systems, including binary α‐/β‐Ln(BH4)3 phases (Ln = Gd, Tb, Dy, Ho, Er, and Tm) with direct Ln–HBH–Ln bridges and selected mixed‐metal systems, LiYb(BH4)4, NaYb(BH4)4, KHo(BH4)4, RbTm(BH4)4, with isolated Ln3+ ions embedded in [Ln(BH4)4]– anions are described for the first time using SQUID ...
Wojciech Wegner, Jan van Leusen, Jacek Majewski, Wojciech Grochala, Paul Kögerler   +4 more
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