Results 101 to 110 of about 56,211 (225)

Spontaneous Imbibition of Bicontinuous Microemulsions into Hydrophilic and Hydrophobic Controlled Pore Glasses. [PDF]

ACS Omega
Dahl M, Doll L, Tesch C, Paul B, Hübner J, Tiersch B, Hellweg T, Wellert S.   +7 more
europepmc   +1 more source

The Effect of Water Management and Cell Compression in Bipolar Membrane CO2 Electrolysis to CO

Carbon Energy, EarlyView.
In‐operando neutron imaging uncovers water management challenges in bipolar membrane CO2 electrolysis: Internal water generation floods the cathode, while compression dictates membrane and gas diffusion electrode integrity. Strategic adjustments are applied in this work: dry gas feed and mechanical support of the gas diffusion electrode enable stable ...
Frederik Brendel, Liel Bühler, Luca Bohn, Josephine N. Häberlein, Lukas Helfen, Alessandro Tengattini, Severin Vierrath, Joey Disch   +7 more
wiley   +1 more source

Changing N^C^O to C^N^O Coordination in Cyclometalated Pt(II) and Pd(II) Complexes Modulates Stability and Emission Characteristics: Toward Brighter Versatility

Chemistry – A European Journal, EarlyView.
A new class of cyclometalated metal complexes with pincer luminophores (C^N^O and N^C^O) is reported. They unite high photoluminescence efficiencies in liquid solutions at r.t. with tunable colors across the visible spectrum and convenient synthetic accessibility.
Joschua Lüke, Yokari Godinez‐Loyola, Alexander Hepp, Jutta Kösters, Cristian A. Strassert   +4 more
wiley   +1 more source

Drug-Metabolizing Enzymes in Human Keratinocytes and In Vitro Detection of Cytochrome P450-Mediated Phenolic Lamotrigine Metabolite. [PDF]

Chem Res Toxicol
Deck PN, Müller M, Glässner A, Vogel M, Steffens M, Heubach C, Fechner G, Becker K, Weindl G, Sachs B.   +9 more
europepmc   +1 more source

Polarity on Demand: Nucleophilic, Electrophilic, and Ambiphilic Reactivity at a 9,10‐Dihydro‐9,10‐Disilaanthracene Platform

Chemistry – A European Journal, EarlyView.
A 9,10‐dihydro‐9,10‐disilaanthracene platform was efficiently synthesized and features intrinsically electrophilic Si sites. Upon stepwise reductive Si─H bond cleavage, these Si sites are converted into nucleophilic centers. This controlled polarity switching also enables ambiphilic reactivity within a homo‐heteroelement framework.
Moritz Schmidt, Alexander Virovets, Eugenia Peresypkina, Hans‐Wolfram Lerner, Matthias Wagner   +4 more
wiley   +1 more source

Functional group tolerant iron-catalyzed cyclotrimerization of terminal and internal alkynes. [PDF]

Commun Chem
Klinnert B, Plietker B.
europepmc   +1 more source

SO2 Transfer Enabled by an Easy‐to‐Handle Ionic Liquid

Chemistry – A European Journal, EarlyView.
Best of both worlds: The ionic liquid [NEt3Me][Cl(SO2)n] unites the atom economy and low cost of sulfur dioxide with the safety and applicability of common surrogates, streamlining SO2 transfer to access to 3‐sulfolenes, sulfonamides, and SuFEx reagents.
Johanna S. Sturm, Letizia Lanfredi, Severin Erbertseder, Marius Balizs, Patrick Voßnacker, Simon Steinhauer, Merlin Kleoff, Anja Wiesner, Niklas Limberg, Patrick Pröhm, Franz‐Lucas Haut, Sebastian Riedel   +11 more
wiley   +1 more source

Asymmetric α-Alkylation With Activated and Unactivated Electrophiles by a Highly Productive and Recyclable Lewis Acid/Imidazolium Catalyst. [PDF]

Angew Chem Int Ed Engl
Haußmann J, Beck A, Hornung D, Mistele M, Allgaier A, Frey W, van Slageren J, Kästner J, Peters R.   +8 more
europepmc   +1 more source

Silylium‐Ion‐Initiated Disulfidation of Internal Alkynes With Disulfides

Chemistry – A European Journal, EarlyView.
Silylium‐ion initiation enables the disulfidation of internal alkynes with diaryl disulfides. The catalytic turnover is maintained by the sulfonium ion ArS(ArSSAr)+ as a sulfenium‐ion carrier that reacts with an alkyne to form a thiirenium ion. Its ring opening by disulfide addition yields the 1,2‐bis(arylthio)‐substituted alkene product with E:Z > 95 ...
Dáiríne M. Morgan, Hendrik F. T. Klare, Martin Oestreich   +2 more
wiley   +1 more source

Organelle‐Resolved Tetrazine‐trans‐Cyclooctene Click Chemistry for Cargo Delivery and Release

Chemistry – A European Journal, EarlyView.
Bioorthogonal click chemistry tools provide a means for specific intracellular conjugation of molecules. In this study, we used reactive tetrazine (Tz) and TCO moieties for labeling of organelles and organelle‐specific delivery and activation of doxorubicin prodrugs.
Oleh Durydivka, Marek Chovanec, Rastislav Dzijak, Michal Rahm, Jachym Hrusak, Paul E. Reyes‐Gutierrez, Milan Vrabel   +6 more
wiley   +1 more source