Results 11 to 20 of about 3,857 (276)
Enantioselective and Regioselective Copper-Catalyzed Borocyanation of 1-Aryl-1,3-Butadienes [PDF]
, 2019 A multicomponent copper-catalyzed enantio- and regioselective borocyanation of 1-aryl-1,3-butadienes has been developed. The method provides access to functionalized allylic nitriles in up to 90% yield and 94% ee and thus overcomes some of the long ...
MJ Smith (7801685) +4 more
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Copper-Catalyzed Reaction of 2,3-Allenols with Silylzinc Reagents: Access to 2‑Silyl-1,3-butadienes
, 2022 Reaction of 2,3-allenols with PhMe2SiZnCl or Ph2MeSiZnCl under catalysis of IPrCuCl or SIPrCuCl was carried out, affording 2-silyl-1,3-butadienes. Secondary and tertiary 2,3-allenols could be used as coupling partners.
Yu-Tong Duan (13993213) +2 more
core +1 more source
Triazolopyridines 21.1 The stereochemistry of 1-[1,2,3]triazolo[1,5-a] pyridin-7-yl-4-(2H-[1,2,3]triazol-4-yl)-1,3-butadienes and triazolo ring opening derivatives [PDF]
ARKIVOC, 2002 The synthesis and NMR study of the geometry of 1-[1,2,3]triazolo[1,5-a]pyridin-7-yl-4-(2H- [1,2,3]triazol-4-yl)-1,3-butadienes 1a, 1b, 5 and of new 1-(6-substituted-2-pyridyl)-4-(2H- [1,2,3]triazol-4-yl)-1,3-butadienes 8-10 is reported.
Belén Abarca +2 more
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Carcinogenicity of 1,3-Butadiene
Environmental Health Perspectives, 1992 1,3-Butadiene, a high-production volume chemical used largely in the manufacture of synthetic rubber, is a multiple organ carcinogen in rats and mice. In inhalation studies conducted in mice by the National Toxicology Program, high rates of early lethal lymphomas occurring at exposure levels of 625 ppm or higher reduced the development and expression ...
R L, Melnick, C C, Shackelford, J, Huff
openaire +3 more sources
Beilstein Journal of Organic Chemistry, 2010 Some novel annulated pyrido[2,3-d]pyrimidines 6 and 7 were synthesized stereoselectively by intramolecular hetero Diels–Alder reactions involving 1-oxa-1,3-butadienes.
Mohit L. Deb, Pulak J. Bhuyan
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Thermal Decomposition of Vicinal Dinitroalkanes
CHIMIA, 1988 Three sym-tetraalkyl-dinitroethanes 1-3 have been decomposed in solution at 180 to 215 °C. The alkylated 1,3-butadienes 10,12, and 13 are formed by elemination of HNO2.
Katharina Fritzsche +2 more
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Beilstein Journal of Organic Chemistry, 2018 In strong Brønsted acids (CF3SO3H, FSO3H, D2SO4), (arysulfonyl)allenes (ArSO2–CR1=C=CR2R3) and (arylsulfinyl)allenes (ArSO–CR1=C=CR2R3) undergo cyclization into the corresponding stable 1,2-oxathiolium ions, which were studied by means of NMR and DFT ...
Stanislav V. Lozovskiy +3 more
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Arylthio-substituierte Nitrilylide aus der Thermolyse von 4-Arylthio-3-oxazolin-5-onen
CHIMIA, 1984 Thermolysis of 4-arylthio- and 4-benzylthio-3-oxazolin-5-ones leads to arylthio- and benzylthio-substituted nitrile ylides, which undergo 1,3-dipolar cycloadditions with reactive dipolarophiles to give 5-membered aza-heterocycles (Schemes 1 and 2).
Peter Wipf, Heinz Heimgartner
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(E)-1,1,1-Trifluoro-6,6-bis(4-methoxyphenyl)hexa-3,5-dien-2-one
Molbank, 2020 The title compound was obtained in high yield (84%) via the deacetylation of 3-(3,3-bis(4-methoxyphenyl)allylidene)-1,1,1,5,5,5-hexafluoro-2,4-pentanedione with K2CO3 in refluxing methanol. This previously unreported compound has been fully characterized
Victorio Cadierno
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Synthesis of 6-Nitroderivatives of Oxazolo[3,2-a]-pyridines and Their Reactions with Nucleophiles
Molecules, 2003 5-Nitro-2-pyridone can be selectively N-phenacylated, and the resulting phenacylpyridones I undergo cyclization to 6-nitrooxazolo[3,2-a]pyridinium salts II.
Eugene V. Babaev, Alexander A. Bush
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