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Catalytic transfer hydrogenation
Chemical Reviews, 19741. Olefins 2. Acetylenes 3. Carbonyl Compounds 4. Nitriles 5. Imines, Hydroxylamines, Hydrazones 6. Azo Compounds 7. Nitro Compounds B. Hydrogenolysis 1 , Nitriles 2. Halides 3. Allylic and Benzylic Functional Groups 4. Amines C. Structural Selectivity D. Special Synthetic Applications IV. Mechanism V .
Gottfried Brieger, Terry J. Nestrick
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Catalytic Hydrogen Transfer Reactions
Chinese Journal of Chemistry, 2021AbstractOur recently studies on three types of reactions with hydrogen transfer as a key step, including catalytic asymmetric proton transfer reactions using “chiral proton transfer shuttle”, catalytic B—H bond insertion containing a hydrogen atom transfer, and iron‐catalyzed hydrosilylation reactions containing hydride transfer were briefly introduced.
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Catalytic transfer hydrogenation of olefins
Research on Chemical Intermediates, 1998Catalytic transfer hydrogenation with simultaneous isomerization of 1-olefins (C6-C8), 1,3-cyelohexadiene, 1,7-octadiene and cyclohexene using ammonium formate on 3% Pd/C at 20°C in methanol was studied. The effect of the experimental procedure upon the hydrogenation course was discussed.
Zuzana Dobrovolná, Libor Červený
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Catalytic transfer hydrogenation of mycoepoxydiene
Chemistry of Natural Compounds, 2006Catalytic transfer hydrogenation with hydrogenolysis of mycoepoxydiene (1) by ammonium formate/10% Pd-C gave a new compound, deacetylhexahydromycoepoxydiene (2), whose structure was determined by spectroscopic and X-ray diffraction experiments. In the primary bioassay, 1, 2 and hexahydromycoepoxydiene (3) showed anticancer activities against HeLa in ...
Haiyan Chen +5 more
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Hydrocarbon hydrogen carriers for catalytic transfer hydrogenation of guaiacol
International Journal of Hydrogen Energy, 2020Polycyclic hydrocarbons are known to be efficient hydrogen carriers capable of yielding high purity H2 upon dehydrogenation. Due to their high hydrogen density, high boiling point, and stability, these compounds demonstrate the potential to be used as hydrogen donors under catalytic transfer hydrogenation (CTH) conditions.
Gabriel Fraga +7 more
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Catalytic transfer hydrogenation of soybean oil
Journal of the American Oil Chemists' Society, 1992The catalytic transfer hydrogenation of soybean oil by various hydrogen donors and solvents with palladium‐oncarbon catalyst was investigated in batch and continuous modes. The choice of reaction conditions, donor and catalyst allowed the manufacture of partially hydrogenated oils or semi‐solid fats with controlled fatty acid contents, iodine value ...
A. Šmidovnik, A. Štimac, J. Kobe
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Catalytic Transfer Hydrogenation of Castor Oil
Journal of Chemical Education, 2014The main thickening agent or soap in multipurpose grease, lithium 12-hydroxystearate, is a chemical commodity for the auto industry. This compound is obtained from castor oil via a series of chemical transformations. The first step, hydrogenation of castor oil, has been developed into a laboratory experiment for second-year undergraduate organic ...
Hanan Alwaseem +2 more
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Catalytic transfer hydrogenation of sugar derivatives
Carbohydrate Polymers, 2001Abstract Cyclodextrin azides were successfully converted to the corresponding amino derivatives. When sugar derivatives are transformed, the appropriate transfer agents are limited in number because the most common transfer compounds, e.g. hydrazine hydrate or formic acid, can compete in side reactions.
L Jicsinszky, R Iványi
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