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The Boroxine–Boronic Acid Equilibrium
The equilibrium between boroxines and boronic acids is a major component of their physicochemical properties, key to many of their applications, and a complicating factor in the analysis of their purity and stoichiometry. While the equilibrium is well-known and extensively applied, there is a dearth of information on the mechanism and kinetics of the ...
Chen Li +7 more
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This review highlights the role of self‐assembled monolayers (SAMs) in perovskite solar cells, covering molecular engineering, multifunctional interface regulation, machine learning (ML) accelerated discovery, advanced device architectures, and pathways toward scalable fabrication and commercialization for high‐efficiency and stable single‐junction and
Asmat Ullah, Ying Luo, Stefaan De Wolf
wiley +1 more source
Boronic Acids as Penicillinase Inhibitors [PDF]
β-lactamases are enzymes produced by bacteria resistant to antibiotics. A common feature on beta lactam antibiotics is the beta-lactam ring. β-lactamases hydrolyze the β-lactam ring leaving the antibiotic inoperative.
Barquero, Juan F.
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Citation: 'boronic acids' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.B00714 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms. Requests for commercial
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Application of Boronic Acids in Medicinal Chemistry (Inhibitors, Sensors)
It is well known boronic acids have its unique chemistry and related applications in organic synthesis. The boronic acid functionally group also plays very important roles in medicinal chemistry and chemical biology.
Ni, Nanting
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Boronic acids facilitate rapid oxime condensations at neutral pH [PDF]
We report here the discovery and development of boron-assisted oxime formation as a powerful connective reaction for chemical biology. Oximes proximal to boronic acids form in neutral aqueous buffer with rate constants of more than 104 M−1 s−1, the ...
Gillingham, Dennis +2 more
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The perspective presents an integrated view of neuromorphic technologies, from device physics to real‐time applicability, while highlighting the necessity of full‐stack co‐optimization. By outlining practical hardware‐level strategies to exploit device behavior and mitigate non‐idealities, it shows pathways for building efficient, scalable, and ...
Kapil Bhardwaj +8 more
wiley +1 more source
Fluorogenic affinity gels constructed from clickable boronic acids
Boronate affinity gel was prepared by immobilizing azide-functionalized boronic acid on alkyne-modified Sepharose. Different azide-functionalized boronic acids were synthesized from 2-, 3-, and 4-aminophenylboronic acids.
Lei Ye +3 more
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The binding constants (M−1), HeLa Cell Survival (%)** and PCC** values for the lead boronic acids (** Values shown are for HeLa cells incubated for 2 hrs. at 37°C with 80 nM concentration of the compounds).
Eric A. Tanifum (123168) +6 more
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Arylsulfonyl fluoride boronic acids: preparation and coupling reactivity [PDF]
We report the efficient and practical syntheses of ortho-, meta, and para-sulfonyl fluoride substituted benzene boronic acids. The syntheses of the para- and meta-isomers commence with the appropriate bromo-substituted benzenesulfonyl chlorides, and the ...
Lou, TS-B, Willis, Michael C
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