Increasing nanocurvature effectively enriches the local electron density of the M–N4 motif, which facilitates electron transfer from the metal center to nitrogen atoms. This electronic behavior intensifies the localization and asymmetric distribution of charge, thereby significantly amplifying the dipole moment and polarizability.
Daohu Sheng +7 more
wiley +1 more source
Carbonyl emissions from heated tobacco products. [PDF]
Zervas E +3 more
europepmc +1 more source
Dysregulated TCA cycle contributes to Alzheimer's disease (AD) pathogenesis. Here, we show that microglial isocitrate dehydrogenase 1 (IDH1) is a critical driver. Elevated IDH1 disrupts citrate metabolism and mitochondrial function, exacerbating AD pathology.
Qianqian Li +13 more
wiley +1 more source
Gold-Catalyzed Carbonyl Release and its Adaptation for Prodrug Therapy Using Multivalent Lectin-Directed Artificial Metalloenzymes. [PDF]
Huang J +5 more
europepmc +1 more source
Inspired by spider silk, a bio‐inspired polyamide elastomer with a dynamic physical cross‐linking network is developed. Mimicking the rigid β‐sheet crystals and sacrificial hydrogen bonds of silk, the material achieves an exceptional balance of strength and toughness.
Bo Yang +12 more
wiley +1 more source
High Dietary Carbonyl Iron Reshapes the Gut Microbiome and Impairs Hepatic Insulin Sensitivity in a Time-Dependent Manner. [PDF]
Li Y +5 more
europepmc +1 more source
We developed a series of quinoxalinoquinoxaline (QQ) photosensitizers featuring high and tunable excited‐state reduction potentials (E(PC•+/PC*) = –1.76 to –2.05 V vs. SCE). Their hydrogen‐bonding interaction with carbonyl substrates enables selective single‐electron transfer events for selective nitrilization of 1° amides, offering a tunable ...
Seongwoo Bae, Dongwook Kim, Jinwoo Kim
wiley +1 more source
Diphosphine-Substituted Rhodium Carbonyl Clusters: Synthesis and Structural and Spectroscopic Characterization of the Heteroleptic Rh<sub>4</sub>(CO)<sub>8+2n</sub>(L)<sub>2-n</sub> (n = 0, 1) and {Rh<sub>4</sub>(CO)<sub>10</sub>L}<sub>2</sub> Monomeric and Dimeric Species. [PDF]
Scorzoni G +5 more
europepmc +1 more source
HMPA-Enabled Direct γ'-Arylation of Cyclic Vinylogous Esters. [PDF]
Li YX, Zhao WT, Wu YK.
europepmc +1 more source
Effect of Nucleating Agent on Crystallization of Poly[(<i>R</i>)‑3-hydroxybutyrate-<i>co</i>-(<i>R</i>)‑3-hydroxyhexanoate]. [PDF]
Fujita M, Ohta N, Yagi K, Abe H.
europepmc +1 more source

