Results 201 to 210 of about 29,373 (276)

Halogenase-Assisted Biocatalytic Derivatization of Aminothiazoles and Cephalosporin Antibiotics. [PDF]

J Org Chem
Branham PJ, Saha N, Oyelere SE, Agarwal V.   +3 more
europepmc   +1 more source

Cooling Bromine‐Contained Photovoltaic Perovskites: The Impact of Phase Segregation and Lattice Expansion

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
An optimal bromine content stabilizes the perovskite lattice during extreme temperature cycling by suppressing vacancies and regulating crystal growth, enhances open‐circuit voltage of the device by enhancing defect relaxation via lattice expansion.
Jing Zhang, Rui Liu, Weihui Bi, Peng Mao, Mengyuan Li, Jun Lv, Pochuan Yang, Zongbao Zhang, Gaorong Han, Yufei Zhong   +9 more
wiley   +1 more source

Total Synthesis of Daphnepapytone A. [PDF]

J Org Chem
Martinez JB, Hanson PR.
europepmc   +1 more source

Organotrifluoroborate‐Driven Phase Stabilization and Defect Suppression for Wide‐Bandgap Perovskites

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A multifunctional additive, trifluoro(pyrrolidin‐1‐ium‐1‐ylmethyl) borate (PyMe‐BF3), leverages B‐F coordination and N‐H hydrogen bonding to passivate undercoordinated Pb2+, fill halide vacancies, and suppress phase segregation. Its preferential enrichment at the buried interface targets the defect‐rich region, enabling simultaneous wide‐bandgap ...
Suzhen Liu, Wenhan Yang, Sen Jiang, Yingjie Zhu, Yuexin Lin, Ran Chen, Hongyu Feng, Wenye Jiang, Binglan Xiong, Nan Zhang, Xiaojun Li, Chao Liang   +11 more
wiley   +1 more source

A supporting-electrolyte-free four-compartment electrochemical reactor for aqueous and organic phase electrosynthesis. [PDF]

Proc Natl Acad Sci U S A
Wu H, Liu B, Su C, Chen D, Jiao L, Zheng H, Wang L, Teng Z, Shao L, Xu Y, Liu B.   +10 more
europepmc   +1 more source

Synthesis and Biological Profile of Substituted Pyrrolidinyl Carboxamides for Acyl‐ACP Thioesterase Inhibition

European Journal of Organic Chemistry, EarlyView.
The work outlined herein covers a series of novel herbicidal lead structures that possess a pyrrolidinyl pyrazole carboxamide scaffold as a key structural feature, carrying further substituted benzyl side chains. Based on scaffold hopping approaches from known fungicidal and herbicidal compounds and utilizing an optimized synthetic approach, a broader ...
Elisabeth Asmus, Martin Annau, Neanne Alnafta, David M. Barber, Guido Bojack, Birgit Bollenbach‐Wahl, Ralf Braun, Ronald W. Brown, Luke R. Churchman, Christine Dörnbrack, Andrew Earl, Tyler Fahrenhorst‐Jones, Jörg Freigang, Claudia Hartfiel, Ines Heinemann, Arnim Köhn, Bernd Laber, Michael C. McLeod, Catherine S. Meister, Gudrun Lange, Luka Posa, Shaun Rees, Dirk Schmutzler, Anna M. Reingruber, Jens Frackenpohl   +24 more
wiley   +1 more source

Kinetics of Hypohalous Acid Intermediates Governing Disinfection Byproduct Formation in Peracetic Acid-Treated Halide-Containing Waters. [PDF]

Environ Sci Technol
Li J, DiLoreto S, Huang CH.
europepmc   +1 more source

Triptindane‐9,10,11‐triol: Threefold Hydride Transfer from Lithium Aluminum Hydride as the Key Step to C3‐Symmetrically Trifunctionalized Tribenzo[3.3.3]propellanes

European Journal of Organic Chemistry, EarlyView.
Threefold reduction of 9,10,11‐triptindanetrione with LiAlH4 or NaBH4 yields exclusively the C3‐symmetric triol, suggesting an intracomplex (“rolling”) mechanism. However, use of LiAlH4/LiAlD4 (1 : 1) reveals a preceding hydride exchange. Mechanistic implications are discussed including the reduction of the related diketone.
Thorsten Hackfort, Bernhard M. Malorny, Andreas Mix, Beate Neumann, Hans‐Georg Stammler, Dietmar Kuck   +5 more
wiley   +1 more source

Producing aryl halides from lignin. [PDF]

Nat Commun
Liu Y, Li Y, He Z, Wu S, Ma C, Li W, Li S, Chen Z, Liu S, Tian B.   +9 more
europepmc   +1 more source

EDA Complex–Mediated C(sp3)–H Cross‐Dehydrogenative Coupling Enables Synthesis of Noncanonical α,β‐Diamino Acids

European Journal of Organic Chemistry, EarlyView.
Access to nonproteinogenic α,β‐diamino acids from simple feedstock precursors is of great interest to generate medicinal small molecule libraries. We report a regioselective photoinduced C(sp3)–C(sp3) cross‐dehydrogenative coupling (CDC) of N‐arylglycine derivatives with amides.
Krishnakumar Sachidanandan, Cole Stenftenagel, Athul Joshy, Alexander M. Cluff, Sébastien Laulhé   +4 more
wiley   +1 more source