Results 141 to 150 of about 70,737 (245)

CO2 electroreduction favors carbon isotope 12C over 13C and facilitates isotope separation. [PDF]

open access: yesiScience, 2023
Barecka MH   +5 more
europepmc   +1 more source

A Wagner–Meerwein‐Like Rearrangement Generates a Vinyl Group in the Biosynthesis of the Polychlorinated Lipopeptides Fischerazoles

open access: yesAngewandte Chemie, EarlyView.
The fischerazoles, unusual cyanobacterial chlorinated lipopeptides are reported. During their biosynthesis, a linear fatty acyl‐acyl carrier protein (ACP) precursor is rearranged through the action of the S‐adenosyl‐methionine (SAM)‐dependent methyltransferase FshF, to generate a pendant vinyl group.
Sandra A. C. Figueiredo   +8 more
wiley   +2 more sources

Exclusive Hydroformylation of Terminal Olefins: A Phosphorus‐Free Ruthenium System for the Selective Functionalization of Complex Mixtures

open access: yesAngewandte Chemie, EarlyView.
Development of a phosphorus‐free Ru/DBU catalyst enabling highly chemo‐ and regioselective hydroformylation of terminal olefins, sparing internal double bonds. Optimization of reaction parameters, ligand effects, and substrate scope including industrial feedstocks was realized.
Mohamed Niyaz Vellala Syed Ali   +6 more
wiley   +2 more sources

A Synergistic Approach Combining Stable Carbon Isotope Ratio Analysis and Melissopalynology for the Authentication of Honey from Thailand. [PDF]

open access: yesFoods
Judprasong K   +12 more
europepmc   +1 more source

Rapid Access to Carbon-Isotope-Labeled Alkyl and Aryl Carboxylates Applying Palladacarboxylates. [PDF]

open access: yesJACS Au, 2023
Ton SJ   +6 more
europepmc   +1 more source

Coupled Fe3O4‐Cluster Precipitates and Single Fe‐Atom Catalysts Can Boost Oxygen Reduction via Concomitantly Accelerated Water Dissociation

open access: yesAngewandte Chemie, EarlyView.
Fe3O4 clusters can be precipitated onto Fe–N–C SACs through a residual‐oxygen‐assisted precipitation approach. Compelling evidence, including operando spectroscopy and ab initio calculations, suggests that Fe3O4‐cluster precipitates not only induce asymmetric electronic structures of Fe‐N4 active center to optimize the OH* adsorption, but also ...
Cheng‐Kai Du   +10 more
wiley   +2 more sources

Environmental changes and their effects on carbon isotope distribution in Lake Plateliai over the past 130 years: insights from sediment organic fractions and diatom assemblages. [PDF]

open access: yesPLoS One
Barisevičiūtė R   +9 more
europepmc   +1 more source

Spatio-Temporal Variations in Carbon Isotope Discrimination Predicted by the JULES Land Surface Model. [PDF]

open access: yesJ Geophys Res Biogeosci, 2022
Palmer L   +9 more
europepmc   +1 more source

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