Results 241 to 250 of about 445,914 (314)

Modular Assembly of Dynamic Polymer Networks From Heteroaffinity Cross‐Links to Multivalent Proteins

open access: yesAngewandte Chemie, EarlyView.
This study develops a method to modularly assemble oligomeric binding proteins, like streptavidin, using heterobifunctional cross‐linkers that have both a strong‐ and a weak‐affinity binding moiety. These dynamic cross‐linkers enable the assembly of polymer networks with unique meta‐stable nonequilibrium topologies, and that exhibit chemically tunable ...
Tianyue Dai   +6 more
wiley   +2 more sources

Bis(silylene)‐Mediated N═N Bond Scission of Diazo Compounds

open access: yesAngewandte Chemie, EarlyView.
The carborane‐based bis(silylene) enables unprecedented N═N bond scission in diazodiarylmethanes. While xanthene‐ and aniline‐based scaffolds promote end‐on addition with partial N═N activation, the carborane‐based variant uniquely achieves complete N═N bond scission of Ar2C═N═N compounds, resulting in isolable disilicon nitride imino species.
Yun Xiong, Shenglai Yao, Matthias Driess
wiley   +2 more sources

Precision and Practicality: A Novel Cellulose Gum-Based Indirect Bonding Protocol for Orthodontic Bracket Placement. [PDF]

open access: yesCureus
Garlapati Y   +8 more
europepmc   +1 more source

Photocatalytic Cross‐Coupling of Phenols and Heteroaryl Halides With Machine Learning‐Guided Reaction Prediction

open access: yesAngewandte Chemie, EarlyView.
Photocatalytic cross‐coupling: A redox‐neutral photochemical method enables direct C(sp2)─C(sp2) bond formation between phenols and heteroaryl halides using an organic dye and base. Complementary radical generation allows efficient cross‐coupling in up to 91% yield. Mechanistic studies, DFT, HTE, and machine learning rationalize and predict reactivity,
Matthew C. Carson   +4 more
wiley   +2 more sources

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