Results 21 to 30 of about 13,312 (269)

Reinvestigation of 2,2,6,6-tetramethylpiperidine-1-oxoammonium mono- and tribromide: From old compounds to new findings

open access: yesResults in Chemistry, 2021
The preparation and characteristics of 2,2,6,6-tetramethylpiperidine-1-oxoammonium bromides, old compounds with promising perspectives for use in modern energy storage devices, were reinvestigated.
Irina Y. Ponedel'kina   +2 more
doaj   +1 more source

Synthesis of benzocycloalkene derivatives via Pd-catalyzed one-pot two-step reactions of benzocyclic ketones, tosylhydrazide with aryl bromides

open access: yesJournal of Saudi Chemical Society, 2018
A new method for the synthesis of benzocycloalkene derivatives is described, through the palladium-catalyzed one-pot two-step reactions of benzocyclic ketones, tosylhydrazide with aryl bromides.
Zhenze Sun, Ping Liu, Bin Dai
doaj   +1 more source

Cu(I)- and Pd(0)-Catalyzed Arylation of Oxadiamines with Fluorinated Halogenobenzenes: Comparison of Efficiency

open access: yesMolecules, 2020
The comparison of the possibilities of Pd- and Cu-catalyzed amination reactions using fluorine-containing aryl bromides and iodides with oxadiamines to produce their N,N′-diaryl derivatives was carried out.
Maria S. Lyakhovich   +5 more
doaj   +1 more source

Engineered extracellular vesicles enriched with the miR‐214/199a cluster enhance the efficacy of chemotherapy in ovarian cancer

open access: yesMolecular Oncology, EarlyView.
Loss of the miR‐214/199a cluster is associated with recurrence in ovarian cancer. Engineered small extracellular vesicles (m214‐sEVs) elevate miR‐214‐3p/miR‐199a‐5p in tumor cells, suppress β‐catenin, TLR4, and YKT6 signaling, reprogram tumor‐derived sEV cargo, reduce chemoresistance and migration, and enhance carboplatin efficacy and survival in ...
Weida Wang   +12 more
wiley   +1 more source

About the Rare-Earth Metal(III) Bromide Oxoarsenates(III) RE5Br3[AsO3]4 with A- (RE = La and Ce) or B-Type Structure (RE = Pr, Nd, Sm–Tb) and RE3Br2[AsO3][As2O5] (RE = Y, Dy–Yb)

open access: yesSolids
The monoclinic rare-earth metal(III) bromide oxoarsenates(III) RE5Br3[AsO3]4 of the A-type (RE = La and Ce) crystallize in the space group C2/c with the lattice parameters a = 1834.67(9) pm, b = 553.41(3) pm, c = 1732.16(9) pm and β = 107.380(3)° for ...
Ralf J. C. Locke   +4 more
doaj   +1 more source

Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow

open access: yesBeilstein Journal of Organic Chemistry, 2018
A copper-based photocatalyst, Cu(tmp)(BINAP)BF4, was found to be active in a photoredox Appel-type conversion of alcohols to bromides. The catalyst was identified from a screening of 50 complexes and promoted the transformation of primary and secondary ...
Clémentine Minozzi   +3 more
doaj   +1 more source

Loss of IGF‐1R impairs DNA‐PKcs recruitment to chromatin leading to defective end‐joining

open access: yesMolecular Oncology, EarlyView.
IGF‐1R promotes radioresistance by facilitating DNA‐PKcs recruitment to chromatin, enabling non‐homologous end‐joining (NHEJ) repair of double‐strand breaks. Inhibition or loss of IGF‐1R disrupts this recruitment to damage sites, driving compensatory reliance on microhomology‐mediated end‐joining (MMEJ) repair.
Matthew O. Ellis   +3 more
wiley   +1 more source

Facile synthesis of functionalized spiro[indoline-3,2'-oxiran]-2-ones by Darzens reaction

open access: yesBeilstein Journal of Organic Chemistry, 2013
A series of functionalized spiro[indoline-3,2'-oxiran]-2-ones was efficiently synthesized by Darzens reaction of phenacyl bromides with isatins both with N-alkyl groups and without N-substituent in the presence of potassium carbonate as a base catalyst ...
Qin Fu, Chao-Guo Yan
doaj   +1 more source

Epigenetic silencing of the liver‐specific lncRNA LUNAR promotes liver cancer progression via NOTCH activation

open access: yesMolecular Oncology, EarlyView.
LUNAR is a liver‐specific long noncoding RNA (lncRNA) that is highly expressed in normal liver but becomes epigenetically silenced in hepatocellular carcinoma through promoter hypermethylation. Loss of LUNAR is associated with NOTCH activation, epithelial–mesenchymal transition, and metastasis, whereas restoring LUNAR restrains metastatic progression ...
Se Ha Jang   +9 more
wiley   +1 more source

Copper/N,N-Dimethylglycine Catalyzed Goldberg Reactions Between Aryl Bromides and Amides, Aryl Iodides and Secondary Acyclic Amides

open access: yesMolecules, 2014
An efficient and general copper-catalyzed Goldberg reaction at 90–110 °C between aryl bromides and amides providing the desired products in good to excellent yields has been developed using N,N-dimethylglycine as the ligand.
Liqin Jiang
doaj   +1 more source

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