Results 1 to 10 of about 1,823 (242)

Diaza-1,3-butadienes as Useful Intermediate in Heterocycles Synthesis [PDF]

open access: yesMolecules, 2022
Many heterocyclic compounds can be synthetized using diaza-1,3-butadienes (DADs) as key structural precursors. Isolated and in situ diaza-1,3-butadienes, produced from their respective precursors (typically imines and hydrazones) under a variety of ...
Jorge Heredia-Moya   +2 more
exaly   +4 more sources

α-Diimine Cisplatin Derivatives: Synthesis, Structure, Cyclic Voltammetry and Cytotoxicity [PDF]

open access: yesMolecules, 2022
Three new Pt(II) complexes [(dpp-DAD)PtCl2] (I), [(Mes-DAD(Me)2)PtCl2] (II) and [(dpp-DAD(Me)2)PtCl2] (III) were synthesized by the direct reaction of [(CH3CN)2PtCl2] and corresponding redox-active 1,4-diaza-1,3-butadienes (DAD).
Dmitriy S. Yambulatov   +10 more
doaj   +2 more sources

Domino reactions of chromones with activated carbonyl compounds [PDF]

open access: yesBeilstein Journal of Organic Chemistry
Domino reactions of chromones with activated carbonyl compounds, such as dimethyl acetone-1,3-dicarboxylate and 1,3-diphenylacetone, and with 1,3-bis(silyloxy)-1,3-butadienes, electroneutral equivalents of 1,3-dicarbonyl dianions, allow for a convenient ...
Peter Langer
doaj   +2 more sources

Michael addition of P-nucleophiles to azoalkenes provides simple access to phosphine oxides bearing an alkylhydrazone moiety [PDF]

open access: yesFrontiers in Chemistry, 2023
β-Hydrazonophosphine oxides are precursors of useful organophosphorus compounds, including phosphorylated N-heterocycles, α-aminophosphonates, and vinylphosphonates.
Alexandr O. Kokuev   +1 more
doaj   +2 more sources

One-Pot Synthesis of Push–Pull Butadienes from 1,3-Diethyl-2-thiobarbituric Acid and Propargylic Alcohols

open access: yesMolbank, 2022
A new synthetic procedure for obtaining two previously reported donor-acceptor butadiene dyes, namely 5-(3,3-bis(4-methoxyphenyl)allylidene)-1,3-diethyl-2-thioxodihydropyrimidine-4,6(1H,5H)-dione and 5-(3,3-bis(4-(dimethylamino)phenyl)allylidene)-1,3 ...
Javier Francos, Victorio Cadierno
doaj   +1 more source

Butadiene or styrene or butadiene and styrene or else? [PDF]

open access: yesOccupational and Environmental Medicine, 2006
Commentary on the paper by Sathiakumar et al ( Occup Environ Med , December 2005)* In the December 2005 issue of this journal, Sathiakumar and colleagues1 report on the extended follow up of the University of Alabama cohort in the styrene–butadiene–rubber industry.
K, Straif, R, Baan, V, Cogliano
openaire   +2 more sources

Synthesis and Characterization of Multiple Functionalized Cyclohexanone Using Diels–Alder Reaction of α-Nitrocinnamate

open access: yesReactions, 2022
A systematic study of the Diels–Alder reaction of α-nitrocinnamate was performed. The reaction of p-substituted α-nitrocinnamate with 2,3-dimethyl-1,3-butadienes smoothly proceeded regardless of the p-substituent, which was either an electron-donating or
Takumi Hamada   +2 more
doaj   +1 more source

Rotational Barrier and Conjugation: Theoretical Study of Resonance Stabilization of Various Substituents for the Donors NH2 and OCH3 in Substituted 1,3-Butadienes

open access: yesIndonesian Journal of Chemistry, 2019
The barrier to internal rotation around the central C2–C3 single bond of a series of (1E)-monosubstituted 1,3-butadienes and (1E,3E)-1-Y-4-X-disubstituted butadienes, with Y=NH2 or OCH3 and X=NO2, CHO, COOH, CN, CF3, Cl or F, were studied at the density ...
Ali Hussain Yateem
doaj   +1 more source

Carcinogenicity of 1,3-Butadiene

open access: yesEnvironmental Health Perspectives, 1992
1,3-Butadiene, a high-production volume chemical used largely in the manufacture of synthetic rubber, is a multiple organ carcinogen in rats and mice. In inhalation studies conducted in mice by the National Toxicology Program, high rates of early lethal lymphomas occurring at exposure levels of 625 ppm or higher reduced the development and expression ...
R L, Melnick, C C, Shackelford, J, Huff
openaire   +3 more sources

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