Development of a Late-Stage Functionalization Strategy to Access Diverse 3,5-Disubstituted 1,2,4-Thiadiazoles. [PDF]
Dobria A +3 more
europepmc +1 more source
Three‐Layer‐Structured Garnet‐Dominant Composite Solid Electrolyte for Solid‐State Batteries
The three‐layer‐structured garnet‐dominant composite solid electrolyte (GD‐CSE) is designed for solid‐state batteries. The GD‐CSE is composed of over 80 wt. % contents of LGLZO. This three‐layer CSE has high ionic conductivity and high potential stability.
Wooyoung Lee +13 more
wiley +1 more source
A Mg‐gradient polyacrylonitrile nanofiber (PAN@Mg) layer is introduced on the current collector. This 2‐μm‐thick layer regulates Li diffusion via the Coble creep mechanism, preventing direct Li–solid electrolyte contact. Its elasticity effectively mitigates stress, preserving interfacial integrity during cycling. This approach enables highly reversible
Jaeik Kim +14 more
wiley +1 more source
Crystal structure and Hirshfeld surface analysis of 1-(2-chloro-acet-yl)-3-methyl-2,6-bis-(4-methylphen-yl)piperidin-4-one. [PDF]
Divyabharathi S +3 more
europepmc +1 more source
Bis‐Dichlorosilyl Functionalized C4‐Cumulene With Unique Bonding Scenario
Herein, we report a silylene‐functionalized C4‐cumulene (2) and investigate its bonding scenario employing computational methods such as NBO analysis, AIM, and energy decomposition analysis‐natural orbital for chemical valence (EDA‐NOCV). The EDA‐NOCV analysis showed that compound 2 prefers to possess electron‐sharing covalent sigma and dative covalent
Saroj Kumar Kushvaha +10 more
wiley +1 more source
Syntheses and structures of <i>N</i>-(2-fluoro-phen-yl)-2-oxo-2<i>H</i>-chromene-3-carboxamide and <i>N</i>-[4-(methyl-sulfon-yl)phen-yl]-2-oxo-2<i>H</i>-chromene-3-carboxamide. [PDF]
Sunithakumari M +5 more
europepmc +1 more source
Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview
The graphical abstract summarizes the review “Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview”, highlighting representative Pd(II)‐catalyzed methods for the β‐arylation of α‐amino acids. Key mechanistic features, substrate diversity, and synthetic relevance of these transformations are showcased. Abstract Metal‐catalyzed C─
Davide Illuminati +4 more
wiley +1 more source
Synthesis, crystal structure and Hirshfeld surface analysis of bis-(2-amino-1,3,4-thia-diazol-3-ium) diaqua-dichlorido(propanedioato-κ<sup>2</sup> <i>O</i> <sup>1</sup>,<i>O</i> <sup>3</sup>)manganate(II). [PDF]
Nuralieva G +6 more
europepmc +1 more source
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve +4 more
wiley +1 more source
Multi-Level Uncinatectomies and Posterior Column Osteotomies to Correct a Cervical Kyphotic Deformity: Case Instruction With Intraoperative Picture and Video. [PDF]
Jain H +4 more
europepmc +1 more source

