Nickel‐Catalyzed LiF‐Rich Interface for Silicon Anodes
ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.Modulating the decomposition of F‐containing species in the electrolyte to form LiF‐rich SEI has been proven to be an effective strategy for interface optimization. Herein, through nickel‐catalyzed pyrolysis of carbon precursors on silicon, graphene‐like carbon was formed to construct three‐dimensional conductive networks.
Haoqi Li +13 more
wiley +1 more source
Masked Silylenes: Controlled Generation and Reactivity Under Thermal and Equilibrium Conditions
European Journal of Inorganic Chemistry, EarlyView.This Review provides an overview of masked silylenes as bench‐stable precursors that release silylenes (R2Si:) under thermal activation or reversible equilibria. Precursor preparation, generation pathways, and characteristic reactivity are summarized, including trapping chemistry, reversible interconversions, insertion‐type processes, and small ...
Kei Ota, Kanata Miyahara, Norio Nakata
wiley +1 more source
Highly efficient synthesis of 3,4-diarylbutadiene sulfones using Heck-Matsuda reaction. [PDF]
RSC Adv, 2022 Shurupova OV +4 more
europepmc +1 more source
Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application
European Journal of Organic Chemistry, EarlyView.Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley +1 more source
1,2‐Diazetidines − Structure, Synthesis, and Functionalization
European Journal of Organic Chemistry, EarlyView.1,2‐Diazetidines are saturated four‐membered heterocycles featuring two adjacent nitrogen atoms. Despite recent advances in their synthesis and promising potential in medicinal chemistry, the chemistry of these cyclic hydrazines remains underexplored.
Stefan Roesner
wiley +1 more source
Hetero-Diels-Alder reactions of N-phosphoryltrihaloacetimidoyl chlorides with 1,3-butadienes
ARKIVOC, 2012 Mykola V. Kolotylo +2 more
doaj +1 more source
Structural design and 3D printing of flexible integrated electronic systems
FlexMat, EarlyView.This review provides a comprehensive overview of design and integration strategies for individual components in flexible electronics, highlights the 3D‐printing fabrication techniques, and discusses recent advances in system‐level integration and their applications in real‐time monitoring and intelligent robotics.
Jiani Gong +8 more
wiley +1 more source
Gold(I)-Catalyzed Intermolecular Reactions of Alkynes with Carbon Nucleophiles: What We Knowand What We Don't. [PDF]
ACS CatalRodrigalvarez J +3 more
europepmc +1 more source
InfoMat, EarlyView.This work constructs a series of graphite anodes with systematically varied binder distribution, porosity, and electrode thickness to resolve the role of microstructural heterogeneity during fast charging. The digital twin framework reveals how phase‐level structural gradients govern Li plating, SEI formation, and diffusion‐induced stresses, providing ...
Yejin Kang +4 more
wiley +1 more source
SmI<sub>2</sub>/Sm-Induced Reductive Silacyclization of Alkene/Diene Derivatives Using Dichlorosilanes or 1,2-Dichlorodisilanes via Reductive Radical-Polar Crossover. [PDF]
ChemistryChen Z +7 more
europepmc +1 more source