Solid-State Chemistry with Nonmetal Nitrides [PDF]
, 1993 Among the nonmetal nitrides, the polymeric binary compounds BN and Si3N4are of particular interest for the development of materials for high-performance applications. The outstanding features of both substances are their thermal, mechanical, and chemical
Schnick, Wolfgang
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Aggregation-Induced Fluorescence of Carbazole and o-Carborane Based Organic Fluorophore
Frontiers in Chemistry, 2019 Carbazole based fluorophores 9-butyl-3,6-bis-(phenylethynyl)-9H-carbazole (1) and 9-butyl-3,6-bis-(2-phenyl-o-carborane)-9H-carbazole (2) were synthesized via Sonogashira type cross-coupling reaction and followed by insertion with decaborane.
Jiemin Jiao +7 more
doaj +1 more source
Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes
He huaxue yu fangshe huaxue, 2023 Borane is a class of boron compounds, including active small borane molecules and relative stable polyhedral borane compounds, and has widely applied in energy storage, material science, and pharmaceutical medicine, especially as promising boron carriers
JING Yi +4 more
doaj +1 more source
Fast and long-lasting Fe(Ⅲ) reduction by boron toward green and accelerated Fenton chemistry.
Angewandte Chemie, 2020 Generation of hydroxyl radicals in the Fenton system (Fe(II)/H 2 O 2 ) is seriously limited by the sluggish kinetics of Fe(III) reduction and fast Fe(III) precipitation.
Peng Zhou +6 more
semanticscholar +1 more source
Boron isotope ratio (delta B-11) measurements in water framework directive monitoring programs: comparison between double focusing sector field ICP and thermal ionization mass spectrometry [PDF]
, 2010 International audienceThe aim of our research was to compare delta B-11 measurements performed with thermal ionization mass spectrometry (TIMS) and sector field-inductively coupled plasma-mass spectrometry (SF-ICP-MS) and evaluate the feasibility of ...
Aggarwal +44 more
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Novel B(Ar')2(Ar'') hetero-tri(aryl)boranes: a systematic study of Lewis acidity [PDF]
, 2016 A series of homo- and hetero-tri(aryl)boranes incorporating pentafluorophenyl, 3,5-bis(trifluoromethyl)phenyl, and pentachlorophenyl groups, four of which are novel species, have been studied as the acidic component of frustrated Lewis pairs for the ...
Ashley +61 more
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Angewandte Chemie, 2020 Although hexagonal boron nitride (h-BN) has recently been identified as a highly efficient catalyst for the oxidative dehydrogenation of propane (ODHP) reaction, the reaction mechanisms, especially regarding radical chemistry of this system, remain ...
Xuanyu Zhang +14 more
semanticscholar +1 more source
Chemical Bonding in the Boron Buckyball [PDF]
, 2008 A symmetry analysis of the valence shell in the boron buckyball B80, shows a perfect match with the symmetry of the valence shell in C60 .The cap atoms participate in the bonding by 30 orbitals which transform as the sigma bonds along the 6-6 edges.
Ceulemans, Arnout +3 more
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Macropolyhedral boron-containing cluster chemistry: two-electron variations in intercluster bonding intimacy. Contrasting structures of 19-vertex [(eta(5)-C5Me5)HIrB18H19(PHPh2)] and [(eta(5) -C5Me5)IrB18H18(PH2Ph)] [PDF]
, 2004 Fused double-cluster [(5-C5Me5)IrB18H18(PH2Ph)]8, from syn-[(5-C5Me5)IrB18H20] 1 and PH2Ph, retains the three-atoms-in-common cluster fusion intimacy of 1, in contrast to [(5-C5Me5)HIrB18H19(PHPh2)]6, from PHPh2 with 1, which exhibits an opening to a ...
Jelínek, T. +5 more
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Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation [PDF]
, 2010 Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H_2 in less than 60 s at 25 °C.
Han, Won-Sik +9 more
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