Results 61 to 70 of about 13,312 (269)

Ionic Liquid-Mediated, Rapid N-Alkylation of Heterocyclic Compounds with Trialkyl Phosphites in the Presence of Dialkyl Acetylenedicarboxylates

E-Journal of Chemistry, 2012
Ionic liquids such as 1,3-dialkylimidazolium bromides and make excellent solvents for N-alkylation of heterocyclic compounds such as saccharin and rhodanine with trialkyl phosphites in the presence of dialkyl acetylenedicarboxylates.
Alireza Hassanabadi, Mohammad H. Mosslemin, Mohammad Anary-Abbasinejad, Azadeh Kalantarinejad, Mozhdeh Jerjisi Shirazi   +4 more
doaj   +1 more source

Tough and Skin‐Free Porous Polyelectrolyte Complex Hydrogels via Salt‐Induced Aqueous Phase Separation

Advanced Functional Materials, EarlyView.
Controlling counterion exchange rate during aqueous phase separation enables the formation of skin‐free, homogeneously porous polyelectrolyte complex hydrogels by suppressing kinetically trapped skin layers and macrovoids. The resulting hydrogel networks exhibit exceptional toughness (∼15 MJ·m−3) and enable 3D (bio)printing and post‐functionalization ...
Adrivit Mukherjee, Vishakha Vishakha, Julien Es Sayed, Hugo Brummer, Peter Dijkstra, Ajay Giri Prakash Kottapalli, Ranjita K. Bose, Marleen Kamperman   +7 more
wiley   +1 more source

Multifunctional Solid Polymer Electrolyte Films Integrating Intrinsic Self‐Healing and Dual Photo‐/pH‐Responsive Ionic Sensing for Intelligent Flexible Electronics

Advanced Functional Materials, EarlyView.
Multifunctional solid polymer electrolyte (SPE) films integrating intrinsic self‐healing, mechanical stretchability, and dual photo‐ and pH‐responsive ionic conductivity are developed. Constructed from thermoplastic polyurethane (TPU) and hydrogen‐bonded poly(thiourea triethylene glycol) (PTUEG3), these films form a dynamic supramolecular network ...
Mei‐Li Li, Tse‐Yu Lo, Chia‐Wei Chang, Yen‐Shen Hsu, Chen‐Yi Chien, Yu‐Yao Huang, Chia‐Ti Wu, Chun‐Chi Chang, Bo‐Chen Chen, Heng‐Hsuan Su, Chin‐Hua Liu, Che‐Ning Yeh, Jiun‐Tai Chen   +12 more
wiley   +1 more source

Pd‐Catalyzed Cross‐Coupling of Alkylbisboronic Esters

ChemistryOpen
A Pd‐catalyzed cross‐coupling between alkylbisboronic esters and aryl bromides is described. A variety of aryl bromides are found to be competent substrates in the reaction.
Philip P. Scott, Christopher E. Baird, Elizabeth A. Kraichely, Liam M. Radeke, Timothy J. Barker   +4 more
doaj   +1 more source

One‐Step Curcumin‐Mediated Multiphoton Lithography for Bioactive 3D Scaffolds

Advanced Functional Materials, EarlyView.
Curcumin‐mediated multiphoton lithography enables one‐step fabrication of highly architected complex gelatin methacryloyl scaffolds by exploiting curcumin as a multifunctional bioactive photoinitiator. The resulting 3D structures support mesenchymal stem cell adhesion, proliferation, and migration, while exhibiting dual antibacterial activity through ...
Myrto Charitaki, Michalis Stavrou, Chrysanthi Pinelopi Apostolidou, Elmina Kabouraki, David Gray, Anna Mitraki, Anthi Ranella, Maria Farsari   +7 more
wiley   +1 more source

COMPARATIVE POTENCY OF PIPECURONIUM BROMIDE AND PANCURONIUM BROMIDE

British Journal of Anaesthesia, 1989
Cumulative dose-response curves were constructed to determine the comparative potency of pipecuronium and pancuronium. From these, the ED50 and ED95 values were calculated. These were 24.96 micrograms kg-1 and 44.96 micrograms kg-1, respectively, for pipecuronium and 30.42 micrograms kg-1 and 61.12 micrograms kg-1, respectively, for pancuronium.
J C, Stanley, R K, Mirakhur
openaire   +2 more sources

Intrinsic Interfacial Energy Alignment Enables ETL‐Free Organic Solar Cells

Advanced Functional Materials, EarlyView.
Molecular orientation of the small‐molecule donor BTR‐Cl induces a vacuum‐level shift that pins the Fermi level at ∼4.4 eV at the active layer/Ag interface, enabling Ohmic contact formation without an electron transport layer. This strategy is extended to ternary PM6:Y6:BTR‐Cl devices, achieving an ETL‐free efficiency of 18.6% with enhanced operational
Heng Liu, Yuang Fu, Cangyu Wang, Luhang Xu, Xian‐Kai Chen, Man Chung Tang, Xinhui Lu   +6 more
wiley   +1 more source

Make‐Use‐Remake: Toward Indefinite Low‐Temperature Material Loops

Advanced Functional Materials, EarlyView.
We introduce a regenerable materials platform built from microparticles bound by a temperature‐responsive polymer shell, enabling strong, processable structures from diverse feedstocks. The material is shaped at low temperatures (80°C) using common manufacturing methods and reprocessed repeatedly in the presence of water, demonstrating stable ...
Nikola Křivánková, Wouter van der Wijngaart, Ulrica Edlund   +2 more
wiley   +1 more source

Nickel-catalyzed reductive thiolation and selenylation of unactivated alkyl bromides

Nature Communications, 2018
Chalcogen-containing compounds find broad application in chemical industry. Here, the authors report a nickel-catalyzed reductive chalcogenation of unactivated alkyl bromides with thiosulfonates and selenosulfonates to access a range of unsymmetrical ...
Yi Fang, Torben Rogge, Lutz Ackermann, Shun-Yi Wang, Shun-Jun Ji   +4 more
doaj   +1 more source

A Facile Synthesis of Substituted Benzyl Selenocyanatesâ€

Molecules, 2004
Benzyl selenocyanates can be made from the corresponding benzylic bromides or chlorides in 30-60 minutes using acetonitrile as a solvent. The products may be obtained pure in satisfactory yields without recourse to chromatography.
Joanne Kivella Tillotson, Joelle Rodriguez, Corey Mostafa, Bianca Matos, Linda A. Jacob   +4 more
doaj   +1 more source