Results 261 to 270 of about 539,727 (292)
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Dimethyl formamide solvates of CaCl2
Thermochimica Acta, 1981Abstract The water of hydration in inorganic salts plays a vital role in stabilising their crystal structures, as is evidenced by the fact that on dehydration the structures change radically. In order to understand further the role played by the solvent in the development of an ordered lattice, dimethyl formamide (DMF) solvates of inorganic salts ...
U.R.K. Rao +2 more
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Characterization of the CaCl2EuCl2 and CaCl2SrCl2 systems by X-ray powder diffraction
Journal of Solid State Chemistry, 1987The systems CaCl2SrCl2 and CaCl2EuCl2 were studied over the entire composition range by X-ray powder diffraction. The CaCl2XCl2 (X = Sr, Eu) systems behave similarly and exhibit two single-phase regions with corresponding adjacent two-phase regions. The first single-phase region exhibits the SrI2-type and the second the SrBr2-type structure.
Monika Olejak-Chodan, Harry A. Eick
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The Journal of Chemical Thermodynamics, 1986
Abstract Heat capacities and phase-transition enthalpies between 270 and 400 K have been measured for commercial samples of calcium chloride hexahydrate, tetrahydrate, and dihydrate, and ferric chloride hexahydrate, by adiabatic-shield calorimetry.
Knut K. Meisingset, Fredrik Grønvold
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Abstract Heat capacities and phase-transition enthalpies between 270 and 400 K have been measured for commercial samples of calcium chloride hexahydrate, tetrahydrate, and dihydrate, and ferric chloride hexahydrate, by adiabatic-shield calorimetry.
Knut K. Meisingset, Fredrik Grønvold
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Partition coefficient of CaCl2 in NaCl
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 19711. The concentration dependence of the equilibrium partition coefficient of CaCl2 in NaCl was determined. 2. Possible reasons are indicated for the jump-like change in the partition coefficient near the melting point of NaCl.
A. N. Kirgintsev +2 more
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Phase change stability of CaCl2·6H2O
Solar Energy, 1984Abstract A CaCl2·6H2O composition with a slight excess of water was found very stable on repeated phase change (over 1000 cycles) in a heat cycle test (35 ∼ 18°C), using vertical glass tubes of 950 mm height. The mole ratio of water CaCl 2 , n, was 6.11, less than that of the peritectic composition (n = 6.14).
Hiroshi Kimura, Junjiro Kai
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Thermal decomposition of Ca2SiO4·CaCl2
Cement and Concrete Research, 1971Abstract High-temperature microscopy, high-temperature X-ray diffraction, DTA and TGA indicated that synthetic Ca2SiO4·CaCl2 decomposes according to the reaction The direct development of ga′-Ca2SiO4 from structural relics of decomposed Ca2SiO4·CaCl2 is proposed.
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Solubility of Calcium in CaCl2-CaO
ECS Transactions, 2008The solubility of calcium in calcium chloride - calcium oxide is of interest in processes reducing metal oxides in calcium chloride based salt systems. The solubility of calcium in calcium chloride was measured as 2.7mol% at 1073K. This reduced to 0.4mol% at a calcium oxide content of 9.0mol%.
Stephen Shaw, Robert Watson
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Salt effect on vapor–liquid equilibria for binary systems of propanol/CaCl2 and butanol/CaCl2
Fluid Phase Equilibria, 2005Abstract The binary vapor–liquid equilibrium (VLE) data for salt-containing systems of 1-propanol/CaCl2, 2-propanol/CaCl2, 1-butanol/CaCl2 and 2-butanol/CaCl2 were determined and correlated. The UNIQUAC model was used to correlate the VLE data, and optimal parameters of the model were obtained.
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The MgCl2KClCaCl2 phase diagram
Thermochimica Acta, 1993Abstract The MgCl 2 KClCaCl 2 phase diagram has been determined using the method of thermal analysis. The liquidus system is a simple one with two eutectics at MgCl 2 (48 mol. %)—KCl (40 mol. %)—CaCl 2 (12 mol.%), m.p. 722 K; and MgCl 2 (35 mol.%)—KCl (63 mol.%)—CaCl 2 (2 mol. %), m.p. 700–725 K.
George S. Perry, Hayley Fletcher
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