Acta Crystallographica Section E: Crystallographic Communications, 2022 The central tetrahydropyridine ring of the title compound, C19H17N3O2, adopts a screw-boat conformation. In the crystal, strong C—H...O and N—H...N hydrogen bonds form dimers with R22(14) and R22(12) ring motifs, respectively, between consecutive ...
Khammed A. Asadov +6 more
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Crystal engineering via C-H...F and C-H...[π] interactions in two substituted indoles [PDF]
, 2004 The crystal structures of 1-(4-fluorophenyl)-2-phenyl-4,5,6,7-tetrahydro-1H-indole, C20H18FN, and 1-(4-fluorophenyl)-6,6-dimethyl-2-phenyl-4,5,6,7-tetrahydro-1H-indole, C22H22FN, have been determined in order to study the role of `organic fluorine' in ...
Choudhury, A. R. +2 more
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Insights into Thiol–Aromatic Interactions: A Stereoelectronic Basis for S–H/π Interactions [PDF]
, 2017 Thiols can engage favorably with aromatic rings in S–H/π interactions, within abiological systems and within proteins. However, the underlying bases for S–H/π interactions are not well understood.
Sudipta K. Sinha (3699772) +6 more
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Anion Binding to Resorcinarene-Based Cavitands: The Importance of C–H•••Anion Interactions [PDF]
, 2008 Anions rather than cations: While resorcinarenes bind cations through cation-π interactions, methylene-bridged cavitands surprisingly bind anions through C-H⋯anion interactions with the acetal protons at the wider rim (see model of the complex in the ...
S. S. ZHU +17 more
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Coordination polymers utilizing N-oxide functionalised host ligands [PDF]
, 2012 Pyridyl functionalized host molecules are oxidized to their N-oxide analogues and form a series of coordination polymers and discrete complexes with transition metal cations.
Hardie, Michaele J. +11 more
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Crystal structure of 1-methoxypyrene
Acta Crystallographica Section E: Crystallographic Communications, 2015 The title compound, C17H12O, crystallized with three independent molecules (A, B and C) in the asymmetric unit. In the crystal, the three independent molecules are linked by π–π interactions [centroid–centroid distances = 3.551 (3)–3.977 (2) Å], which ...
Eric G. Morales-Espinoza +4 more
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Structural variability of Ag(I) metal–organic networks: C–H⋯π and metal⋯π interactions [PDF]
, 2016 The synthesis and X-ray structural characterization of two silver(I) coordination polymers, [Ag2(bpp)2(Phdac)]·5H2O (1) and [Ag2(bpp)(HSSal)] (2), are reported, where bpp = 4,4′-trimethylene dipyridine, H2Phdac = 1,4-phenylenediacetic acid, and H3SSal ...
Debdoot Hazari (840247) +4 more
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Crystal structure of 2-(3-bromophenyl)-1,3-dithiane
Acta Crystallographica Section E: Crystallographic Communications, 2015 In the title compound, C10H11BrS2, the 1,3-dithiane ring has a chair conformation with the 1,4-disposed C atoms being above and below the remaining four atoms. The bromobenzene ring occupies an equatorial position and forms a dihedral angle of 86.38 (12)°
Julio Zukerman-Schpector +4 more
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Crystal structures of 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile exhibit different intermolecular π-stacking, C—H...Nnitrile and C—H...Npyridine interactions [PDF]
, 2015 The two title compounds are isomers of C6H3ClN2 containing a pyridine ring, a nitrile group, and a chloro substituent. The molecules of each compound pack together in the solid state with offset face-to-face π-stacking, and intermolecular C—H...Nnitrile ...
Thomas J. O'Connor +2 more
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Crystal structure of 10-ethyl-7-(9-ethyl-9H-carbazol-3-yl)-10H-phenothiazine-3-carbaldehyde
Acta Crystallographica Section E: Crystallographic Communications, 2017 The title compound, C29H24N2OS, contains a phenothiazine moiety linked to a planar carbazole unit (r.m.s. deviation = 0.029 Å) by a C—C single bond. The phenothiazine moiety possesses a typical non-planar butterfly structure with a fold angle of 27.36 (9)
Vairavan Mahalakshmi +4 more
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