Results 121 to 130 of about 398,278 (315)
Mass spectrometry based identification of AMP‐O‐Tris generated by Thermococcus onnurineus Cas10
Isolated Thermococcus onnurineus Cas10 generates the noncanonical ATP‐derived product AMP‐O‐Tris while in Tris‐containing buffer as identified via mass spectrometry, revealing relaxed nucleophile selectivity under isolated conditions. These findings suggest that multiprotein Csm complex assembly restricts Cas10 reactivity toward canonical cyclic ...
Su‐Jin Lee +6 more
wiley +1 more source
Abruptly changing from aerobic to anaerobic conditions (sudden anaerobization) induced growth inhibition and a significant increase in intracellular labile ferrous iron in the aerotolerant anaerobe Amphibacillus xylanus. We found that free flavins mediate efficient electron transfer from NADH to ferric iron under anaerobic conditions, suggesting that ...
Shinya Kimata +13 more
wiley +1 more source
The Pursuit of Effective Catalysis for C-C and C-N Cross-Coupling under Mild Conditions
Homogeneous transition metal-catalysis has had a great impact on the synthesis of organic molecules in recent years. The selective mono-arylation of small molecules, a class of reactions predominantly achieved via transition metal-catalyzed cross ...
MacQueen, Preston
core
Synthesis and characterization of Ru-loaded anodized aluminum oxide for hydrogenation catalysis
Anodized aluminum oxides (AAOs) are synthesized and used as catalyst support in combination with Ru as metal in hydrogenation catalysis. SEM and TEM analysis of the as-synthesized AAOs reveal uniform, ordered nanotubes with pore diameters of 18 nm, which
Glas, Daan +19 more
core +1 more source
In a murine model of myocardial ischemia and reperfusion (MI/R), the CD36 azapeptide ligand MPE‐298 reduces cardiac injury and transiently lowers left ventricular long‐chain fatty acids (LCFAs) accumulation 3 h after reperfusion, accompanied by a decrease of oxidative stress and inflammation‐associated genes' expression in the heart and adipose tissue.
Jade Gauvin +12 more
wiley +1 more source
Heterogeneous catalysis: Catch me if you can!
Chemists are like detectives: they like to know 'whodunit' during a catalytic reaction. Combining advanced electron microscopy with intelligent molecular design has now provided strong evidence for the presence of a highly active site within a complex ...
Inorganic Chemistry and Catalysis +2 more
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UiO‐66(Zr) metal–organic frameworks are chemically stable, biocompatible, and highly tunable nanomaterials. Their modular structure enables controlled drug delivery, multimodal bioimaging, and light‐activated photodynamic therapy, supporting integrated diagnostic and therapeutic (theranostic) applications in cancer and biomedical research.
Veronika Huntošová +2 more
wiley +1 more source
Even though EXAFS is a young technique already quite a few very important results have been obtained in catalysis. Especially the results on Wilkinson’s catalyst (Section 8.3.1), the sulfided Co—Mo/A1203 catalyst (Section 8.3.3), bromine and krypton on ...
Koningsberger, D.C., Prins, R.
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Due to the increasing emission of carbon dioxide (CO2), greenhouse effects are becoming more and more severe, causing global climate change. The conversion and utilization of CO2 is one of the possible solutions to reduce CO2 concentrations.
Liu, Miao +9 more
core +1 more source

