Ionic Precursors Transformed Into Vinyl Acetate Synthesis Catalyst via Reaction‐Driven Restructuring
This work demonstrates that a simple physical mixture of Pd and Au ionic precursors, KOAc promoter, and SiO2 support can transform into a highly active vinyl acetate synthesis catalyst through reaction‐driven restructuring. The results highlight reaction‐induced restructuring as an innovative and sustainable catalyst design strategy.
Byeong Jun Cha +11 more
wiley +1 more source
A Half-Century of Supramolecular Thermodynamics: A Retrospective of Our Multidisciplinary Approach. [PDF]
Danil de Namor AF, Al Hakawati N.
europepmc +1 more source
A new class of photoresponsive liquid‐crystalline (LC) adhesives based on biomineral‐inspired organic/inorganic colloidal hybrids is reported. These colloidal LC materials are formed by hybridization of a hydroxyapatite nanorod with azobenzene‐based forklike molecules.
Junya Uchida +4 more
wiley +1 more source
Charge Migration in Cations: Structures, Energies, and Vibrational Frequencies of Ground and Excited States of HCCX+, CH3X+, Vinyl Bromide Cation and Propiolic Acid Cations. [PDF]
Mukherjee D +4 more
europepmc +1 more source
A Li2O‐rich solid electrolyte interphase (SEI) is engineered on graphite through a propylene carbonate‐based electrolyte to spatially regulate Li plating. The homogeneous interphase lowers Li nucleation barriers, promotes conformal Li deposition around graphite particles, and suppresses dendritic accumulation, enabling durable hybrid Li‐ion/Li‐metal ...
Robert Kuphal +8 more
wiley +1 more source
Oxonium-Embedded Benzo[<i>b</i>]perylene: A Redox-Switchable Closed-Shell π‑Cation, and Its Paramagnetic Charge-Transfer Salt with TCNE<sup>•</sup>. [PDF]
Duan C +12 more
europepmc +1 more source
Disentangling Bulk and Surface Contributions to Charge and Discharge Fading in High‐Voltage LiCoO2
High‐voltage operation of LiCoO2 accelerates capacity fading through bulk and surface degradation. By introducing a LiTaO3 coating to selectively suppress surface degradation, bulk and surface contributions to charge and discharge fading are decoupled.
Hyungjoon Moon +6 more
wiley +1 more source
Simultaneous electrochemical detection of multiple heavy metal cations using multi-walled carbon nanotubes functionalized with a ferrocenyl-based 1,4-disubstituted-1,2,3-triazole complex. [PDF]
Al Khalyfeh K +8 more
europepmc +1 more source
A dynamically actuated reconfigurable topographical surface (DARTS) integrates contact‐mediated bactericidal nanotopography with programmable mechanical actuation to actively disrupt bacterial biofilms. Dynamic surface reconfiguration enhances bacterial killing and suppresses implant‐associated infections in vivo, providing a new strategy for active ...
Mohammad Asadi Tokmedash +4 more
wiley +1 more source
Non-dispersive second-order charge recombination at mesoporous TiO<sub>2</sub>/adsorbed molecules/electrolyte interfaces. [PDF]
Narita M, Mori S.
europepmc +1 more source

