Results 11 to 20 of about 5,456,471 (384)

Carboxylic Acids as Adaptive Functional Groups in Metallaphotoredox Catalysis.

open access: yesAccounts of Chemical Research, 2022
ConspectusThe development of palladium-catalyzed cross-coupling methods for the activation of C(sp2)-Br bonds facilitated access to arene-rich molecules, enabling a concomitant increase in the prevalence of this structural motif in drug molecules in ...
Sebastian B. Beil   +3 more
semanticscholar   +1 more source

A review of anodic catalysts and their application in (non-)Kolbe electrocatalytic decarboxylation of carboxylic acids

open access: yesCarbon Resources Conversion, 2023
Biomass, as the exclusive and abundant organic resources, is considered to be the promising renewable resource. Carboxylic acids are one of the many compounds that can be obtained from raw biomass.
Shichun Wang   +6 more
doaj   +1 more source

Nontraditional Fragment Couplings of Alcohols and Carboxylic Acids: C(sp3)-C(sp3) Cross-Coupling via Radical Sorting.

open access: yesJournal of the American Chemical Society, 2022
Alcohols and carboxylic acids are among the most commercially abundant, synthetically versatile, and operationally convenient functional groups in organic chemistry. Under visible light photoredox catalysis, these native synthetic handles readily undergo
H. A. Sakai, D. MacMillan
semanticscholar   +1 more source

A Unified Approach to Decarboxylative Halogenation of (Hetero)aryl Carboxylic Acids.

open access: yesJournal of the American Chemical Society, 2022
Aryl halides are a fundamental motif in synthetic chemistry, playing a critical role in metal-mediated cross-coupling reactions and serving as important scaffolds in drug discovery.
Tiffany Q. Chen   +11 more
semanticscholar   +1 more source

Recent advances in decarboxylative nitration of carboxylic acids [PDF]

open access: yesChemical Review and Letters, 2019
In this review, we will summarize the available literature on the preparation of nitro compounds from the corresponding carboxylic acids through nitrodecarboxylation. The review is divided into three major sub-sections.
Soma Majedi   +2 more
doaj   +1 more source

Correlation between C=O Stretching Vibrational Frequency and pKa Shift of Carboxylic Acids

open access: yesJournal of Physical Chemistry B, 2022
Identifying the pKa values of aspartic acid (Asp) and glutamic acid (Glu) in active sites is essential for understanding enzyme reaction mechanisms. In this study, we investigated the correlation between the C=O stretching vibrational frequency (νC=O) of
Keisuke Saito   +2 more
semanticscholar   +1 more source

Ligand-controlled divergent dehydrogenative reactions of carboxylic acids via C–H activation

open access: yesScience, 2021
Description Desaturating acids Molecular motifs with neighboring C=C and C=O double bonds are central to the synthesis of fine chemicals, pharmaceuticals, and polymers. Wang et al.
Zhen Wang   +6 more
semanticscholar   +1 more source

Late-Stage β-C(sp3)-H Deuteration of Carboxylic Acids.

open access: yesJournal of the American Chemical Society, 2021
Carboxylic acids are highly abundant in bioactive molecules. In this study, we describe the late-stage β-C(sp3)-H deuteration of free carboxylic acids. On the basis of the finding that C-H activation with our catalysts is reversible, the de-deuteration ...
A. Uttry   +2 more
semanticscholar   +1 more source

Carboxylic acids and light interact to affect nanoceria stability and dissolution in acidic aqueous environments

open access: yesBeilstein Journal of Nanotechnology, 2023
Cerium atoms on the surfaces of nanoceria (i.e., cerium oxide in the form of nanoparticles) can store or release oxygen, cycling between Ce3+ and Ce4+; therefore, they can cause or relieve oxidative stress within living systems.
Matthew L. Hancock   +2 more
doaj   +1 more source

Effects of Carboxylic Acids on Friction and Wear Reducing Properties for Alkylmethylimidazolium Derived Ionic liquids

open access: yesTribology Online, 2006
Lubricant additive technology to improve lubricant performances is an important issue for ionic liquids to be applied practically. Effects of carboxylic acids with different carbon chain length in ionic liquid on tribological properties were examined ...
Hideto Kamimura   +6 more
doaj   +1 more source

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