Results 21 to 30 of about 43,175 (307)

Benzylethyldimethylammonium bromide [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2008
The crystal structure of the title compound, C(11)H(18)N(+)·Br(-), has been determined as part of an ongoing study of the influence of the alkyl chain length on amphiphilic activity of quaternary ammonium salts. The title salt forms a three-dimensional network of ionic contacts through weak C-H⋯Br hydrogen bonds, with donor-acceptor distances in the ...
Hodorowicz, Maciej, Stadnicka, Katarzyna
openaire   +3 more sources

Efficient syntheses of climate relevant isoprene nitrates and (1R,5S)-(−)-myrtenol nitrate [PDF]

open access: yes, 2016
Here we report the chemoselective synthesis of several important, climate relevant isoprene nitrates using silver nitrate to mediate a ’halide for nitrate’ substitution. Employing readily available starting materials, reagents and Horner–Wadsworth–Emmons
Bew, Sean   +3 more
core   +2 more sources

Electroanalytical Sensing of Bromides Using Radiolytically Synthesized Silver Nanoparticle Electrocatalysts

open access: yesJournal of Analytical Methods in Chemistry, 2017
Monitoring bromides (Br−) is of crucial importance since bromates, potential human carcinogens, are formed during ozonation of water containing bromides in concentrations >100 μg L−1.
Jadranka Milikić   +5 more
doaj   +1 more source

Palladium-Catalyzed Cascade Approach to 12-(Aryl)indolo[1,2- c ]quin­azolin-6(5 H )-ones [PDF]

open access: yes, 2018
A straightforward one-pot approach to the synthesis of challenging 12-arylindolo[1,2-c]quinazolin-6(5H)-ones is described. Starting from readily available o-(o-aminophenylethynyl)trifluoroacetanilides, palladium-catalyzed aminoarylation of the triple ...
Arcadi, Antonio   +6 more
core   +1 more source

Synthesis and Antimicrobial Activity of Carboxylate Phosphabetaines Derivatives with Alkyl Chains of Various Lengths

open access: yesJournal of Chemistry, 2013
The purpose of the present study was to investigate the antibacterial activity of fifteen novel nanosized alkyl esters of carboxylate phosphabetaine: β-(carboxyalkyl)ethyltriphenylphosphonium bromides 4–8, β-(carboxyalkyl)-β ...
Irina V. Galkina   +6 more
doaj   +1 more source

Synthesis of Pyridinium Amphiphiles Used for Transfection and Some Characteristics of Amphiphile/DNA Complex Formation [PDF]

open access: yes, 2000
Pyridinium amphiphiles have found practical use for the delivery of DNA into cells. Starting from 4-methylpyridine, a general synthesis has been devised for the production of pyridinium amphiphiles which allows variation in both the hydrophobic part and ...
Bosgraaf, Bouke,   +10 more
core   +2 more sources

Practical synthesis of aryl-2-methyl-3-butyn-2-ols from aryl bromides via conventional and decarboxylative copper-free Sonogashira coupling reactions

open access: yesBeilstein Journal of Organic Chemistry, 2014
Two efficient protocols for the palladium-catalyzed synthesis of aryl-2-methyl-3-butyn-2-ols from aryl bromides in the absence of copper were developed.
Andrea Caporale   +3 more
doaj   +1 more source

Synthesis of Optically Active Bifunctional Building Blocks through Enantioselective Copper-Catalyzed Allylic Alkylation Using Grignard Reagents [PDF]

open access: yes, 2007
Enantioselective copper-catalyzed allylic alkylations were performed on allylic bromides with a protected hydroxyl or amine functional group using several Grignard reagents and Taniaphos L1 as a ligand.
Feringa, Ben L.,   +3 more
core   +1 more source

Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process

open access: yesNature Communications, 2016
Benzyl bromides can be activated for radical reactions by photocatalytic single electron transfer. Here the authors show thatN-heterocyclic carbenes are also capable of activating this pathway for nitrobenzyl bromides, and that the radical intermediates ...
Bao-Sheng Li   +7 more
doaj   +1 more source

Paired electrolysis-enabled nickel-catalyzed enantioselective reductive cross-coupling between α-chloroesters and aryl bromides

open access: yesNature Communications, 2022
Precise matching of reaction rate and electric potential of electrodes in paired electrolysis is challenging. Here, the authors develop paired-electrolysis-enabled nickel-catalyzed enantioselective reductive cross-coupling of α-chloroesters and aryl ...
Dong Liu   +6 more
doaj   +1 more source

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