Copper-Catalyzed Regioselective Ortho C-H Cyanation of Vinylarenes [PDF]
A copper-based catalytic technique for the regioselective ortho C-H cyanation of vinylarenes has been developed. This method provides an effective means for the selective functionalization of vinylarene derivatives.
Albrecht +50 more
core +1 more source
Mechanochemical borylation of aryldiazonium salts; merging light and ball milling
Merging of photo- and mechanochemical activation permitted studying the role of eosin Y in the borylation of aryldiazonium salts in a ball mill. Simultaneous neat grinding/irradiation of the reactants and the photocatalyst led to the formation of ...
José G. Hernández
doaj +1 more source
A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes [PDF]
Frustrated Lewis pairs are compounds containing both Lewis acidic and Lewis basic moieties, where the formation of an adduct is prevented by steric hindrance.
Chernichenko, K. +2 more
core +1 more source
Back to the Electrofuture: Named Reactions Powered by Electroorganic Syntheses
Bridging classical named reactions with modern electroorganic chemistry, this review presents how electrochemical strategies can revive and reinterpret historically significant transformations, highlighting their emerging potential as sustainable alternatives in contemporary organic synthesis.
Debajit Maiti +4 more
wiley +1 more source
Hydrogen Bond Directed ortho‐Selective C−H Borylation of Secondary Aromatic Amides [PDF]
Shao‐Tao Bai +2 more
openalex +1 more source
Iridium‐Catalyzed Site‐ and Enantioselective C(sp2)‐H Borylation of Benzhydryl Ethers: Enantioselectivity Amplification by Kinetic Resolution Relay [PDF]
Jing Ke +3 more
openalex +1 more source
Synthesis of fluorescent tetracyclic lactams by a “one pot” three steps palladium-catalyzed borylation, Suzuki coupling (BSC) and lactamization. DNA and polynucleotides binding studies [PDF]
Tetracyclic lactams (benzothieno[2,3-c]quinolones) were prepared by “one pot” three steps palladium-catalyzed borylation, Suzuki coupling (BSC) and lactamization, starting from ortho-haloanilines and alkyl 3-bromobenzo[b]thiophene-2-carboxylates.
Castanheira, Elisabete M. S. +4 more
core +1 more source
A strategy of C3/C4 and C5/C4 bis-C–H functionalization of furfural and 5-hydroxymethylfurfural is presented. This task has been accomplished by the initial iridium-catalyzed C–H borylation of furfural, equipped with an appropriate imine function ...
Alessia Mori +4 more
doaj +1 more source
Electroreductive Borylation of Unactivated (Hetero)Aryl Chlorides Without Light Using Cumulene Electrocatalysts [PDF]
Yihuan Lai +4 more
openalex +1 more source
Dearomative C2-borylation of indoles
The dearomative functionalization of indoles to C2-borylated indolenium compounds is achieved under mild conditions by leveraging the high Lewis acidity of bis(1-methyl- ortho -carobranyl)borane.
Ayesha Begum +2 more
openaire +2 more sources

