Results 151 to 160 of about 288,749 (288)

Concerted Proton and Electron Transfer in Heterogeneous Electrocatalytic CO2 Reduction

open access: yesAngewandte Chemie, EarlyView.
Concerted proton‐electron transfer (CPET) enables CO2‐to‐CO conversion with significantly reduced energy cost compared to cation‐stabilized pathways. Under controlled mass transport of proton donors, CPET dominates at modest potentials. At higher overpotentials, a cation‐stabilized pathway is found to dominate.
Seonmyeong Noh   +3 more
wiley   +2 more sources

Advancements in Graphdiyne‐Based Multiscale Catalysts for Green Hydrogen Energy Conversion

open access: yesAdvanced Intelligent Discovery, EarlyView.
This review systematically explores the fundamental characteristics of graphdiyne (GDY), cutting‐edge field of GDY‐based multiscale catalysts within sustainable energy conversion systems.Special emphasis is placed on the structure‒property relationships in different reactions.
Qian Xiao, Lu Qi, Siao Chen, Yurui Xue
wiley   +1 more source

Serum PFAS in Aircraft Rescue and Firefighting (ARFF) Firefighters From Six U.S. Airport Fire Departments

open access: yesAmerican Journal of Industrial Medicine, EarlyView.
ABSTRACT Introduction Use of aqueous film‐forming foam (AFFF) is a source of exposure to per‐ and polyfluoroalkyl substances (PFAS) for firefighters working in aircraft rescue and firefighting (ARFF) settings. However, data characterizing the association between serum PFAS concentrations and exposure risk factors for ARFF firefighters are limited ...
Miriam M. Calkins   +19 more
wiley   +1 more source

Monitoring Redox Pathways and Performance Limitations in Lithium‐Sulfur Batteries Using In Situ 7/6Li and 33S NMR Spectroscopies

open access: yesAngewandte Chemie, EarlyView.
Lithium‐sulfur (Li‐S) batteries contain various NMR‐active nuclear isotopes, including 7Li, 6Li and 33S, which are sensitive to the different chemical reactions that occur during battery cycling. Herein, we use a combination of lithium and sulfur operando NMR spectroscopy to provide new insights at the molecular level, fundamental understanding being ...
Jana B. Fritzke   +7 more
wiley   +2 more sources

Chemical Metabolomics: Chemical Biology Tools for Advanced Metabolism Investigations

open access: yesAngewandte Chemie, EarlyView.
The human metabolism has been investigated for several millennia. The metabolome is known for a high complexity due to a large number of different metabolites that are present at different concentrations. Metabolomics has been developed as a field to investigate the entire human metabolome and to elucidate disease development mechanisms.
Alejandro Torregrosa‐Chinillach   +4 more
wiley   +2 more sources

Radical‐Based On‐Surface Transformation of Nonplanar Aromatics Into Nonbenzenoid Nanographenes

open access: yesAngewandte Chemie, EarlyView.
Formation of radicals in nonplanar hydrocarbons through thermally induced dehydrogenation leads to molecular transformation via intramolecular radical‐based cyclization and dimerization, leading to formation of nonbenzenoid nanographenes. ABSTRACT On‐surface synthesis has emerged as a powerful tool for atomically precise C─C bond formation, enabling ...
Daniel Rothhardt   +8 more
wiley   +2 more sources

Regioselective Synthesis of Benzylsilanols from Kobayashi‐Type Reagents via C(sp3)─H Bond Activating 1,4‐Palladium Migration

open access: yesAngewandte Chemie, EarlyView.
A Pd‐catalyzed regioselective synthesis of benzylsilanols from Kobayashi‐type reagents has been developed through a mechanistically distinct approach involving 1,4‐Pd migration followed by intramolecular transmetalation. The reaction can be combined with various prior transition‐metal‐catalyzed processes and the resulting benzylsilanols have been ...
Ryo Shintani, Keisuke Tachibana
wiley   +2 more sources

Volcanic forcing of the Lomagundi-Jatuli carbon isotope excursion. [PDF]

open access: yesProc Natl Acad Sci U S A
Blichert-Toft J   +6 more
europepmc   +1 more source

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