Results 11 to 20 of about 25,994 (307)

Metal-Free Synthesis of Aryltriphenylphosphonium Bromides by the Reaction of Triphenylphosphine with Aryl Bromides in Refluxing Phenol

open access: yesACS Omega, 2019
A metal-free synthesis of aryltriphenylphosphonium bromides by the reaction of triphenylphosphine with aryl bromides in refluxing phenol is developed. This reaction tolerates hydroxymethyl, hydroxyphenyl, and carboxyl groups in aryl bromides, allowing to
Wenhua Huang, Chun-Hong Zhong
doaj   +2 more sources

Nickel-Catalyzed Reductive Coupling of Unactivated Alkyl Bromides and Aliphatic Aldehydes [PDF]

open access: yes, 2021
We report the development of a mild, convenient coupling of aliphatic aldehydes and unactivated alkyl bromides. The catalytic system features the use of a common Ni(II) precatalyst and a readily available bisoxazoline ligand and affords silyl-protected ...
John, Montgomery, Cole, Cruz
core   +1 more source

Synthesis of Tetrasubstituted Allenes via Palladium-Catalyzed Cross-Coupling of Vinyl Bromides with Diazo Compounds [PDF]

open access: yes, 2019
A highly efficient palladium-catalyzed cross-coupling of 2,2-diarylvinyl bromides with diazo compounds was developed, providing a convenient approach for the synthesis of tetrasubsti-tuted allenes. Both aryl diazo carbonyl compounds and N-tosylhydrazones
Chen-Guo, Feng   +7 more
core   +1 more source

Glycosylation chemistry promoted by iodine monobromide: Efficient synthesis of glycosyl bromides from thioglycosides, and O-glycosides from 'disarmed' thioglycosides and glycosyl bromides

open access: yes, 1997
Iodine monobromide has been found to be an efficient reagent for the conversion of both 'armed' and 'disarmed' thioglycosides (-SMe, -SPr(i), - SPh) into glycosyl bromides.
Kartha, K.P.R., Field, R.A.; id_orcid
core   +6 more sources

Pd-Catalyzed Nucleophilic Fluorination of Aryl Bromides [PDF]

open access: yes, 2014
On the basis of mechanism-driven reaction design, a Pd-catalyzed nucleophilic fluorination of aryl bromides and iodides has been developed. The method exhibits a broad substrate scope, especially with respect to nitrogen-containing heteroaryl bromides ...
Stephen L. Buchwald   +10 more
core   +1 more source

Copper/iron co-catalyzed alkoxycarbonylation of unactivated alkyl bromides [PDF]

open access: yes, 2018
Carbonylative transformations of alkyl bromides have been explored less than those of aryl halides, in part because of the high barrier to activation of aryl bromides.
Li, Y., Wu, X.-F.
core   +1 more source

THE BROMIDES IN EPILEPSY [PDF]

open access: yesThe Journal of Nervous and Mental Disease, 1890
n ...
openaire   +1 more source

Copper-Catalyzed Bifunctionalization/Annulation of Unactivated Alkene with Alkyl Bromides

open access: yes, 2023
β-Lactam is a ubiquitous scaffold in bioactive compounds and pharmaceuticals. Herein, we disclose a streamlined method for the construction of β-lactams starting from unactivated alkenes and alkyl bromides via a Cu-catalyzed inter-/intramolecular ...
Cancan Feng (15299897)   +1 more
core   +1 more source

Synthesis and Antimicrobial Activity of Carboxylate Phosphabetaines Derivatives with Alkyl Chains of Various Lengths

open access: yesJournal of Chemistry, 2013
The purpose of the present study was to investigate the antibacterial activity of fifteen novel nanosized alkyl esters of carboxylate phosphabetaine: β-(carboxyalkyl)ethyltriphenylphosphonium bromides 4–8, β-(carboxyalkyl)-β ...
Irina V. Galkina   +6 more
doaj   +1 more source

OPTIMIZATION AND MECHANISTIC STUDIES OF FACILE DEBROMINATION OF VINYL BROMIDES WITH VICINAL SUBSTITUTED AMINO GROUP RESIDUES

open access: yesZagazig Journal of Pharmaceutical Sciences, 1994
Debromination of α- bromoketones can be conducted easily. However, debromination of vinyl bromides is extremely difficult and requires vigorous conditions. This study describes the optimum conditions for the facile debromination of vinyl bromides.
Osama Al-Sabbagh   +3 more
doaj   +1 more source

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