Results 41 to 50 of about 37,334 (332)

Rapid iododeboronation with and without gold catalysis: application to radiolabelling of arenes [PDF]

open access: yes, 2017
Radiopharmaceuticals incorporating radioactive iodine in combination with SPECT imaging play a key role in nuclear medicine, with applications in drug development and disease diagnosis.
Fletcher, Conor   +5 more
core   +2 more sources

Asymmetric Synthesis of 1-Heteroaryl-1-arylalkyl Tertiary Alcohols and 1-Pyridyl-1-arylethanes by Lithiation-Borylation Methodology [PDF]

open access: yes, 2013
The synthesis of highly enantioenriched alpha-heterocyclic tertiary alcohols has been achieved via lithiation-borylation of a configurationally stable lithiated carbamate and heterocyclic pinacol boronic esters followed by oxidation. Protodeboronation of
Aggarwal V. K.   +41 more
core   +3 more sources

Boronic Acid-Based Electrochemical Sensors for Detection of Biomolecules

open access: yesInternational Journal of Electrochemical Science, 2013
Boronic acids can form reversible covalent bonds with 1, 2- or 1, 3-diols to generate five or six-membered cyclic complexes. Thus, boronic acid functionalized compounds and materials have attracted much attention in both chemistry and biology as the ...
Lin Liu, Ning Xia, Yun Xing, Dehua Deng
doaj   +1 more source

Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Five-, Six-, and Seven-Membered β-Substituted Cyclic Enones: Enantioselective Construction of All-Carbon Quaternary Stereocenters [PDF]

open access: yes, 2011
The first enantioselective Pd-catalyzed construction of all-carbon quaternary stereocenters via 1,4-addition of arylboronic acids to β-substituted cyclic enones is reported. Reaction of a wide range of arylboronic acids and cyclic enones using a catalyst
Gatti, Michele   +3 more
core   +2 more sources

Chemoselective Suzuki-Miyaura cross-coupling via kinetic transmetallation [PDF]

open access: yes, 2016
Chemoselective Suzuki-Miyaura cross-coupling generally requires a designed deactivation of one nucleophile towards transmetallation. Here we show that boronic acids can be chemoselectively reacted in the presence of ostensibly equivalently reactive ...
Fazakerley, Neal J.   +2 more
core   +1 more source

One-pot synthesis of four-coordinate boron(III) complexes by the ligand-promoted organic group migration between boronic acids

open access: yesScientific Reports, 2017
Multidisciplinary applications of four-coordinate boron(III) complexes make them very attractive and challenging research field in chemistry, biology and material sciences.
Venkata S. Sadu   +3 more
doaj   +1 more source

Synthesis of Solution-Phase Phosphoramidite and Phosphite Ligand Libraries and Their In Situ Screening in the Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids [PDF]

open access: yes, 2007
Herein, we report the automated parallel synthesis of solution-phase libraries of phosphoramidite ligands for the development of enantioselective catalysts.
Feringa, Ben L.,   +5 more
core   +1 more source

Organoboronic acids/esters as effective drug and prodrug candidates in cancer treatments: challenge and hope

open access: yesJournal of Enzyme Inhibition and Medicinal Chemistry, 2023
Boronic acids/esters have recently emerged in the field of medicinal and pharmaceutical research due to their exceptional oxophilicity, low toxicity, and unique structure. They are known as potent enzyme inhibitors, cancer therapy capture agents, and can
Mothana K. Al-Omari   +12 more
doaj   +1 more source

A perspective on using experiment and theory to identify design principles in dye-sensitized solar cells [PDF]

open access: yes, 2018
Dye-sensitized solar cells (DSCs) have been the subject of wide-ranging studies for many years because of their potential for large-scale manufacturing using roll-to-roll processing allied to their use of earth abundant raw materials.
Abuabara SG   +18 more
core   +4 more sources

Recent developments in the Suzuki-Miyaura reaction: 2010-2014 [PDF]

open access: yes, 2015
The Suzuki-Miyaura reaction (SMR), involving the coupling of an organoboron reagent and an organic halide or pseudo-halide in the presence of a palladium or nickel catalyst and a base, has arguably become one of most utilized tools for the construction ...
Maluenda, Irene, Navarro, Oscar
core   +2 more sources

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