Advanced Energy Materials, EarlyView.Ru─Ni nanoclusters are anchored on WC via a rapid microwave quasi‐solid‐state method to build an ordered flexible interfacial hydrogen bond network. This structure boosts water dissociation and enables barrier‐free H/OH transport via the Grotthuss mechanism, forming dual H‐to‐Ru and OH‐to‐Ni spillover pathways to overcome the key challenges of alkaline
Xiangrui Zhuge +8 more
wiley +1 more source
Carbon‐Confined Fe3C/Fe3N Janus Interfaces for Selective Nitric Oxide‐to‐Ammonia Electroreduction
Angewandte Chemie, EarlyView.A defect‐rich, graphitic‐carbon‐confined Fe3C/Fe3N Janus catalyst integrates NO transport, adsorption/activation, and interfacial H supply for efficient nitric oxide electroreduction to ammonia. Built from earth‐abundant elements, this architecture enables high‐yield and high‐efficiency NH3 synthesis while valorizing industrial NO emissions.
Jialing Song +10 more
wiley +2 more sources
Carbon Isotope Ratios as Biomarkers for Added Sugar Intake: Fundamental Limitations that Constrain Valid Application. [PDF]
J NutrLouie JCY.
europepmc +1 more source
A Large Scale Multi‐Modal Workflow for Battery Characterization: From Concept to Implementation
Advanced Energy Materials, EarlyView.Isolated characterization techniques produce independent datasets and single‐property insights. However, progressively more holistic interpretations of battery‐material behavior is needed in the future. Here we demonstrate a coordinated multimodal workflow enabling the correlation of heterogeneous datasets and the construction of multidimensional ...
François Cadiou +34 more
wiley +1 more source
Formation of Gallium Monofluoride in the Coordination Sphere of Nickel
Angewandte Chemie, EarlyView.The elusive gas‐phase species gallium monofluoride forms selectively in the coordination sphere of a nickel(II) centre as a product of C(sp3)–F bond activation, with a weakly coordinating anion as the fluorine source. The herein reported gallium monofluoride ligand acts as a very strong σ‐donor ligand at nickel and serves as a fluorine donor towards ...
Johannes Stephan +6 more
wiley +2 more sources
Carbon isotope effects in cometabolic oxidation of halogenated organics by a methanotroph. [PDF]
Environ Sci Pollut Res IntRauniyar P +3 more
europepmc +1 more source
Advanced Energy Materials, EarlyView.Aliovalent B‐site substitution with Sn2+ in lead‐free perovskite, Cs3Bi2Br9, is employed to simultaneously induce lattice contraction and bromine vacancy through charge imbalance and ionic radius mismatch. The resulting structural distortion modulates the electronic structure and improves charge separation, leading to enhanced visible‐light‐driven CO2 ...
Justin Khor +7 more
wiley +1 more source
Angewandte Chemie, EarlyView.Directional control within the secondary coordination sphere redefines CO2 reduction by iron porphyrins. Simply rearranging identical urea hydrogen‐bond donors modulates reactivity, revealing that optimal catalysis does not only arise from maximal intermediate stabilization, but also from directional, adaptive non‐covalent interactions that balance ...
Ashutosh Vishwakarma +7 more
wiley +2 more sources
Measurement of Stable Carbon Isotope Ratio of Volatile Organic Compounds Using Thermal Desorption-Gas Chromatography-Combustion-Isotope Ratio Mass Spectrometry. [PDF]
Int J Anal ChemYuhong L, Xihuang L, Cifu L, Xijie Y.
europepmc +1 more source
Insights into the biological control of the carbon isotope signatures of ancient aquatic organisms. [PDF]
Proc Natl Acad Sci U S A, 2023 Kranz SA.
europepmc +1 more source