Results 91 to 100 of about 1,147 (212)

Synthesis of Natural Carbazole Alkaloids: An Update

Natural Product Communications
Carbazoles alkaloids are tricyclic aromatic heterocyclic organic compounds, consisting of a central pyrrole ring fused with two benzene rings. Carbazole derivatives are an important class of nitrogen-containing heterocyclic compounds that are widely ...
Thi Chung Nguyen, Vo Cong Dung, Xuan Duc Dau   +2 more
doaj   +1 more source

High‐Energy‐Density Redox Flow Batteries: Mechanisms, Design Strategies, and Recent Progress

Chemistry – A European Journal, EarlyView.
ABSTRACT The inherent intermittency of energy sources such as solar and wind power hinders the transition to renewable energy, necessitating advanced energy storage solutions. Enhancing energy density is crucial for lowering system costs and enabling large‐scale deployment.
Xiaolian Zhao, Jiaxin Yu, Nannan Jia, Chuzhang Hong, Yue Luo, Wantong Jing, Zhiming Feng, Xinhua Liu, Rui Tan   +8 more
wiley   +1 more source

When Light Challenges Heat: Mechanistic Insights Into a Reaction Competing With Cadogan Cyclisation in Nitro‐Perylenediimides

Chemistry – A European Journal, EarlyView.
Visible‐light irradiation of nitro‐perylenediimide in the presence of triphenylphosphine reveals an unexpected pathway competing with the classical Cadogan cyclization. Mechanistic investigations uncover the rapid and selective formation of bay‐functionalized 1‐iminophosphorane‐12‐hydroxy perylenediimide derivatives.
Manuel Pedrón Laserna, Ilaria Ciofini, Piétrick Hudhomme   +2 more
wiley   +1 more source

Delayed room temperature phosphorescence enabled by phosphines

Nature Communications
Organic ultralong room-temperature phosphorescence (RTP) usually emerges instantly and immediately decays after excitation removal. Here we report a new delayed RTP that is postponed by dozens of milliseconds after excitation removal and decays in two ...
Guang Lu, Jing Tan, Hongxiang Wang, Yi Man, Shuo Chen, Jing Zhang, Chunbo Duan, Chunmiao Han, Hui Xu   +8 more
doaj   +1 more source

Green Electrochromic Film Formation via Phenylcarbazole Polymerization in Ionic Liquids

Chemistry – A European Journal, EarlyView.
The scheme depicts the three‐step electropolymerization of two electrochromic polycarbazole derivatives, 4‐(9H‐carbazol‐9‐yl)phenol and 4‐(3‐methoxy‐9H‐carbazol‐9‐yl)phenol, performed at constant potential using the green ionic liquid BMIM TFSI. This medium enables controlled polymer growth and enhances electrochromic performance, yielding robust and ...
Carolina Gascó, Sara Santiago, Rosa Maria Sebastián, Gonzalo Guirado   +3 more
wiley   +1 more source

Single‐Step Synthesis of Dithieno[3,2‐b:2′,3′‐e]Pyridines and Their Acid‐Dependent Optical and Photosensitising Properties

Chemistry – A European Journal, EarlyView.
The synthesis of dithieno[3,2‐b:2′,3′‐e]pyridines (DTPs) is herein reported, and their optical properties are studied both experimentally and computationally. Protonation or methylation of the nitrogen atom induced bathochromic shifts in their absorption and emission spectra.
Dominic Taylor, Matthew Wallace, Leonardo Amicosante, Gary S. Nichol, Scott J. Dalgarno, Filipe Vilela, Iain A. Wright, Neil B. McKeown   +7 more
wiley   +1 more source

Asymmetric Diphosphane Dioxides With A–π–A–π’–D Scaffolds for High‐Purity Deep‐Blue Luminescence

Chemistry – A European Journal, EarlyView.
Diphosphane dioxide‐based luminophores with donor–π–acceptor– π’–acceptor scaffold enable efficient deep‐blue emission from tunable charge‐transfer states affording high photoluminescence up to 95%. OLEDs reach EQE 4.9%, aided by triplet–triplet annihilation, highlighting a practical route to high‐performance blue emitters.
Eetu Hakkarainen, Zong‐Ying Liu, Jhon Sebastian Oviedo Ortiz, Nicolas Vanthuyne, Jeanne Crassous, Ondřej Mrózek, Fabien B. L. Cougnon, Wen‐Yi Hung, Pi‐Tai Chou, Igor O. Koshevoy, Andrey Belyaev   +10 more
wiley   +1 more source

Polycarbazole–NiOOH Interfacial Engineering of BiVO4 Photoanodes for Efficient and Stable Solar Water Splitting

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A π‐conjugated carbazole (p‐CBZ) layer is electro‐polymerized on BiVO4 to form a p–n heterojunction that enhances charge separation and suppresses surface recombination, while a NiOOH co‐catalyst accelerates oxygen evolution kinetics. The synergistic BVO/p‐CBZ/NiOOH photoanode delivers a high photocurrent density and long‐term stability for efficient ...
Lakshman Sundar Arumugam, Ana Gutierrez‐Blanco, Agustin O. Alvarez, Alejandro Saura Aviles, Mahesh Eledath‐Changarath, Rafael Abargues, Juan Francisco Sánchez‐Royo, Helena Rabelo, Maria Chiara Spadaro, Jordi Arbiol, Javier E. Durantini, Sixto Giménez   +11 more
wiley   +1 more source

Flexible Direct‐Conversion X‐Ray Detectors: From Emerging Materials to Conformal Imaging

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This comprehensive review analyzed the performance, challenges, and future directions of four emerging material systems for next‐generation flexible direct‐conversion X‐ray detectors: organic semiconductors, perovskites, metal–organic frameworks, and inorganic metal compounds.
Haipeng Di, Guoliang Ma, Jiaxin Mu, Kailian Dong, Haibin Li, Manjing Wang, Xin Song, Haojin Li, Jianwei Xu, Yiying Zhao, Jingjing Zhao, Guojia Fang   +11 more
wiley   +1 more source

A Co‐Self‐Assembled Monolayer With Enhanced Coverage and Defect Passivation for Efficient Inverted Perovskite Solar Cells

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This study achieved a co‐self‐assembled monolayer (Co‐SAM) with more uniform coverage on nickel oxide substrates and enhanced passivation of buried interfaces by incorporating 4PABCz into Me‐4PACz. Perovskite solar cells fabricated with this Co‐SAM achieved an efficiency of 26.33% and exhibited enhanced stability. The combination of nickel oxide (NiOx)
Zhiwei Deng, Xianyong Zhou, Kaixin Huang, Kai Yuan, Yuanwei Wang, Guo Ding, Chuanyi Huang, Bin Tian, Jinbo Chen, Binbin Yu, Hanjian Lai, Zhixin Liu, Lei Yan, Shi Chen, Wei Tang, Chang Liu, Xingzhu Wang   +16 more
wiley   +1 more source