Miniature β-Hairpin Mimetic by Intramolecular Hydrogen Bond and C-H···π Interactions. [PDF]
ACS Omega, 2022 Canonically, protein β-hairpin motifs are stabilized by intramolecular hydrogen bonds. Here, we attempt to develop a rational design recipe for a miniature hairpin structure stabilized by hydrogen bonding as well as C–H···π interaction and try to ...
Nandi SK +4 more
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Weak interactions but potent effect: tunable mechanoluminescence by adjusting intermolecular C-H···π interactions. [PDF]
Chem Sci, 2018 This study provides a reliable strategy to tune the mechanoluminescent colors by adjusting the weak intermolecular interactions.
Xie Z +9 more
europepmc +4 more sources
Fullerene Complexation in a Hydrogen-Bonded Porphyrin Receptor via Induced-Fit: Cooperative Action of Tautomerization and C-H···π Interactions. [PDF]
J Am Chem Soc, 2023 A supramolecular chiral hydrogen-bonded tetrameric aggregate possessing a large cavity and tetraarylporphyrin substituents was assembled using alternating 4H- and 2H-bonds between ureidopyrimidinone and isocytosine units, respectively.
Jozeliu Naitė A +9 more
europepmc +2 more sources
A Catalytic Role for C-H/π Interactions in Base Excision Repair by Bacillus cereus DNA Glycosylase AlkD. [PDF]
J Am Chem Soc, 2016 DNA glycosylases protect genomic integrity by locating and excising aberrant nucleobases. Substrate recognition and excision usually take place in an extrahelical conformation, which is often stabilized by π-stacking interactions between the lesion ...
Parsons ZD +3 more
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Hydrogen bonding patterns and C-H...π interactions in the structure of the antiparkinsonian drug (R)-rasagiline mesylate determined using laboratory and synchrotron X-ray powder diffraction data. [PDF]
Acta Crystallogr B Struct Sci Cryst Eng Mater, 2023 Dugarte-Dugarte AJ +7 more
europepmc +3 more sources
Intramolecular C−H···π Interactions in Metal-Porphyrin Complexes [PDF]
, 2004 Cambridge Structural Database (CSD) was screened in order to find intramolecular C−H···π interactions with a chelate ring of coordinated porphyrin. It was found 154 crystal structures with 244 intramolecular C−H···π interactions in transition metal ...
Goran A. Bogdanović +3 more
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Crystal structure of 4-(anthracen-9-yl)pyridine
Acta Crystallographica Section E: Crystallographic Communications, 2021 The title compound, C19H13N, which crystallizes in the monoclinic C2/c space group with one half-molecule in the asymmetric unit, was synthesized by Suzuki–Miyaura cross-coupling reaction of 9-bromoanthracene with pyridin-4-ylboronic acid and purified by
Meng Zhao +5 more
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Molecules, 2023 The dynamic and static nature of the XH-∗-π and YX-∗-π (X = F, Cl, Br, and I; Y = X and F) interactions in the distorted π-system of corannulene (π(C20H10)) is elucidated with a QTAIM dual functional analysis (QTAIM-DFA), where asterisks emphasize the ...
Satoko Hayashi +3 more
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Acta Crystallographica Section E: Crystallographic Communications, 2021 In the title compound, C14H7Cl4FN2, the dihedral angle between the 4-fluorophenyl ring and the 2,4-dichlorophenyl ring is 46.03 (19)°. In the crystal, the molecules are linked by C—H...N interactions along the a-axis direction, forming a C(6) chain.
Namiq Q. Shikhaliyev +6 more
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