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We describe as 'reversible' a bidirectional catalyst that allows a reaction to proceed at a significant rate in response to even a small departure from equilibrium, resulting in fast and energy-efficient chemical transformation. Examining the relation between reaction rate and thermodynamic driving force is the basis of electrochemical investigations ...
Vincent Fourmond+2 more
openaire +4 more sources
Aggregation-Induced Catalysis: Asymmetric Catalysis with Chiral Aggregates
So far, there have been 4 methods to control chirality including the use of chiral auxiliaries, reagents, solvents, and catalysts documented in literature and textbooks.
Yao Tang+9 more
doaj +1 more source
Nanoparticles for Catalysis [PDF]
Nanoscience emerged in the last decades of the 20th century with the general aim to determine those properties that appear when small particles of nanometric dimensions are prepared and stabilized.[...]
Hermenegildo García+2 more
openaire +5 more sources
Anion–π catalysis on carbon allotropes
Anion–π catalysis, introduced in 2013, stands for the stabilization of anionic transition states on π-acidic aromatic surfaces. Anion–π catalysis on carbon allotropes is particularly attractive because high polarizability promises access to really strong
M. Ángeles Gutiérrez López+7 more
doaj +1 more source
AbstractNature’s enzymes are an ongoing source of inspiration for scientists. The complex processes behind their selectivity and efficiency is slowly being unraveled, and these findings have spawned many biomimetic catalysts. However, nearly all focus on the conversion of small molecular substrates.
van Dongen, S.F.H.+4 more
openaire +4 more sources
Oxidation of propene from air by atmospheric plasma-catalytic hybrid system [PDF]
The pulsed dielectric barrier discharge (DBD) combined with the palladium supported on alumina beads, was investigated for propene (C3H6) removal from air. The effects of thermal-catalysis, plasma-catalysis (in-plasma catalysis and post-plasma catalysis),
Pham Thien Huu+2 more
doaj +1 more source
The development of active and stable photocatalysts for the degradation of volatile organic compounds under visible light is important for efficient light utilization and environmental protection.
Nikita Kovalevskiy+7 more
doaj +1 more source
Conformational Dynamics of metallo-β-lactamase CcrA during Catalysis Investigated by Using DEER Spectroscopy [PDF]
Previous crystallographic and mutagenesis studies have implicated the role of a position-conserved hairpin loop in the metallo-β-lactamases in substrate binding and catalysis.
Aitha, Mahesh+8 more
core +2 more sources
RNA catalysis—is that it? [PDF]
Article and publication date are at http://www.rnajournal.org/cgi/doi/10.1261/rna.049874.115. Freely available online through the RNA Open Access option.
Wilson, Timothy J., Lilley, David M. J.
openaire +4 more sources
Search for Nucleon Decays induced by GUT Magnetic Monopoles with the MACRO Experiment [PDF]
The interaction of a Grand Unification Magnetic Monopole with a nucleon can lead to a barion-number violating process in which the nucleon decays into a lepton and one or more mesons (catalysis of nucleon decay).
Ambrosio, M.+114 more
core +6 more sources