Results 101 to 110 of about 72,832 (304)

Computational evaluation of zirconocene catalysts for ε-caprolactone cationic ring-opening polymerization

open access: yesScientific Reports
This quantum chemical study presents the ligand effect and a structure–property relationship in the cationic ring-opening polymerization (CROP) of ε-caprolactone using zirconocene catalysts.
Wijitra Meelua   +2 more
doaj   +1 more source

Phenomenological characterization of sequential dual-curing of off-stoichiometric "thiol-epoxy" systems: Towards applicability [PDF]

open access: yes, 2017
An extensive characterization of a sequential dual-curing system based on off-stoichiometric “thiol-epoxy” mixtures was carried out using thiol compounds of different functionality.
Belmonte, Alberto   +3 more
core   +1 more source

Tuning the Dielectric Properties of Individual Clay Nanosheets by Interlayer Composition: Toward Nano‐Electret Materials

open access: yesAdvanced Functional Materials, EarlyView.
The dielectric properties of clays are studied on the level of individual monolayers and functional double stacks. The material breakdown characteristics and charge storage performance are analyzed. For illustration, a defined charge pattern representing a cuneiform character is produced, written into a microscopic clay tile, referencing the origins of
Sebastian Gödrich   +6 more
wiley   +1 more source

Synthesis of Early Transition Metal Bisphenolate Complexes and Their Use as Olefin Polymerization Catalysts [PDF]

open access: yes, 2009
Bisphenolate ligands with pyridine- and benzene-diyl linkers have been synthesized and metalated with group 4 and 5 transition metals. The solid-state structures of some of the group 4 complexes have been solved.
Bercaw, John E., Golisz, Suzanne R.
core   +1 more source

Fast‐Responding O2 Gas Sensor Based on Luminescent Europium Metal‐Organic Frameworks (MOF‐76)

open access: yesAdvanced Functional Materials, EarlyView.
Luminescent MOF‐76 materials based on Eu(III) and mixed Eu(III)/Y(III) show rapid and reversible changes in emission intensity in response to O2 with very short response times. The effect is based on triplet quenching of the linker ligands that act as photosensitizers. Average emission lifetimes of a few milliseconds turn out to be mostly unaffected by
Zhenyu Zhao   +5 more
wiley   +1 more source

"Analysis of factors influencing preparation of high molecular weight polyisobutylene"

open access: yesHecheng xiangjiao gongye
Isobutylene polymerization was studied with the rare-earth metal scandium cationic complexes as catalysts and molecular weight and its distribution, and glass transition temperature of polyisobutylene were investigated by screening the catalyst system ...
TU Xiao-yan1, CHENG Peng-fei1, LIU Yun1, LI Shi-hui2, HUANG An-ping1, LI Guang-quan1
doaj   +1 more source

Protecting Group-Free Synthesis of Glycopolymer-Type Amphiphilic Macromonomers and Their Use for the Preparation of Carbohydrate-Decorated Polymer Particles

open access: yesBiomolecules, 2019
Polymer particles modified with carbohydrates on their surfaces are of significant interest, because their specific recognition abilities to biomolecules are valuable for developing promising materials in biomedical fields.
Jin Motoyanagi   +3 more
doaj   +1 more source

Electroactive Metal–Organic Frameworks for Electrocatalysis

open access: yesAdvanced Functional Materials, EarlyView.
Electrocatalysis is crucial in sustainable energy conversion as it enables efficient chemical transformations. The review discusses how metal–organic frameworks can revolutionize this field by offering tailorable structures and active site tunability, enabling efficient and selective electrocatalytic processes.
Irena Senkovska   +7 more
wiley   +1 more source

Photoswitching Conduction in Framework Materials

open access: yesAdvanced Functional Materials, EarlyView.
This mini‐review summarizes recent advances in state‐of‐the‐art proton and electron conduction in framework materials that can be remotely and reversibly switched on and off by light. It discusses the various photoswitching conduction mechanisms and the strategies employed to enhance photoswitched conductivity.
Helmy Pacheco Hernandez   +4 more
wiley   +1 more source

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