A Practical, Two-Step Synthesis of 2-Substituted 1,3-Butadienes
, 2016 A two-step procedure for preparing 2-alkyl-1,3-butadienes is described. Cuprate addition to commercially available 1,4-dibromo-2-butene yields 3-alkyl-4-bromo-1-butene, a product of SN2′ substitution.
Scott McN. Sieburth (1538176) +2 more
core +1 more source
Synthesis and characterization of 1-amino-4-methylthio-2-nitro-1,3-butadienes
, 1997 Treatment of 3-nitrothiophene with prim. and sec. amines, followed by S-methylation leads to (Z,Z)-1- amino-4-methylthio-2-nitro-1,3-butadienes (3). Oxidation of these with LTA yields a mixture of the 2-methylthio-4-nitropyrroles (6) and the acetoxylated
Kumaran, Govindaraj +4 more
core +1 more source
Ruthenium-Catalyzed Silylation of 1,3-Butadienes with Vinylsilanes
, 2015 A novel method for the synthesis of 1-silyl-substituted 1,3-butadienes, based on [RuHCl(CO)(PCy3)2]-catalyzed silylative coupling of terminal (E)-1,3-dienes with vinylsilanes, is reported. The reaction provides a facile and straightforward access to (E,
Maciej Kubicki (832465) +4 more
core +1 more source
β-Silyl Carbonyl Groups as New Photodegradation Units in Poly(butadienes)
, 2016 β-Silyl Carbonyl Groups as New Photodegradation Units in Poly ...
Ke Yung King (2716333) +2 more
core +1 more source
Evidence for a Retro-Diels−Alder Reaction on a Single Crystalline Surface: Butadienes on Ge(100)
, 2016 Evidence for a Retro-Diels−Alder Reaction on a Single Crystalline Surface: Butadienes on Ge ...
Stacey F. Bent (1291512) +3 more
core +1 more source
Stereospecific synthesis of - and -1 alkoxy-1,3-butadienes
, 1984 A stereospecific, highly efficient, generally applicable synthesis of - and -1-alkoxy-1,3-butadienes involving dehydrative decarboxylations of 4,5-unsaturated-2-alkoxy-3-hydroxy-carboxylic acids is described.Peer Reviewedhttp://deepblue.lib.umich.edu ...
Masato Koreeda +3 more
core +1 more source
Journal of Applied Polymer Science, EarlyView.Zn/Al‐NO3 layered double hydroxide offers a low‐zinc alternative for sulfur vulcanization of nitrile rubber, reducing nominal zinc loading by an estimated 71%. Its potential as a vulcanization activator depends on the curing system: conventional curing preserves tensile strength despite slower kinetics, whereas efficient curing maintains comparable ...
Lucas Castro Roza de Faria +8 more
wiley +1 more source
A highly stereoselective synthesis of substituted butadienes and conjugated polyenes
, 1992 A highly stereoselective synthesis of 1,3-butadienes and its higher enyl analogs has been developed through thermal dehydrative ring opening of cyclopropyl carbinols in ...
Ila, Hiriyakkanavar +2 more
core +1 more source
Synthesis of functionalized diaryl sulfides by cyclocondensation of 3-arylthio-1-silyloxy-1,3-butadienes with 1,1,3,3-tetramethoxypropane, dimethyl allene-1,3-dicarboxylate, 1,1-bis(methylthio)-1-en-3-ones and 3-oxo-orthoesters [PDF]
, 2009 This dissertation is concerned with the development of synthesis of functionalized diarylsulfides. The first chapter contains the synthesis of novel 3-arylthio-1-silyloxy-1,3-butadienes in two steps.
Imran, Muhammad (gnd: 138810885)
core +1 more source
Glyoxylic‐Acetal‐Based Gel‐Polymer Electrolytes for Lithium‐Ion Batteries
Batteries &Supercaps, Volume 8, Issue 3, March 2025.A safe electrolyte based on tetraethoxyglyoxal (LE) is combined with a methacrylate polymer matrix. The resulting gel‐polymer electrolyte (GPE) exhibits an increased flash point, suitable ionic conductivity, and a stable performance in lithium‐ion battery cells.
Christian Leibing +4 more
wiley +1 more source