Results 11 to 20 of about 58,617 (322)
A new synthetic procedure for obtaining two previously reported donor-acceptor butadiene dyes, namely 5-(3,3-bis(4-methoxyphenyl)allylidene)-1,3-diethyl-2-thioxodihydropyrimidine-4,6(1H,5H)-dione and 5-(3,3-bis(4-(dimethylamino)phenyl)allylidene)-1,3 ...
Javier Francos, Victorio Cadierno
doaj +1 more source
Butadiene or styrene or butadiene and styrene or else? [PDF]
Commentary on the paper by Sathiakumar et al ( Occup Environ Med , December 2005)* In the December 2005 issue of this journal, Sathiakumar and colleagues1 report on the extended follow up of the University of Alabama cohort in the styrene–butadiene–rubber industry.
K, Straif, R, Baan, V, Cogliano
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β-Hydrazonophosphine oxides are precursors of useful organophosphorus compounds, including phosphorylated N-heterocycles, α-aminophosphonates, and vinylphosphonates.
Alexandr O. Kokuev +1 more
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A systematic study of the Diels–Alder reaction of α-nitrocinnamate was performed. The reaction of p-substituted α-nitrocinnamate with 2,3-dimethyl-1,3-butadienes smoothly proceeded regardless of the p-substituent, which was either an electron-donating or
Takumi Hamada +2 more
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Copper-Catalyzed Reaction of 2,3-Allenols with Silylzinc Reagents: Access to 2‑Silyl-1,3-butadienes
Reaction of 2,3-allenols with PhMe2SiZnCl or Ph2MeSiZnCl under catalysis of IPrCuCl or SIPrCuCl was carried out, affording 2-silyl-1,3-butadienes. Secondary and tertiary 2,3-allenols could be used as coupling partners.
Yu-Tong Duan (13993213) +2 more
core +1 more source
NHeterocyclic Carbene Stabilized 1Bora-1,3-butadienes
Deprotonation of [(NHC)(Fmes)B-allyl]+ borenium cations (NHC, IMes (a) or IMe2 (b); Fmes, 2,4,6-(CF3)3C6H2) provides an easy entry to the NHC-stabilized 1-bora-1,3-butadienes. They feature a planar s-trans-conformation just like 1,3-butadiene.
Gerhard Erker +7 more
core +1 more source
In vitro and in vivo mutagenicity of the butadiene metabolites butadiene diolepoxide, butadiene monoepoxide and diepoxybutane [PDF]
Three metabolites of 1,3-butadiene, namely butadiene diolepoxide, butadiene monoepoxide and diepoxybutane, were tested in the bacterial mutation assay using Salmonella typhimurium strain TA100 with and without metabolic activation (S9 mix). All three compounds showed a mutagenic response. The bifunctional epoxide was more effective than the diolepoxide
I D, Adler +3 more
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The barrier to internal rotation around the central C2–C3 single bond of a series of (1E)-monosubstituted 1,3-butadienes and (1E,3E)-1-Y-4-X-disubstituted butadienes, with Y=NH2 or OCH3 and X=NO2, CHO, COOH, CN, CF3, Cl or F, were studied at the density ...
Ali Hussain Yateem
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Carcinogenicity of 1,3-Butadiene
1,3-Butadiene, a high-production volume chemical used largely in the manufacture of synthetic rubber, is a multiple organ carcinogen in rats and mice. In inhalation studies conducted in mice by the National Toxicology Program, high rates of early lethal lymphomas occurring at exposure levels of 625 ppm or higher reduced the development and expression ...
R L, Melnick, C C, Shackelford, J, Huff
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A summary of the investigation and applications of the inverse electron demand Diels—Alder reaction is provided that have been conducted in our laboratory over a period that now spans more than 35 years.
Jiajun Zhang, Vyom Shukla, D. Boger
semanticscholar +1 more source

