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Catalytic reductive desymmetrization of malonic esters
Nature Chemistry, 2021Desymmetrization of fully substituted carbons with a pair of enantiotopic functional groups is a practical strategy for the synthesis of quaternary stereocentres, as it divides the tasks of enantioselection and C-C bond formation. The use of disubstituted malonic esters as the substrate of desymmetrization is particularly attractive, given their easy ...
Pengwei Xu, Zhongxing Huang
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Catalytic NOx Reduction Studies
SAE Technical Paper Series, 1973<div class="htmlview paragraph">Hundreds of catalysts have been evaluated in bench activity tests, using synthetic engine exhaust gas to determine conversion of NO to N<sub>2</sub> and NH<sub>3</sub>. Many of these catalysts were also exposed to actual engine exhaust in an engine-dynamometer test, and then re-evaluated in ...
H. R. Jackson +2 more
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Selective Catalytic Reduction - Europe's NOx Reduction Technology
SAE Technical Paper Series, 2003<div class="htmlview paragraph">The high efficiency of the diesel engine has made it the primary propulsion source for truck applications worldwide. In Europe, the penetration of diesel engines in passenger cars is growing rapidly in an effort to meet the stringent CO<sub>2</sub> future emission targets.
W. Müller +4 more
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CATALYTIC REDUCTION OF DINITRILES
Russian Chemical Reviews, 1964CONTENTS I. Introduction 319 II. Reaction conditions 319 III. Deamination of primary amines 322 IV. Mechanism of the catalytic reduction of nitriles 322 V. Influence of dinitrile structure on the course of the reaction 326 VI.
L Kh Freidlin, T A Sladkova
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Catalytic Azide Reduction in Biological Environments
ChemBioChem, 2012AbstractIn the quest for the identification of catalytic transformations to be used in chemical biology and medicinal chemistry, we identified iron(III) meso‐tetraarylporphines as efficient catalysts for the reduction of aromatic azides to their amines.
Pijus K, Sasmal +9 more
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Reduction-resistant and reduction-catalytic double-crown nickel nanoclusters
Nanoscale, 2014Ni6(SCH2CH2Ph)12(Ni6) was synthesized using three different methods and fully characterized; importantly, the reduction-resistance and reduction-catalysis properties of Ni6 were revealed.
Min, Zhu +4 more
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Catalytic enantioselective reductive Eschenmoser-Claisen rearrangements
ScienceAn important challenge in enantioselective catalysis is developing strategies for the precise synthesis of neighboring congested all-carbon quaternary stereocenters. The well-defined transition states of [3,3]-sigmatropic rearrangements and their underlying stereospecificity render them powerful tools for the synthesis of such arrays.
Guoting Zhang +2 more
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1.8 Catalytic Reduction of Carbonates
2018AbstractCarbonates are basic chemicals that are widely used in both industry and academia. Their reduction under either homogeneous or heterogeneous catalytic conditions generates formates, methanol, or methane. Carbonates can also act as a C1 building block for the reductive methylation of amines.
Y. Li, K. Ding
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Nonselective catalytic reduction
Applied Catalysis A: General, 1993Sanjay Agarwal, Jerry Spivey
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