Results 21 to 30 of about 5,856 (239)

A Hoveyda–Grubbs‐Type Olefin Metathesis Catalyst Bearing a Fluorinated Unsymmetrical NHC Ligand

European Journal of Inorganic Chemistry, EarlyView.
A fluorinated unsymmetrical NHC ruthenium complex was synthesised and employed as a catalyst for olefin metathesis reactions. The modification of the steric and electronic properties of the NHC ligand through the introduction of fluorine substituents results in improved activity but lower selectivity compared to the analogous non‐fluorinated NHC ...
Rubina Troiano, Concetta Liguori, Chiara Costabile, Fabia Grisi   +3 more
wiley   +1 more source

Actinide 4,4′‐Bipyridine‐N,N′‐Dioxide Coordination Polymers: Cationic Framework Structures Templated by Dicyanoaurate and Tetracyanoaurate Counterions

European Journal of Inorganic Chemistry, EarlyView.
Th4+ or UO22+ actinides, neutral bipyridine‐N,N’‐dioxide ligands, and anionic cyanoaurate linkers are combined to generate a family of four coordination polymers. ‘Truss bridge’ and square grid cationic frameworks are yielded when using [Au(CN)2]− or [Au(CN)4]−, respectively, indicating a templating effect guided by either aurophilic interactions ...
Sylvain St. Louis, Thomas E. Karpiuk, Daniel B. Leznoff   +2 more
wiley   +1 more source

Dioxomolybdenum(VI) Complexes Supported by Fluxional Bis(amide)‐Functionalized Aminophenolate Ligands

European Journal of Inorganic Chemistry, EarlyView.
New bis(amide) aminophenolate ligands form dioxomolybdenum(vi) and dioxotungsten(vi) complexes showing solvent‐dependent nuclearity. Whilst monomeric complexes featuring methoxide ligands are obtained in methanol, water triggers formation of μ‐oxo‐bridged dimers via oxo exchange, verified by 18O labelling.
Pasi Vikberg, Anssi Peuronen, Manu Lahtinen, Ari Lehtonen   +3 more
wiley   +1 more source

Main Group Metals in Redox Catalysis

European Journal of Inorganic Chemistry, EarlyView.
Main group metal redox catalysis is emerging as a credible alternative to transition metal chemistry. Elements from groups 13 to 15 now enable diverse catalytic manifolds, driven by ligand design and control of electronic structure. This review highlights recent advances, key design principles, and remaining challenges, positioning main group metals as
Olympia Mouriki, Alba Martinez‐Bascuñana, Oriol Planas   +2 more
wiley   +1 more source

The Hydrogenation of MNi3 Compounds (M = Si, Ge, Sn, Sb, Zr, V, Fe)

European Journal of Inorganic Chemistry, EarlyView.
Hexagonal Ni3Sn takes up hydrogen to form α‐Ni3SnHx (filled Ni3Sn type, ΔV = 0.9%), followed by a transition to the cubic β‐Ni3SnHy (filled AuCu3 type, ΔV = 1.1% with respect to pristine Ni3Sn), while MNi3 (M = Zr, Si, Sb) compounds show no reaction toward hydrogen and MNi3 (M = V, Fe, Ge) compounds only a minute hydrogen uptake.
André Götze, Mihai I. Sturza, Leonie Jurkschat, Önder F. Serhadli, Anastasiya Yu. Polevik, Alexey N. Kuznetsov, Holger Kohlmann   +6 more
wiley   +1 more source

Imidazolium Modified UiO‐67 Metal‐Organic Frameworks for CO2 Adsorption

European Journal of Inorganic Chemistry, EarlyView.
CO2 sorption in UiO‐67 and its imidazolium‐functionalized derivatives is examined with emphasis on the role of different counterions. Structural characterization and spectroscopic studies provide insight into how functionalization affects pore environments and CO2 interactions.
Lisa Eisele, Jakob Blaschke, Shaghayegh Naghdi, Dogukan H. Apaydin, Stephen Nagaraju Myakala, Dominik Eder, Katharina Bica‐Schröder   +6 more
wiley   +1 more source

From Olefin Coordination to Rh─N Bond Formation and Oxidative Addition: pH Effects in Rhodium α‐Methyl‐β‐Amidoitaconate Complexes

European Journal of Inorganic Chemistry, EarlyView.
The coordination of α‐methyl‐β‐amidoitaconate at Rh(I) diphosphine complexes is studied using a combination of high‐field and low‐field flow NMR spectroscopy and X‐ray analysis. In the presence of basic or acidic additives, the formation of neutral Rh(I) or Rh(III) complexes occurs.
Neeraja M. Kaimal, Thomas Osterland, Hans‐Joachim Drexler, Torsten Beweries   +3 more
wiley   +1 more source

Fluorinated and B‐Vinylated Tris(pyridyl)borate in Copper(I) Coordination Chemistry

European Journal of Inorganic Chemistry, EarlyView.
Coordinatively flexible tris(pyridyl)borate stabilizes copper coordination complexes, including those with ethylene and carbon monoxide. Fluorinated tris(pyridyl)borate with a vinyl substituent on boron was synthesized and comprehensively characterized, expanding the diversity and functional versatility of the poly(pyridyl)borate ligand family.
Deepika V. Karade, Mukundam Vanga, Xiuxiu Sun, H. V. Rasika Dias   +3 more
wiley   +1 more source

A Personal Perspective on Metalloprotein Structure and the Future of Macromolecular X‐Ray Crystallography

Journal of the Chinese Chemical Society, EarlyView.
While X‐ray crystallography has been the primary method for determining the structures of metalloproteins, cryoEM has taken over this role, illustrated by [4Fe4S]‐cluster containing proteins deposited in the Protein Data Bank. What will be the role for X‐ray crystallography as cryoEM and machine learning methods dominate the initial structural analysis?
Douglas C. Rees
wiley   +1 more source

Bioinorganic Site‐Specific Conjugation of Multi‐Arm Linkers to Create Pharmaceuticals With Targeting and Effector Functions

Journal of the Chinese Chemical Society, EarlyView.
This Account showcases a modular, multi‐arm linker platform that decouples payload loading from antibody conjugation. By leveraging a computationally designed ACPGHA zinc‐binding motif, we demonstrate the construction of homogeneous antibody‐drug conjugates and theranostic antibody‐radionuclide conjugates with high payload loading. The multi‐arm linker
Cédric Grauffel, Tse Wen Chang, Carmay Lim   +2 more
wiley   +1 more source