Results 41 to 50 of about 3,857 (276)

Battery‐Inspired Electrochemical Synapses for Neuromorphic Applications

open access: yesAdvanced Science, EarlyView.
Battery‐ion‐inspired synaptic devices integrate diverse electrolyte systems (solid, ion‐gel, liquid) with transition metal oxides, two‐dimensional materials, and organic channels to regulate ion‐electron coupling. By tailoring ion transport and host interactions, these platforms enable controllable plasticity and energy‐efficient implementations for ...
Won Woo Lee   +6 more
wiley   +1 more source

Intermolecular Diels–Alder Cycloaddition/Cross-Coupling Sequences of 2‑Bromo-1,3-butadienes

open access: yes, 2020
2-Bromo-1,3-butadienes are demonstrated to be effective substrates for tandem Diels–Alder/transition metal cross-coupling reaction sequences. Intermolecular cycloaddition of a 2-bromo-1,3-diene with activated dienophiles proceeded under Lewis acid ...
Hans Choi (8366853)   +7 more
core   +1 more source

Synthesis of Functionalized Biaryls, Benzophenones, Phenols, Fluorenones, Fluoroarenes, and Chloroarenes based on formal [3+3] Cyclocondensations of 1,3-bis(silyloxy)-1,3-butadienes and 1,3,5-tris(silyloxy)-1,3,5-hexatrienes [PDF]

open access: yes, 2009
The work in this dissertation is mainly concerned with synthesis of sterically encumbered biaryls, highly functionalized polyketide-type phenols, benzophenones, phenols, (arylated, chlorinated and fluorinated) azaxanthones, functionalized fluorenones ...
Adeel, Muhammad (gnd: 138536554)
core   +1 more source

A Dispersant‐Driven Carbon‐Binder Domains Homogeneity in High‐Energy‐Density Electrodes for Lithium‐Ion Batteries

open access: yesAdvanced Science, EarlyView.
A polar dispersant, aromatic‐functionalized polyacrylate (AFPA), enables the formation of a uniform CBD network by enhancing miscibility with PVDF and suppressing phase separation. This leads to α‐phase crystallization of PVDF and aligned CNT networks within the CBD, resulting in well‐connected structures that improve cohesion, electron/ion transport ...
Da‐Sol Kwon   +17 more
wiley   +1 more source

Gas-Phase Pyrolytic Reaction of 4-Aryl-3-buten-2-ols and Allyl Benzyl Ethers: Kinetic and Mechanistic Study

open access: yesMolecules, 2010
Flash vacuum pyrolysis (FVP) of 4-aryl-3-buten-2-ols [ArCH=CH-CH(CH3)OH, where Ar is phenyl, p-MeO, p-Me, p-Cl, p-NO2] gave the corresponding buta-1,3-dien-1-ylbenzene (ArCH=CH-CH=CH2, where Ar is Ph, p-MeO, p-Me, p-Cl, p-NO2) and 7-X-1,2 ...
Maher R. Ibrahim   +3 more
doaj   +1 more source

Synthesis and Asymmetric Diels−Alder Reactions of Enantiopure 3-(Alkylsulfinyl)-1-methoxy-1,3-butadienes

open access: yes, 2016
Simple syntheses of enantiopure (E)- and (Z)-3-(alkylsulfinyl)-1-methoxy-1,3-butadienes 2 and 3 were provided by the addition of (1S)-isoborneol-10-sulfenic and (S)-phenyl-2-hydroxyethanesulfenic acids 8 to (E)- and (Z)-1-methoxybut-1-en-3-ynes (9) and ...
Paola Bonaccorsi (1795771)   +4 more
core   +1 more source

Flame Suppression in Lithium‐Ion Batteries During Thermal Runaway Through Solvent Design Considering the Volatility–Flammability Relationship

open access: yesAdvanced Science, EarlyView.
An asymmetric sulfonate solvent forms thermally stable interphases and demonstrates non‐flammability, suppressing heat accumulation for safer, high‐performance lithium‐ion batteries. ABSTRACT An asymmetric sulfonate‐based linear solvent, 2,2,2‐trifluoromethyl mesylate (FMS), is designed and used as the primary solvent in liquid electrolytes to enhance ...
Chi‐Yeong Hong   +12 more
wiley   +1 more source

Different reactivity of phosphorylallenes under the action of Brønsted or Lewis acids: a crucial role of involvement of the P=O group in intra- or intermolecular interactions at the formation of cationic intermediates

open access: yesBeilstein Journal of Organic Chemistry, 2019
3-Methylbuta-1,2-dien-1-ylphosphonic acid derivatives (phosphorylallenes) [X2(O=)P–CR=C=CMe2, X = Cl, OMe, NR2, or SAr] undergo intramolecular cyclization into the corresponding 1,2-oxaphospholium ions in the Brønsted superacid TfOH.
Stanislav V. Lozovskiy   +2 more
doaj   +1 more source

Palladium-catalyzed cross-coupling of cyclopropylmethyl N-tosylhydrazones with aromatic bromides: an easy access to multisubstituted 1,3-butadienes

open access: yes, 2013
Direct synthesis of 1,1-disubstitued 1,3-butadienes has been efficiently realized from the cross-coupling of cyclopropylmethyl N-tosylhydrazones with aromatic bromides by means of PdCl2(MeCN)(2) as catalyst.
Liu, Tingting   +4 more
core   +1 more source

Thermochemical Core–Shell Architecturing of Si‐SWCNT Composites for High‐Performance Li‐Ion Battery Anodes

open access: yesAdvanced Science, EarlyView.
A thermochemically engineered core–shell Si architecture is developed through the controlled evolution of a SWCNT‐coated Mg2Si precursor. The process simultaneously generates a nanoporous Si shell for strain accommodation and Li+ transport, a chemically anchored SiC interfacial layer for robust mechanical and electrical coupling, and a Mg‐containing Si
Dong Gyun Hong   +11 more
wiley   +1 more source

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