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Enantioconvergent catalysis [PDF]
Beilstein Journal of Organic Chemistry, 2016 An enantioconvergent catalytic process has the potential to convert a racemic starting material to a single highly enantioenriched product with a maximum yield of 100%.
Justin T. Mohr +2 more
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Magnetic catalysis and inverse catalysis for heavy pions [PDF]
Journal of High Energy Physics, 2019 We investigate the QCD phase diagram for nonzero background magnetic fields using first-principles lattice simulations. At the physical point (in terms of quark masses), the thermodynamics of this system is controlled by two opposing effects: magnetic ...
G. Endrődi +4 more
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Nature Reviews Chemistry, 2021 We describe as 'reversible' a bidirectional catalyst that allows a reaction to proceed at a significant rate in response to even a small departure from equilibrium, resulting in fast and energy-efficient chemical transformation. Examining the relation between reaction rate and thermodynamic driving force is the basis of electrochemical investigations ...
Vincent Fourmond +2 more
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Kinetic Regularities of Methane Dry Reforming Reaction on Nickel-Containing Modified Ceria–Zirconia
Energies, 2021 The Ni-containing catalysts based on ceria–zirconia doped with Ti and Ti+Nb were prepared by the solvothermal method in supercritical fluids. Ni deposition was carried out by incipient wetness impregnation and the one-pot technique.
Valeria Fedorova +9 more
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Carbon Formation during Methane Dry Reforming over Ni-Containing Ceria-Zirconia Catalysts
Nanomaterials, 2022 Two series of Ni/Ce(Ti/Nb)ZrO2 catalysts were prepared using citrate route and original solvothermal continuous flow synthesis in supercritical isopropanol and studied in dry reforming of methane (DRM). TEM, XPS and FTIRS of adsorbed CO confirm influence
Ekaterina Smal +10 more
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Energies, 2021 This review considers problems related to design of efficient structured catalysts for natural gas and biofuels transformation into syngas. Their active components are comprised of fluorite, perovskite and spinel oxides or their nanocomposites (both bulk
Vladislav Sadykov +3 more
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Microheterogeneous Catalysis [PDF]
Molecules, 2010 The catalytic effect of micelles, polymers (such as DNA, polypeptides) and nanoparticles, saturable receptors (cyclodextrins and calixarenes) and more complex systems (mixing some of the above mentioned catalysts) have been reviewed. In these microheterogeneous systems the observed changes in the rate constants have been rationalized using the ...
Bernal Pérez, Eva +2 more
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Angewandte Chemie International Edition, 2019 AbstractHigh acidity and structural confinement are pivotal elements in asymmetric acid catalysis. The recently introduced imidodiphosphorimidate (IDPi) Brønsted acids have met with remarkable success in combining those features, acting as powerful Brønsted acid catalysts and “silylium” Lewis acid precatalysts in numerous thus far inaccessible ...
Lucas Schreyer +2 more
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Novel Ni/Ce(Ti)ZrO2 Catalysts for Methane Dry Reforming Prepared in Supercritical Alcohol Media
Energies, 2020 To achieve a high activity and coking stability of nickel catalysts in dry reforming of methane, materials comprised of ceria–zirconia doped by Ti were investigated as supports.
Yuliya Bespalko +9 more
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Chimica Techno Acta, 2023 The main idea of the investigation was to define testing parameters with the lowest influence of internal and external diffusion on catalytic activity in hydrodesulfurization of dibenzothiophene.
Polina P. Mukhacheva +7 more
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