Results 251 to 260 of about 552,882 (305)
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Carbonyl polyhedra in crystalline carbonyl clusters
Transition Metal Chemistry, 1992An attempt has been made to elucidate the low-energy modes of vibration of the icosahedral envelope of carbonyl ligands in the series of dodecacarbonyl clusters, Co4(CO)12, RhCo2(CO)12, Ir2Co2(CO)12, and Fe3(CO)12, from an examination of their crystalline structures. It was hoped that this approach would give additional evidence necessary for a clearer
Brian F. G. Johnson, Roderick Edmonds
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Binuclear Cyclopentadienylcobalt Carbonyls: Comparison with Binuclear Iron Carbonyls
Journal of the American Chemical Society, 2005The binuclear cyclopentadienylcobalt carbonyls Cp2Co2(CO)n (n = 3, 2, 1; Cp = eta5-C5H5) are studied by density functional theory using the B3LYP and BP86 functionals. The experimentally known monobridged isomer Cp2Co2(CO)2(mu-CO) and the tribridged isomer Cp2Co2(mu-CO)3 of Cp2Co2(CO)3 with formal Co-Co single bonds are found to be similar in energy ...
Hongyan, Wang +3 more
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Darmstadtium carbonyl and carbide resemble platinum carbonyl and carbide
Chem. Commun., 2004DsC and DsCO are calculated to be very similar to PtC and PtCO, suggesting that even the latest 6d elements resemble the corresponding 5d elements chemically.
Michael, Patzschke, Pekka, Pyykkö
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Alkylcobalt carbonyls. 8. (Chloromethyl)- and (chloroacetyl)cobalt carbonyls
Organometallics, 1987ClCH2C(O)Co(CO)4 (I) is prepd. by the reaction of ClCH2COCl with Na[Co(CO)4]. I readily decarbonylates to ClCH2Co(CO)4 (II). I is formed from II at .apprx.5 bar of CO pressure and room temp. or at 1 bar of CO by cooling to .apprx.-10 Deg in a reversible reaction.
Galamb, Vilmos +3 more
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α‐Thianthrenium Carbonyl Species: The Equivalent of an α‐Carbonyl Carbocation
Angewandte Chemie - International Edition, 2022Tobias Ritter
exaly
Radical Carbonyl Propargylation by Dual Catalysis
Angewandte Chemie - International Edition, 2021Huan-Ming Huang +2 more
exaly
Carbonyl force constants and carbonyl-carbonyl interaction constants of metal carbonyls
Inorganic Chemistry, 1968openaire +1 more source

