Unexpected Formation of Neutral Alkyl-Ni(II) Complexes Bearing Unsymmetrical <i>C</i>,<i>N</i>,<i>N</i>'-Pincer Iminopyrrolyl Ligands via Intramolecular C-H Bond Activation: A Distinct Type of Single-Component Ethylene Polymerization Catalysts. [PDF]
Figueira CA +6 more
europepmc +1 more source
Enhanced C-H bond activation by tuning the local environment of surface lattice oxygen of MoO3. [PDF]
Jiang C +4 more
europepmc +1 more source
E2A selectively regulates TGF‐β–induced apoptosis in KRAS‐mutant non‐small cell lung cancer
Ability to induce apoptosis by TGF‐β is frequently lost in advanced lung adenocarcinoma despite intact TGF‐β signaling. We identify E2A as a mutant KRAS–dependent mediator of resistance to TGF‐β–induced apoptosis. TGF‐β induces E2A via SMAD3 in mutant KRAS cells, and E2A silencing restores apoptosis and enhances radiation response in cell lines ...
Sergei Chuikov +3 more
wiley +1 more source
Enhancing the high-spin reactivity in C-H bond activation by Iron (IV)-Oxo species: insights from paclitaxel hydroxylation by CYP2C8. [PDF]
Yue D, Hirao H.
europepmc +1 more source
Synergistic effects of CH3CO2H and Ca2+ on C-H bond activation by MnO4. [PDF]
Shi H +5 more
europepmc +1 more source
We analyze cisplatin–DNA adducts (CDAs) and double‐strand breaks (DSBs) in a cell‐cycle‐dependent manner. We find that CDAs form similarly across all cell cycle phases. DSBs arise only in S‐phase. CDAs might not directly impair DSB repair, but S‐phase DSB lesions evolve in the presence of CDAs and disrupt repair in G2, also causing radiosensitization ...
Ye Qiu +10 more
wiley +1 more source
Synergistic C-H bond activation across molybdenum-iridium multiply bonded complexes: a cascade of transformations. [PDF]
Dubrawski Z +5 more
europepmc +1 more source
Rethinking plastic waste: innovations in enzymatic breakdown of oil‐based polyesters and bioplastics
Plastic pollution remains a critical environmental challenge, and current mechanical and chemical recycling methods are insufficient to achieve a fully circular economy. This review highlights recent breakthroughs in the enzymatic depolymerization of both oil‐derived polyesters and bioplastics, including high‐throughput protein engineering, de novo ...
Elena Rosini +2 more
wiley +1 more source
Infrared Irradiation-Assisted Solvent-Free Pd-Catalyzed (Hetero)aryl-aryl Coupling via C-H Bond Activation. [PDF]
Albano G +5 more
europepmc +1 more source

