Results 1 to 10 of about 200 (197)

Diaza-1,3-butadienes as Useful Intermediate in Heterocycles Synthesis

open access: yesMolecules, 2022
Many heterocyclic compounds can be synthetized using diaza-1,3-butadienes (DADs) as key structural precursors. Isolated and in situ diaza-1,3-butadienes, produced from their respective precursors (typically imines and hydrazones) under a variety of ...
Christian David Alcívar Leon   +2 more
exaly   +3 more sources

One-Pot Synthesis of Push–Pull Butadienes from 1,3-Diethyl-2-thiobarbituric Acid and Propargylic Alcohols

open access: yesMolbank, 2022
A new synthetic procedure for obtaining two previously reported donor-acceptor butadiene dyes, namely 5-(3,3-bis(4-methoxyphenyl)allylidene)-1,3-diethyl-2-thioxodihydropyrimidine-4,6(1H,5H)-dione and 5-(3,3-bis(4-(dimethylamino)phenyl)allylidene)-1,3 ...
Javier Francos, Victorio Cadierno
doaj   +1 more source

α-Diimine Cisplatin Derivatives: Synthesis, Structure, Cyclic Voltammetry and Cytotoxicity

open access: yesMolecules, 2022
Three new Pt(II) complexes [(dpp-DAD)PtCl2] (I), [(Mes-DAD(Me)2)PtCl2] (II) and [(dpp-DAD(Me)2)PtCl2] (III) were synthesized by the direct reaction of [(CH3CN)2PtCl2] and corresponding redox-active 1,4-diaza-1,3-butadienes (DAD).
Dmitriy S. Yambulatov   +10 more
doaj   +1 more source

Butadiene or styrene or butadiene and styrene or else? [PDF]

open access: yesOccupational and Environmental Medicine, 2006
Commentary on the paper by Sathiakumar et al ( Occup Environ Med , December 2005)* In the December 2005 issue of this journal, Sathiakumar and colleagues1 report on the extended follow up of the University of Alabama cohort in the styrene–butadiene–rubber industry.
K, Straif, R, Baan, V, Cogliano
openaire   +2 more sources

Michael addition of P-nucleophiles to azoalkenes provides simple access to phosphine oxides bearing an alkylhydrazone moiety

open access: yesFrontiers in Chemistry, 2023
β-Hydrazonophosphine oxides are precursors of useful organophosphorus compounds, including phosphorylated N-heterocycles, α-aminophosphonates, and vinylphosphonates.
Alexandr O. Kokuev   +1 more
doaj   +1 more source

Synthesis and Characterization of Multiple Functionalized Cyclohexanone Using Diels–Alder Reaction of α-Nitrocinnamate

open access: yesReactions, 2022
A systematic study of the Diels–Alder reaction of α-nitrocinnamate was performed. The reaction of p-substituted α-nitrocinnamate with 2,3-dimethyl-1,3-butadienes smoothly proceeded regardless of the p-substituent, which was either an electron-donating or
Takumi Hamada   +2 more
doaj   +1 more source

Rotational Barrier and Conjugation: Theoretical Study of Resonance Stabilization of Various Substituents for the Donors NH2 and OCH3 in Substituted 1,3-Butadienes

open access: yesIndonesian Journal of Chemistry, 2019
The barrier to internal rotation around the central C2–C3 single bond of a series of (1E)-monosubstituted 1,3-butadienes and (1E,3E)-1-Y-4-X-disubstituted butadienes, with Y=NH2 or OCH3 and X=NO2, CHO, COOH, CN, CF3, Cl or F, were studied at the density ...
Ali Hussain Yateem
doaj   +1 more source

Carcinogenicity of 1,3-Butadiene

open access: yesEnvironmental Health Perspectives, 1992
1,3-Butadiene, a high-production volume chemical used largely in the manufacture of synthetic rubber, is a multiple organ carcinogen in rats and mice. In inhalation studies conducted in mice by the National Toxicology Program, high rates of early lethal lymphomas occurring at exposure levels of 625 ppm or higher reduced the development and expression ...
R L, Melnick, C C, Shackelford, J, Huff
openaire   +3 more sources

Synthesis of some novel annulated pyrido[2,3-d]pyrimidines via stereoselective intramolecular hetero Diels–Alder reactions of 1-oxa-1,3-butadienes

open access: yesBeilstein Journal of Organic Chemistry, 2010
Some novel annulated pyrido[2,3-d]pyrimidines 6 and 7 were synthesized stereoselectively by intramolecular hetero Diels–Alder reactions involving 1-oxa-1,3-butadienes.
Mohit L. Deb, Pulak J. Bhuyan
doaj   +1 more source

Thermal Decomposition of Vicinal Dinitroalkanes

open access: yesCHIMIA, 1988
Three sym-tetraalkyl-dinitroethanes 1-3 have been decomposed in solution at 180 to 215 °C. The alkylated 1,3-butadienes 10,12, and 13 are formed by elemination of HNO2.
Katharina Fritzsche   +2 more
doaj   +1 more source

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