Results 51 to 60 of about 55,078 (177)

Methylenverbindungen von Nichtmetallen, III [1]. Metallcarbonyl-Komplexe mit methylenverbrückten Diphosphor-Liganden / Methylene Compounds of Non-Metals, III [1] Metal Carbonyl Complexes of Methylene-Bridged Diphosphorus Ligands

open access: yes, 1980
Compounds of the type R2PCH2PR2 (R = PriO, Me2N) react with cis-LM(CO)4 (L = Bicyclo[2,2,1]hepta-2,5-dien; M = Cr, Mo, W) complexes to yield cis-substituted [R2PCH2PR2]M(CO)4 derivatives.
M. Fild, W. Handke, W. Sheldrick
semanticscholar   +1 more source

Alkaloid-like Molecules for Drug Discovery [PDF]

open access: yes, 2016
The alkaloid class of natural compounds is extensively known for their variety of biological activities. A high percentage of currently employed chemotherapeutic drugs - more than 60% for cancer are of plant origin, and many are alkaloids.[1] Synthetic ...
Rawling, T, Ung, AT, Williams, SG
core  

Indole diterpenoid natural products as the inspiration for new synthetic methods and strategies. [PDF]

open access: yes, 2017
Indole terpenoids comprise a large class of natural products with diverse structural topologies and a broad range of biological activities. Accordingly, indole terpenoids have and continue to serve as attractive targets for chemical synthesis.
Corsello, Michael A   +2 more
core   +1 more source

Recent Advances in Ene Reactions with Carbon Enophiles

open access: yesAdvanced Synthesis &Catalysis, Volume 367, Issue 22, November 28, 2025.
Recent advances in the classical intra‐ and intermolecular ene nexus with carbon enophiles (alkenes, alkynes, arynes, and allenes) show a considerable increase in structural complexity and an enormous potential for functional applications in polymer science.
Thomas J. J. Müller
wiley   +1 more source

Kohlenhydrat-Modelle, I. Kinetische und thermodynamische Effekte bei Acetalisierungsreaktionen enantiomerenreiner Thiolactole [PDF]

open access: yes, 1985
Die Herstellung des enantiomerenreinen Thiolactols 1 wird beschrieben. Bei der Acetalisierung mit racemischem 1-Phenylethanol (rac-2) reagiert je nach Wahl der Reaktionsbedingungen entweder (R)-2 oder (S)-2 ...
Frost   +11 more
core   +1 more source

Ion‐Pairing‐Modulated Diradical Properties in Partially Conjugated Negatively Charged π‐Electronic Systems

open access: yesChemistry – A European Journal, Volume 31, Issue 65, November 20, 2025.
A quinonoidal dipyrrolyldiketone boron complex with an orthogonally arranged catechol unit in the dianionic form exhibited diradical properties, as observed from the singlet–triplet energy gaps (ΔEST) that were modulated by coexisting countercations. ΔEST values were controlled by the bridging boron moieties in the dianion diradicals.
Hiroto Kobayashi   +4 more
wiley   +1 more source

Synthesis and reactions of bicyclic [n.4.1] Ketones. [PDF]

open access: yes, 1974
Thesis (M.Phil.)--Chinese University of Hong Kong.Bibliography: leaves 59 ...

core  

Activation of 1,2- and 1,3-Ketoamides with Thiourea Organocatalyst for the Enantioselective Domino Synthesis of Fuctionalized Cyclohexanes

open access: yes, 2013
International audienceSeveral reactive sites of 1,2- and 1,3-ketoamides were successively exploited in two complementary domino transformations for the synthesis of polysubstituted monocyclic or bridged bicyclic cyclohexanes, with the creation of up to ...
Bonne, Damien   +7 more
core   +4 more sources

Diels-Alder reactions of 3-furylamines in organic and aqueous solvents [PDF]

open access: yes, 2006
Various 5-methyl-3-aminofurans have been shown to undergo facile Diels-Alder reactions with methyl acrylate in aqueous media. Reactions proceeded with exclusive regiochemistry, and enamine cycloadducts were readily hydrolyzed to afford 7-oxabicyclo[2.2.1]
Hugel, H, Lingham, A, Rook, T
core   +1 more source

X-ray and NMR spectroscopic characterisation of cyclic titanodiphenylsiloxanes and examination of the hydrolytic stability of their Si-O-Ti bonds [PDF]

open access: yes, 1998
Six crystalline titanodiphenylsiloxanes have been synthesised by reaction of diphenylsilanediol (DPSD) with titanium tetraisopropoxide or its complexes with acetylacetonate (acac) as ligand.
Hoebbel, Dagobert   +4 more
core   +2 more sources

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