Results 31 to 40 of about 91,509 (283)

Polimerização 1,4 - cis de butadieno com o sistema catalítico tetracloreto de titânio/triisobutilalumínio/iodo 1,4 cis-Polymerization of butadiene by the catalyst system titanium tetrachloride/triisobutylaluminium/iodine

open access: yesPolímeros, 2000
Foi utilizado o sistema catalítico tipo Ziegler-Natta modificado, constituído por TiCl4/I2/Al(i-Bu)3 para a síntese de polibutadieno com alto teor de unidades 1,4-cis.
Neusa M. T. Pires   +2 more
doaj   +1 more source

Impact of Reaction System Turbulence on the Dispersity and Activity of Heterogeneous Ziegler–Natta Catalytic Systems for Polydiene Production: Insights from Kinetic and CFD Analyses

open access: yesCompounds
An analysis was conducted to investigate how reaction system turbulence affects the butadiene-isoprene copolymerization in the presence of the TiCl4 + Al(i-Bu)3 catalytic system.
Konstantin A. Tereshchenko   +3 more
doaj   +1 more source

Fire properties of styrenic polymer–clay nanocomposites based on an oligomerically-modified clay [PDF]

open access: yes, 2006
An oligomerically-modified clay has been used to fabricate nanocomposites with styrenic polymers, such as polystyrene, high-impacted polystyrene, poly(styrene-co-acrylonitrile) and acrylonitrile–butadiene–styrene by melt blending. The clay dispersion was
Jiang, David D.   +2 more
core   +2 more sources

Effect of Monomer Mixture Composition on TiCl4-Al(i-C4H9)3 Catalytic System Activity in Butadiene–Isoprene Copolymerization: A Theoretical Study

open access: yesComputation
Divinylisoprene rubber, a copolymer of butadiene and isoprene, is used as raw material for rubber technical products, combining isoprene rubber’s elasticity and butadiene rubber’s wear resistance.
Konstantin A. Tereshchenko   +4 more
doaj   +1 more source

Synthesis of 6-Nitroderivatives of Oxazolo[3,2-a]-pyridines and Their Reactions with Nucleophiles

open access: yesMolecules, 2003
5-Nitro-2-pyridone can be selectively N-phenacylated, and the resulting phenacylpyridones I undergo cyclization to 6-nitrooxazolo[3,2-a]pyridinium salts II.
Eugene V. Babaev, Alexander A. Bush
doaj   +1 more source

Characterization of carbon monoxide, methane and nonmethane hydrocarbons in emerging cities of Saudi Arabia and Pakistan and in Singapore [PDF]

open access: yes, 2016
We investigate the composition of 63 C2-C10 nonmethane hydrocarbons (NMHCs), methane (CH4) and carbon monoxide (CO), in Jeddah, Mecca, and Madina (Saudi Arabia), in Lahore, (Pakistan), and in Singapore. We established a database with which to compare and
Aburizaiza, Omar S   +11 more
core   +1 more source

What Do Large Language Models Know About Materials?

open access: yesAdvanced Engineering Materials, EarlyView.
If large language models (LLMs) are to be used inside the material discovery and engineering process, they must be benchmarked for the accurateness of intrinsic material knowledge. The current work introduces 1) a reasoning process through the processing–structure–property–performance chain and 2) a tool for benchmarking knowledge of LLMs concerning ...
Adrian Ehrenhofer   +2 more
wiley   +1 more source

Unexpected high performance of ZIF-8 membranes for 1,3-butadiene purification

open access: yesJournal of Membrane Science Letters, 2023
The purification of 1,3-butadiene from C4 hydrocarbon mixtures currently relies on energy-intensive extractive distillation. In this study, we employed ZIF membranes for this challenging separation for the first time, unveiling their superior capability ...
Jun-Wei Wang, Zhiqin Qiang, Xiaoli Ma
doaj   +1 more source

Blends of Nitrile Butadiene Rubber/poly (Vinyl Chloride): the Use of Maleated Anhydride Castor Oil Based Plasticizer [PDF]

open access: yes, 2016
Recently, much attention has been focused on research to replace petroleum-based plasticizers, with biodegradable materials, such as biopolymer which offers competitive mechanical properties.
Dewi, I. R. (Indiah)   +2 more
core  

Sampling Free Energy Surfaces as Slices by Combining Umbrella Sampling and Metadynamics [PDF]

open access: yes, 2016
Metadynamics (MTD) is a very powerful technique to sample high-dimensional free energy landscapes, and due to its self-guiding property, the method has been successful in studying complex reactions and conformational changes.
Awasthi, Shalini   +2 more
core   +2 more sources

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