Results 61 to 70 of about 200 (197)

Polarity on Demand: Nucleophilic, Electrophilic, and Ambiphilic Reactivity at a 9,10‐Dihydro‐9,10‐Disilaanthracene Platform

Chemistry – A European Journal, EarlyView.
A 9,10‐dihydro‐9,10‐disilaanthracene platform was efficiently synthesized and features intrinsically electrophilic Si sites. Upon stepwise reductive Si─H bond cleavage, these Si sites are converted into nucleophilic centers. This controlled polarity switching also enables ambiphilic reactivity within a homo‐heteroelement framework.
Moritz Schmidt, Alexander Virovets, Eugenia Peresypkina, Hans‐Wolfram Lerner, Matthias Wagner   +4 more
wiley   +1 more source

Dinuclear Group 4 Metallocene Catalysts of the Type [(Cp2M)2(μ‐Me)(μ‐C2R)]: Structure‐Activity Relationships in Ethylene Polymerization

Chemistry – A European Journal, EarlyView.
Homo‐ and heterodinuclear group 4 metallocene complexes of the type [(Cp2M)2(μ‐Me)(μ‐C2R)] (M = Ti, Zr) are active catalysts for the polymerization of ethylene in the presence of aluminium‐free activators. The catalytically active species are proposed to have dinuclear character and depending on the type of activator, unique reactivity was observed ...
Hanan Al Hamwi, Mirko Rippke, Anke Spannenberg, Michal Horáček, Jiří Pinkas, Vojtěch Varga, Martin Lamač, Fabian Reiß, Torsten Beweries   +8 more
wiley   +1 more source

SO2 Transfer Enabled by an Easy‐to‐Handle Ionic Liquid

Chemistry – A European Journal, EarlyView.
Best of both worlds: The ionic liquid [NEt3Me][Cl(SO2)n] unites the atom economy and low cost of sulfur dioxide with the safety and applicability of common surrogates, streamlining SO2 transfer to access to 3‐sulfolenes, sulfonamides, and SuFEx reagents.
Johanna S. Sturm, Letizia Lanfredi, Severin Erbertseder, Marius Balizs, Patrick Voßnacker, Simon Steinhauer, Merlin Kleoff, Anja Wiesner, Niklas Limberg, Patrick Pröhm, Franz‐Lucas Haut, Sebastian Riedel   +11 more
wiley   +1 more source

Catalytic Oxidation of CO and VOC in Flue Gas of Coffee Roasting Machines

Chemie Ingenieur Technik, EarlyView.
Platinum‐coated cordierite monoliths effectively oxidized CO and VOC in coffee roasting exhaust with higher Pt loadings lowering light‐off temperatures. Scaled up 90 g/ft3 catalyst in a 5 kg roaster achieved 96% CO and around 78% VOC conversion at 350°C, highlighting stable operation requires flue gas temperatures ≥350°C.
Till Hauswald, Kalle Weidauer, Christoph Hahn, Sven Kureti   +3 more
wiley   +1 more source

Comparative Study of Gas and Liquid Flow in Packed Beds Using Phase‐Contrast MRI

Chemie Ingenieur Technik, EarlyView.
This work presents applications of phase‐contrast magnetic resonance imaging (MRI) to investigate fluid flow fields and temperature in packed beds. Comparison of ethane (C2H6) gas flow with that of water flow is done at similar flow conditions. The temperature of water is also measured using MRI.
Maitreyi Sangal, Maria Anikeeva, Frank Godenschweger, Jan‐Bernd Hövener, Oliver Speck   +4 more
wiley   +1 more source

Harnessing machine learning and optimization for informed chemical engineering decisions: A styrene reactor analysis

The Canadian Journal of Chemical Engineering, EarlyView.
This study shows that integrating multiple machine learning models with optimization and decision‐making improves chemical process design, and that a consensus‐based strategy across models provides more robust and reliable operating recommendations than any single model, especially under limited or noisy data conditions.
Farough Agin, Clémence Fauteux‐Lefebvre, Jules Thibault   +2 more
wiley   +1 more source

Resource‐Efficient Electrodes with Metallized Woven‐Glass‐Grid Current Collectors for Lithium‐Ion Batteries

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
The use of metallized glass‐based woven‐grids instead of metal foils as current collectors for LIBs leads to a significant reduction in metal usage by over 90 % and weight savings of more than 80 %, resulting in an 11 % increase in specific energy at the cell level. Abstract A novel class of resource‐efficient, woven‐glass‐grid current collectors (CCs)
Yen‐Ming Li, Mohammadjafar Momeni, Huy Nguyen Dang Duc, Suvi von Bahder, Friedrich Roth, Wolfram Münchgesang, Manfred Danziger, Winfried Voitus, Dominik Nuss, Cornelia Sennewald, Tilmann Leisegang   +10 more
wiley   +1 more source

Zebrafish ventral gastrula fate map reveals neural crest progenitor domain

Developmental Dynamics, EarlyView.
Abstract Background Fate maps relate progenitor cell positions to later fates and locations of their progeny, revealing early embryonic organization. Previous zebrafish fate maps identified the origin of germ layers and derivative cell fates, but ventral gastrula progenitor domains were not fully resolved. In particular, the neural crest, a multipotent
Elaine E. Kushkowski, Victoria E. Prince
wiley   +1 more source

Circular and Bio‐Sourced Polymers for Energy Applications: Natural Feedstocks, Recycling, and Upcycling Routes

EcoEnergy, EarlyView.
This review provides a critical comparative analysis of circular and bio‐sourced polymers for energy storage, systematically evaluating natural feedstocks alongside recycling and upcycling strategies for battery components. Key structure–property–performance relationships and inherent trade‐offs between sustainability metrics and electrochemical ...
Priyank Sinha, Amul Jain, Koushik Mahata, Sanjib Banerjee   +3 more
wiley   +1 more source

Nickel‐Catalyzed LiF‐Rich Interface for Silicon Anodes

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Modulating the decomposition of F‐containing species in the electrolyte to form LiF‐rich SEI has been proven to be an effective strategy for interface optimization. Herein, through nickel‐catalyzed pyrolysis of carbon precursors on silicon, graphene‐like carbon was formed to construct three‐dimensional conductive networks.
Haoqi Li, Ming Li, Xiaorui Chen, Jingjing Wang, Mengxin Bai, Xuan Yang, Xingchi Zou, Hao Li, Guiqiang Cao, Bo Sun, Jiaxu Yang, Wenyu Liu, Junqi Zhang, Xifei Li   +13 more
wiley   +1 more source