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Bridged Polycyclic Compounds. VI. The Photoisomerization of Bicyclo [2,2,1]hepta-2,5-diene-2,3-dicarboxylic Acid to Quadricyclo [2,2,1,0^2,6,0^3,5]heptane-2,3-dicarboxylic Acid^1,2

Journal of the American Chemical Society, 1958
Stanley J. Cristol, Robert L. Snell
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Acid-Responsive Dissociation of Ferrocene Compounds: Diels-Alder Diene Equivalents for Selective Preparation of [60]Fullerene-Fused Bicyclo[2.2.1]hept-5-enes.

Journal of Organic Chemistry, 2022
Herein, an unprecedented transformation of [60]fullerene with ferrocene compounds giving access to various [60]fullerene-fused bicyclo[2.2.1]hept-5-enes is presented. In the presence of an acid, ferrocene compounds undergo an unusual dissociation process
Tongxin Liu, Han Wu, N. Ma, Chuanjie Zhang, Pengling Zhang, Jinliang Ma, Guisheng Zhang   +6 more
semanticscholar   +1 more source

N-Iodosuccinimide-Mediated Dimerization of 2-Alkynylnaphthols: A Highly Diastereoselective Construction of Bridged Polycyclic Compounds via Vinylidene ortho-Quinone Methide Intermediate.

Organic Letters, 2020
An unprecedented highly diastereoselective dimerization of 2-alkynylnaphthols is presented to furnish bridged polycyclic compounds containing a bicyclo[3.2.1]octane moiety with good to excellent yields.
Yun-Xuan Tan, Zhengxing Zhao, Zhili Chen, Shengli Huang, Shiqi Jia, Lei Peng, Dashuang Xu, Wenling Qin, Hailong Yan   +8 more
semanticscholar   +1 more source

Bicyclo[m.n.k]alkane Building Blocks as Promising Benzene and Cycloalkane Isosteres: Multigram Synthesis, Physicochemical and Structural Characterization.

Chemistry, 2023
Electrophilic double bond functionalization - intramolecular enolate alkylation sequence was used to obtain a series of bridged and fused bicyclo[m.n.k]alkane derivatives (i.e., bicyclo[4.1.1]octanes, bicyclo[2.2.1]heptanes, bicyclo[3.2.1]octanes ...
Volodymyr V. Semeno, Vadym O. Vasylchenko, Ihor M Fesun, Liudmyla Yu Ruzhylo, Mykhailo O Kipriianov, Kostiantyn P. Melnykov, Artem Skreminskyi, Rustam T. Iminov, Pavel K. Mykhailiuk, B. Vashchenko, O. Grygorenko   +10 more
semanticscholar   +1 more source

Bicyclo[2.1.1]hexanes by Visible Light-Driven Intramolecular Crossed [2 + 2] Photocycloadditions.

Organic Letters, 2022
Bicyclo[2.2.1]hexanes have become increasingly popular building blocks in medicinal chemistry as bridged scaffolds that provide unexplored chemical space.
T. Rigotti, T. Bach
semanticscholar   +1 more source

Imidazole-catalyzed construction of bridged bicyclo [3.3.1] ketals via formal [3 + 3]-cycloaddition of naphthols and 2-hydroxyl chromene derivatives.

Organic and biomolecular chemistry
Bridged bicyclo[3.3.1]nonanes having the O,O-ketal subunit are widely found in medicinal compounds. While several acid-catalyzed approaches have been reported for the construction of ketals, this study discloses an imidazole-catalyzed modular ...
Asha Budakoti, Priyankar Jha, Meenakshi Verma, P. Vasudev, Atul Gupta   +4 more
semanticscholar   +1 more source

Diverse Synthesis of Arene-Fused [n.1.1]-Bridged Molecules via Catalytic Cycloaddition and Rearrangement Reactions.

Angewandte Chemie
Although great advancement has been made in synthesis of 3D bridged bicyclic[n.1.1]-bioisosteres, facile construction of 2D/3D merged molecules incorporating bridged rings, as novel chemical space in drug discovery, remains a significant challenge ...
Tao Yu, Xue Zhao, Zaicheng Nie, Lulu Qin, Z. Ding, Liang Xu, Pengfei Li   +6 more
semanticscholar   +1 more source

Strategies for the Construction of Benzobicyclo[3.2.1]octane in Natural Product Synthesis.

Chemistry
Benzobicyclo[3.2.1]octane is a cage-like unique motif containing a bicyclo[3.2.1]octane structure fused with at least one benzene ring. It is found in various natural products that exhibit structural complexities and important biological activities.
Jia-Xuan Liu, Hui Li, Shi-Peng Zhang, Shi‐Chao Lu, Yanfang Gong, Shu Xu   +5 more
semanticscholar   +1 more source

μ-H-Bridged Bicyclo[3.3.3]undecyl Cations. Theoretical Calculations of Physical and Chemical Properties

, 2000
C. Taeschler, T. S. Sorensen
semanticscholar   +1 more source

Flexible all-perovskite tandem solar cells approaching 25% efficiency with molecule-bridged hole-selective contact

Nature Energy, 2022
Gang Chen, Makhsud I Saidaminov, Hongzhen Lin   +2 more
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