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(2,4,6-Trimethylphenyl)boronic acid–triphenylphosphine oxide (1/1)
In the crystal structure of the title compound, C9H13BO2·C18H15OP, there are O—H...O hydrogen bonds between the O atom of triphenylphosphine oxide and one hydroxy group of the boronic acid. Boronic acid molecules form inversion-related
Sorin Roşca +2 more
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Formose reaction controlled by boronic acid compounds
Formose reactions were carried out in the presence of low molecular weight and macromolecular boronic acid compounds, i.e., sodium phenylboronate (SPB) and a copolymer of sodium 4-vinylphenylboronate with sodium 4-styrenesulfonate (pVPB/NaSS ...
Toru Imai +2 more
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Structure–Reactivity Relationships in Boronic Acid–Diol Complexation
Boronic acids have found widespread use in the field of biomaterials, primarily through their ability to bind with biologically relevant 1,2- and 1,3-diols, including saccharides and peptidoglycans, or with polyols to prepare hydrogels with dynamic ...
William L. A. Brooks +2 more
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Boronic acids/esters have recently emerged in the field of medicinal and pharmaceutical research due to their exceptional oxophilicity, low toxicity, and unique structure. They are known as potent enzyme inhibitors, cancer therapy capture agents, and can
Mothana K. Al-Omari +12 more
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Self-healing boronic acid-based hydrogels for 3D co-cultures
Synthetic hydrogels have been widely adopted as well-defined matrices for three-dimensional (3D) cell culture, with increasing interest in systems that enable the co-culture of multiple cell types for probing both cell-matrix and cell-cell interactions ...
Megan E Smithmyer +5 more
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Boronic Acids as Lewis Acid Catalysts: Myth or Reality?
Boronic acid catalysis has emerged as a mild method for promoting a wide variety of reactions. It has been proposed that the mode of catalysis involves Lewis acid or covalent activation of hydroxyl groups by boron, but limited mechanistic evidence exists.
Shao-Fei Zhang +2 more
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Wisdom from nature: Plant-derived polyphenolic compounds can crosslink boronic acid functionalized polymers through formation of dynamic covalent bonds and function as both cross-linker and bioactive cargo.
Zhuojun Huang +5 more
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Recent development of boronic acid-based fluorescent sensors
As Lewis acids, boronic acids can bind with 1,2- or 1,3-diols in aqueous solution reversibly and covalently to form five or six cyclic esters, thus resulting in significant fluorescence changes.
Guiqian Fang +8 more
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Citation: 'boronic acids' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.B00714 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms. Requests for commercial
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The Boroxine–Boronic Acid Equilibrium
The equilibrium between boroxines and boronic acids is a major component of their physicochemical properties, key to many of their applications, and a complicating factor in the analysis of their purity and stoichiometry. While the equilibrium is well-known and extensively applied, there is a dearth of information on the mechanism and kinetics of the ...
Chen Li +7 more
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