Results 241 to 250 of about 20,975 (356)
Sodium Tetraazidoaurate(III)—From Na[AuCl4]·2H2O to Na[Au(N3)4] and Beyond One Step at a Time
Novel sodium chlorido‐/azidoaurate(III) dihydrates Na[AuCl4–x(N3)x]·2H2O (x = 0, 1, 2, 3, 4) provide the first example of a complete series of gradual substitution on tetramer complex anions to be described. Controlled dehydration of Na[Au(N3)4]·2H2O leads to Na[Au(N3)4]·H2O and Na[Au(N3)4], the latter being a highly explosive material.
Mehmet Somer +10 more
wiley +1 more source
Solvent effects: vibrational circular dichroism (VCD) revealed pronounced solvent‐induced conformational shifts for a tetradentate salen ligand in CDCl3, a solvent generally considered benign. Contrary to the DFT prediction of a single dominant conformer family, quantum cluster growth together with the genetic algorithm guided VCD analysis uncovered ...
Amanda Nhi Tran +9 more
wiley +1 more source
A Claim of Conscience: The Duty to Prove Oneself a Resistor. [PDF]
Pakaluk M, Pakaluk CR.
europepmc +1 more source
Optimal model‐based design of experiments for parameter precision: Supercritical extraction case
Abstract This study investigates the process of chamomile oil extraction from flowers. A parameter‐distributed model consisting of a set of partial differential equations is used to describe the governing mass transfer phenomena in a cylindrical packed bed with solid chamomile particles under supercritical conditions using carbon dioxide as a solvent ...
Oliwer Sliczniuk, Pekka Oinas
wiley +1 more source
On the autonomy of the concept of disease in psychiatry. [PDF]
Schramme T.
europepmc +1 more source
Asymptotic properties of cross‐classified sampling designs
Abstract We investigate the family of cross‐classified sampling designs across an arbitrary number of dimensions. We introduce a variance decomposition that enables the derivation of general asymptotic properties for these designs and the development of straightforward and asymptotically unbiased variance estimators.
Jean Rubin, Guillaume Chauvet
wiley +1 more source
Conservation Laws and the Philosophy of Mind: Opening the Black Box, Finding a Mirror. [PDF]
Pitts JB.
europepmc +1 more source
Spinoza and the Dutch Cartesians on Philosophy and Theology [PDF]
Douglas, Alexander
core +1 more source

