Physically based 3D finite element model of a single mineralized collagen microfibril [PDF]
Mineralized collagen microfibrils in human bone provide its mechanical properties (stiffness, elasticity, ductility, energy dissipation and strength). However, detailed 3D finite element models describing the mechanical behaviour of the mineralized collagen microfibrils are still lacking.
arxiv +1 more source
Initiator-free photo-crosslinkable cellulose-based resists for fabricating submicron patterns via direct laser writing [PDF]
Novel bifunctional cellulose diacetate derivatives were synthesized in order to achieve bio-based photoresists, which can be structured by two-photon absorption via direct laser writing (DLW) without the need to use a photoinitiator. Therefore, cellulose diacetate is functionalized with thiol moieties and olefinic or methacrylic side groups enabling ...
arxiv +1 more source
Resonant soft X-ray scattering reveals cellulose microfibril spacing in plant primary cell walls
Cellulose microfibrils are crucial for many of the remarkable mechanical properties of primary cell walls. Nevertheless, many structural features of cellulose microfibril organization in cell walls are not yet fully described.
Dan Ye+7 more
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Background Genetic modification of plant cell walls has been implemented to reduce lignocellulosic recalcitrance for biofuel production. Plant glycoside hydrolase family 9 (GH9) comprises endo-β-1,4-glucanase in plants.
Jiangfeng Huang+11 more
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Lignocellulose biomass has a tremendous potential as renewable biomaterials for fostering the “bio-based society” and circular bioeconomy paradigm. It requires efficient use and breakdown of fiber cell walls containing mainly cellulose, hemicellulose and
Dinesh Fernando+4 more
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Dispersion of Boron Nitride Powders in Aqueous Suspensions with Cellulose [PDF]
The dispersion of nitride and carbide ceramic particles in water is difficult, due to the absence of hydroxyl groups on their surface. Boron nitride is not an exception and despite its numerous applications, no effective dispersant has been identified so far. We demonstrate here the dispersion properties of two cellulose derivatives for hexagonal boron
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Isolation of Cellulose Nanofibers: Effect of Biotreatment on Hydrogen Bonding Network in Wood Fibers
The use of cellulose nanofibres as high-strength reinforcement in nano-biocomposites is very enthusiastically being explored due to their biodegradability, renewability, and high specific strength properties. Cellulose, through a regular network of inter-
Sreekumar Janardhnan, Mohini Sain
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Hydrogen bonds and twist in cellulose microfibrils [PDF]
There is increasing experimental and computational evidence that cellulose microfibrils can exist in a stable twisted form. In this study, atomistic molecular dynamics (MD) simulations are performed to investigate the importance of intrachain hydrogen bonds on the twist in cellulose microfibrils.
Kannam, Sridhar Kumar+5 more
openaire +4 more sources
Brittle Culm1, a COBRA-like protein, functions in cellulose assembly through binding cellulose microfibrils. [PDF]
Cellulose represents the most abundant biopolymer in nature and has great economic importance. Cellulose chains pack laterally into crystalline forms, stacking into a complicated crystallographic structure.
Lifeng Liu+10 more
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Electronic Band Structures of Pristine and Chemically Modified Cellulose Allomorphs [PDF]
We have investigated the structural properties, vibrational spectra, and electronic band structures of crystalline cellulose allomorphs and chemically modified cellulose with quantum chemical methods. The electronic band gaps of cellulose allomorphs I$_\alpha$, I$_\beta$, II, and III$_1$ lie in the range of 5.0 to 5.6 eV.
arxiv +1 more source