Results 11 to 20 of about 58,617 (322)

One-Pot Synthesis of Push–Pull Butadienes from 1,3-Diethyl-2-thiobarbituric Acid and Propargylic Alcohols

open access: yesMolbank, 2022
A new synthetic procedure for obtaining two previously reported donor-acceptor butadiene dyes, namely 5-(3,3-bis(4-methoxyphenyl)allylidene)-1,3-diethyl-2-thioxodihydropyrimidine-4,6(1H,5H)-dione and 5-(3,3-bis(4-(dimethylamino)phenyl)allylidene)-1,3 ...
Javier Francos, Victorio Cadierno
doaj   +1 more source

Butadiene or styrene or butadiene and styrene or else? [PDF]

open access: yesOccupational and Environmental Medicine, 2006
Commentary on the paper by Sathiakumar et al ( Occup Environ Med , December 2005)* In the December 2005 issue of this journal, Sathiakumar and colleagues1 report on the extended follow up of the University of Alabama cohort in the styrene–butadiene–rubber industry.
K, Straif, R, Baan, V, Cogliano
openaire   +2 more sources

Michael addition of P-nucleophiles to azoalkenes provides simple access to phosphine oxides bearing an alkylhydrazone moiety

open access: yesFrontiers in Chemistry, 2023
β-Hydrazonophosphine oxides are precursors of useful organophosphorus compounds, including phosphorylated N-heterocycles, α-aminophosphonates, and vinylphosphonates.
Alexandr O. Kokuev   +1 more
doaj   +1 more source

Synthesis and Characterization of Multiple Functionalized Cyclohexanone Using Diels–Alder Reaction of α-Nitrocinnamate

open access: yesReactions, 2022
A systematic study of the Diels–Alder reaction of α-nitrocinnamate was performed. The reaction of p-substituted α-nitrocinnamate with 2,3-dimethyl-1,3-butadienes smoothly proceeded regardless of the p-substituent, which was either an electron-donating or
Takumi Hamada   +2 more
doaj   +1 more source

Copper-Catalyzed Reaction of 2,3-Allenols with Silylzinc Reagents: Access to 2‑Silyl-1,3-butadienes

open access: yes, 2022
Reaction of 2,3-allenols with PhMe2SiZnCl or Ph2MeSiZnCl under catalysis of IPrCuCl or SIPrCuCl was carried out, affording 2-silyl-1,3-butadienes. Secondary and tertiary 2,3-allenols could be used as coupling partners.
Yu-Tong Duan (13993213)   +2 more
core   +1 more source

NHeterocyclic Carbene Stabilized 1Bora-1,3-butadienes

open access: yes, 2021
Deprotonation of [(NHC)­(Fmes)­B-allyl]+ borenium cations (NHC, IMes (a) or IMe2 (b); Fmes, 2,4,6-(CF3)3C6H2) provides an easy entry to the NHC-stabilized 1-bora-1,3-butadienes. They feature a planar s-trans-conformation just like 1,3-butadiene.
Gerhard Erker   +7 more
core   +1 more source

In vitro and in vivo mutagenicity of the butadiene metabolites butadiene diolepoxide, butadiene monoepoxide and diepoxybutane [PDF]

open access: yesMutagenesis, 1997
Three metabolites of 1,3-butadiene, namely butadiene diolepoxide, butadiene monoepoxide and diepoxybutane, were tested in the bacterial mutation assay using Salmonella typhimurium strain TA100 with and without metabolic activation (S9 mix). All three compounds showed a mutagenic response. The bifunctional epoxide was more effective than the diolepoxide
I D, Adler   +3 more
openaire   +2 more sources

Rotational Barrier and Conjugation: Theoretical Study of Resonance Stabilization of Various Substituents for the Donors NH2 and OCH3 in Substituted 1,3-Butadienes

open access: yesIndonesian Journal of Chemistry, 2019
The barrier to internal rotation around the central C2–C3 single bond of a series of (1E)-monosubstituted 1,3-butadienes and (1E,3E)-1-Y-4-X-disubstituted butadienes, with Y=NH2 or OCH3 and X=NO2, CHO, COOH, CN, CF3, Cl or F, were studied at the density ...
Ali Hussain Yateem
doaj   +1 more source

Carcinogenicity of 1,3-Butadiene

open access: yesEnvironmental Health Perspectives, 1992
1,3-Butadiene, a high-production volume chemical used largely in the manufacture of synthetic rubber, is a multiple organ carcinogen in rats and mice. In inhalation studies conducted in mice by the National Toxicology Program, high rates of early lethal lymphomas occurring at exposure levels of 625 ppm or higher reduced the development and expression ...
R L, Melnick, C C, Shackelford, J, Huff
openaire   +3 more sources

Inverse Electron Demand Diels—Alder Reactions of Heterocyclic Azadienes, 1‑Aza-1,3-Butadienes, Cyclopropenone Ketals, and Related Systems. A Retrospective

open access: yesJournal of Organic Chemistry, 2019
A summary of the investigation and applications of the inverse electron demand Diels—Alder reaction is provided that have been conducted in our laboratory over a period that now spans more than 35 years.
Jiajun Zhang, Vyom Shukla, D. Boger
semanticscholar   +1 more source

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