Results 171 to 180 of about 195,620 (294)

Ground‐ and Excited‐State Mixed Valency in a 4,4′‐Bipyridine‐Bridged Bimetallic Di‐Ruthenium Complex

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Photoinduced mixed‐valence interactions across a 4,4′‐bpy bridge were studied. MLCT excited states in the bimetallic complex are longer‐lived than in the monometallic reference, thanks to metal–metal electronic coupling and hole delocalization, but are still shorter than the nanosecond timescale relevant for diffusional reactivity.
Ivana Ramírez‐Wierzbicki   +3 more
wiley   +1 more source

Phosphoryl Halogen and Hydrogen Bonding Controls the Solid‐State Structures of Aryl Halide‐Containing Phosphonates

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Intramolecular (RO)2PO→Halogen interaction versus intermolecular (RO)2PO···HOH hydrogen bonds. Although the O···I distance is shorter than the sum of the van der Waals radii of the atoms involved, there is no covalency involved in this interaction.
David Mross   +6 more
wiley   +1 more source

From Phosphinimines to Four‐Membered SiCPN Cations: Insights Into N–Si Bonding and Ring Strain

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Sterically tuned N‐silyl phosphinimines enable four‐membered SiCPN cations. Hydride abstraction yields cyclic cations for Me and iPr substituents at silicon, while tBu gives a protonated intermediate. Multinuclear NMR spectroscopy, X‐ray crystallography, thermochemical density functional theory investigations, and natural bond orbital analyses reveal ...
Alexander Falk, Jonathan O. Bauer
wiley   +1 more source

An overview of some named curves in a Cartesian coordinate system

open access: yesSCIENTIFIC DEVELOPMENT TRENDS AND EDUCATION, 2019
M.G. Akulich, O.I. Gladysheva
openaire   +1 more source

The EU's Strategy for Sustainability: A Landmark Turn With the European Green Deal?

open access: yesEuropean Policy Analysis, EarlyView.
ABSTRACT While the European Green Deal (EGD) has been widely recognized as a milestone in the EU's sustainability strategy, scholars disagree on the nature of the policy change it represents. Critics highlight its limited social and environmental ambitions, despite its portrayal as a “man on the moon” moment.
Ekaterina Domorenok, Franco Gatti
wiley   +1 more source

General Framework for Multi‐Degree‐of‐Freedom Stiffness Matrix Updating for Iterative Solution Algorithms in Hybrid Simulation

open access: yesEarthquake Engineering &Structural Dynamics, EarlyView.
ABSTRACT Iterative solvers are advantageous for handling nonlinear structural analysis problems. The iterative solvers often require updating the stiffness matrix, which limits their application in static and pseudo‐dynamic hybrid simulations because: (1) updating the stiffness matrix of a system involving a physical specimen is challenging; (2 ...
Junyan Xiao, Oh‐Sung Kwon, Evan Bentz
wiley   +1 more source

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