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Catecholate derivatives of zirconocene: Facile methylation of a catecholate ring
Journal of Organometallic Chemistry, 2021Abstract Reaction of [Cp'2ZrMe2] (Cp' = η5-tBuC5H4) with 3,6-di-tert-butylcatechol (H2Cat36) leads to complex [Cp'2ZrCat36] (1). Analogous reaction of [Cp'2ZrMe2] with 3,6-di-tert-butyl-o-benzoquinone (Q36) results in migration of the methyl group from metal to the C6-ring and formation of a complex of 3-tert-butyl-6-methyl-catecholate [Cp'2ZrCat36Me]
Pavel A. Petrov +5 more
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Reactions of 3-ethylcatechol and 3-(methylthio)catechol with catechol dioxygenases
Archives of Biochemistry and Biophysics, 1986The reactions of 3-ethylcatechol and 3-(methylthio)catechol with catechol 1,2-dioxygenase and catechol 2,3-dioxygenase from Pseudomonas putida were examined. Both 3-substituted catechols are oxidized by catechol 2,3-dioxygenase at approximately 30% of the rate observed for catechol oxidation by this enzyme.
R A, Pascal, D S, Huang
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Activity of mushroom tyrosinase on catechol and on a catechol estrogen in an organic solvent
Biochimica et Biophysica Acta (BBA) - Protein Structure and Molecular Enzymology, 1993A suspension of tyrosinase-coated glass beads in butanol effectively oxidizes catechol substrate. The enzyme is not soluble in the organic solvent and activity can be stopped by removal of the solid state enzyme after low-speed centrifugation or decantation.
G M, Jacobsohn +2 more
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The Journal of Clinical Endocrinology & Metabolism, 1972
The substrate specificity of the catechol-O-methyltransferase, purified from human liver 380-fold, has been tested with a variety of compounds. Catechol estrogens, as well as catechol amines are methylated to their corresponding monomethyl ethers. The relation of the rates of methylation of catechol estrogens and catechol amines depended on enzyme and ...
PETER BALL +3 more
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The substrate specificity of the catechol-O-methyltransferase, purified from human liver 380-fold, has been tested with a variety of compounds. Catechol estrogens, as well as catechol amines are methylated to their corresponding monomethyl ethers. The relation of the rates of methylation of catechol estrogens and catechol amines depended on enzyme and ...
PETER BALL +3 more
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A semiempirical study on inhibition of catechol O-methyltransferase by substituted catechols
Journal of Computer-Aided Molecular Design, 1998Catechol and endogenous catechol derivatives are readily methylated by catechol O-methyltransferase (COMT). In contrast, many catechol derivatives possessing electronegative substituents are potent COMT inhibitors. The X-ray structure of the active site of COMT suggests that the methylation involves a lysine as a general base.
Martti Ovaska, Ari Yliniemelä
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Movement Disorders, 2010
AbstractA brief history of the evolution of the term catechol amine and relationship to the treatment of Parkinson's disease.
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AbstractA brief history of the evolution of the term catechol amine and relationship to the treatment of Parkinson's disease.
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Site of excretion of catechol and catecholamines: renal metabolism of catechol
American Journal of Physiology-Legacy Content, 1970B, Rennick, A, Quebbemann
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Multiple catechols in human plasma after drinking caffeinated or decaffeinated coffee
Journal of Chromatography B: Analytical Technologies in the Biomedical and Life Sciences, 2021David S Goldstein +2 more
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