Ground‐ and Excited‐State Mixed Valency in a 4,4′‐Bipyridine‐Bridged Bimetallic Di‐Ruthenium Complex
Photoinduced mixed‐valence interactions across a 4,4′‐bpy bridge were studied. MLCT excited states in the bimetallic complex are longer‐lived than in the monometallic reference, thanks to metal–metal electronic coupling and hole delocalization, but are still shorter than the nanosecond timescale relevant for diffusional reactivity.
Ivana Ramírez‐Wierzbicki +3 more
wiley +1 more source
Intramolecular (RO)2PO→Halogen interaction versus intermolecular (RO)2PO···HOH hydrogen bonds. Although the O···I distance is shorter than the sum of the van der Waals radii of the atoms involved, there is no covalency involved in this interaction.
David Mross +6 more
wiley +1 more source
Toward a documentary standard for performance testing of terrestrial laser scanners used in forensic practice: A statistical procedure to assess change in instrument precision. [PDF]
Gregg M, Muralikrishnan B, Shilling M.
europepmc +1 more source
From Phosphinimines to Four‐Membered SiCPN Cations: Insights Into N–Si Bonding and Ring Strain
Sterically tuned N‐silyl phosphinimines enable four‐membered SiCPN cations. Hydride abstraction yields cyclic cations for Me and iPr substituents at silicon, while tBu gives a protonated intermediate. Multinuclear NMR spectroscopy, X‐ray crystallography, thermochemical density functional theory investigations, and natural bond orbital analyses reveal ...
Alexander Falk, Jonathan O. Bauer
wiley +1 more source
Grounding mathematics in an integrated conceptual structure, part II: intervention study demonstrating robust learning and retention through a grounded curriculum. [PDF]
Mickey KW +3 more
europepmc +1 more source
An overview of some named curves in a Cartesian coordinate system
M.G. Akulich, O.I. Gladysheva
openaire +1 more source
The EU's Strategy for Sustainability: A Landmark Turn With the European Green Deal?
ABSTRACT While the European Green Deal (EGD) has been widely recognized as a milestone in the EU's sustainability strategy, scholars disagree on the nature of the policy change it represents. Critics highlight its limited social and environmental ambitions, despite its portrayal as a “man on the moon” moment.
Ekaterina Domorenok, Franco Gatti
wiley +1 more source
Extended Dynamic Model for the UR16e 6-Degree-of-Freedom Robotic Manipulator. [PDF]
Kern J, Donoso L, Urrea C, González G.
europepmc +1 more source
ABSTRACT Iterative solvers are advantageous for handling nonlinear structural analysis problems. The iterative solvers often require updating the stiffness matrix, which limits their application in static and pseudo‐dynamic hybrid simulations because: (1) updating the stiffness matrix of a system involving a physical specimen is challenging; (2 ...
Junyan Xiao, Oh‐Sung Kwon, Evan Bentz
wiley +1 more source

