Results 41 to 50 of about 15,688 (280)

Clustomesogen Showing Sub‐Zero Liquid Crystal Properties: Supramolecular Assembly Between Cs2[Mo6Ii8(OCOC2F5)6] and Hexaethylenoxide Containing Mesogenic Dimers

open access: yesAdvanced Materials, EarlyView.
Associating a red‐NIR phosphorescent octahedral hexanuclear molybdenum cluster compound with hexaethyleneoxide chains bearing mesogenic units on both ends leads to an emissive hybrid liquid crystal showing mesomorphism on a very unusual temperature range down to −25°C.
Killiann Heinz   +11 more
wiley   +1 more source

Simple and convenient two step synthesis of 5-bromo-2,3-dimethoxy-6-methyl-1,4-benzoquinone

open access: yesGreen Processing and Synthesis, 2019
5-bromo-2,3-dimethoxy-6-methyl-1,4-benzoquinone 3, a key intermediate for preparing coenzyme Q compounds, was readily synthesized in two steps by a reaction sequence starting from the commercially available 3,4,5-trimethoxytoluene 1 via bromination and ...
Qiu Yong-Fu   +4 more
doaj   +1 more source

Polymeric Sorbents as Energy‐Efficient Alternative to Cryogenic Distillation for Light Hydrocarbon Purification

open access: yesAdvanced Materials, EarlyView.
The transition from cryogenic distillation to polymeric sorbents for light hydrocarbon purification is crucial for energy and environmental sustainability. The polymeric sorbents are engineered to separate gas mixtures based on their specific properties.
Kelechi Festus   +9 more
wiley   +1 more source

Adsorption‐Engineered Hydrocarbon Ionomers for Durable Proton‐Exchange Membrane Fuel Cells

open access: yesAdvanced Materials, EarlyView.
Hydrocarbon ionomers suffer from oxidation‐driven interfacial degradation in PEM fuel cell cathodes, leading to catalyst instability. Here, adsorption‐engineered poly(fluorene) ionomers decouple interfacial anchoring from oxidative degradation, enabling strong catalyst–ionomer interactions while resisting electrochemical oxidation.
Heemin Park   +14 more
wiley   +1 more source

2D Abrupt Nano‐Junctions Blending sp–sp2 Bonds on Atomically Precise Heterostructures

open access: yesAdvanced Materials, EarlyView.
A lateral heterostructure between atomically precise sp–sp2$^2$ metalated graphdiyne and sp2$^2$ graphene nanoribbons is realized by on‐surface synthesis and investigated by STM and DFT. The impact of on‐surface synthesis byproducts on covalent junction formation yield is unveiled.
Alice Cartoceti   +10 more
wiley   +1 more source

Hydrazone ligated–vanadium(V) complex: catalytic oxidative bromination of organic substrates promoted by Brønsted acid or Lewis acid

open access: yesDiscover Chemistry
Vanadium(V) complex was prepared by reaction of vanadium acetylacetonate with hydrazone ligand. The complex was characterized by IR, 1H NMR and UV-Visible spectroscopy.
Sunshine Dominic Kurbah   +1 more
doaj   +1 more source

Bromination of Chalcone

open access: yesARO-The Scientific Journal of Koya University
In this research work, a new compound, namely 2,6-dibromo-2,6-bis(bromo(phenyl)methyl)cyclohexanone (1), is synthesized and characterized for possible applications in organic electronic devices.
Kosrat N. Kaka   +3 more
doaj   +1 more source

On the bromination of the dihydroazulene/vinylheptafulvene photo-/thermoswitch

open access: yesBeilstein Journal of Organic Chemistry, 2012
Background: The dihydroazulene (DHA)/vinylheptafulvene (VHF) system (with two cyano groups at C1) functions as a photo-/thermoswitch. Direct ionic bromination of DHA has previously furnished a regioselective route to a 7,8-dibromide, which by elimination
Virginia Mazzanti   +6 more
doaj   +1 more source

Bromination: An Alternative Strategy for Non‐Fullerene Small Molecule Acceptors

open access: yesAdvanced Science, 2020
The concept of bromination for organic solar cells has received little attention. However, the electron withdrawing ability and noncovalent interactions of bromine are similar to those of fluorine and chlorine atoms.
Huan Wang   +10 more
doaj   +1 more source

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