Results 31 to 40 of about 5,856 (239)

Binuclear Copper‐Dependent Oxidative Enzymes Involved in Fungal Natural Product Modifications

open access: yesJournal of the Chinese Chemical Society, EarlyView.
This article summarizes recent biochemical characterizations of a new enzyme family named by the authors as binuclear copper‐dependent oxidative enzymes (BiNCOs). Found in fungal natural product biosynthesis, BiNCOs catalyze diverse CH functionalization reactions, including C(sp3)H halogenation, C(sp3)H hydroxylation, C(sp3)O macrocyclization, and ...
Chen‐Yu Chiang, Masao Ohashi, Yi Tang
wiley   +1 more source

Creating a Masterpiece. The Road to (and Beyond) Woodward and Hoffmann's 1969 Angewandte Chemie Treatise

open access: yesThe Chemical Record, EarlyView.
This publication describes how R. B. Woodward and Roald Hoffmann crafted their masterpiece publications. Illustrations include Woodward's first draft of the famous “Violations There are none. Nor can violations be expected of so fundamental a principle of maximum bonding.” Original but discarded text shows the stepwise paths toward the W‐H masterpieces.
Jeffrey I. Seeman
wiley   +1 more source

Quantum State‐Resolved Photodissociation Dynamics Study of Transition‐Metal Carbonyl and Nitrosyl

open access: yesThe Chemical Record, EarlyView.
State‐resolved scattering measurements provide experimental visualization of nuclear motions in reacting molecules. Carbonyls and nitrosyls are typical ligands in most of the transition‐metal complexes, which undergo dissociation upon visible and ultraviolet photoexcitation.
Keigo Nagamori   +2 more
wiley   +1 more source

Dimethyl‐, Diethyl‐, and Propylene Carbonates: An Emerging Class of Green Solvents for Organic Synthesis

open access: yesThe Chemical Record, EarlyView.
This review highlights recent advances in the use of organic carbonates, dimethyl carbonate (DMC), diethyl carbonate (DEC), and propylene carbonate (PC), as solvents in organic synthesis. Based on over seventy studies from the past 6 years, it shows their application in different organic reaction types, emphasizing their role in safer and more ...
Gabriela T. Quadros   +5 more
wiley   +1 more source

Retracted: Diagnostic Accuracy of Procalcitonin for Bacterial Infection in Liver Failure: A Meta-Analysis

open access: yesBioinorganic Chemistry and Applications, 2023
Bioinorganic Chemistry and Applications
doaj   +1 more source

Protic Ionic Liquids in Contrast to Aprotic Analogs: Transport Properties and Electrochemical Reactivity

open access: yesThe Chemical Record, EarlyView.
The transport properties and electrochemical reactivity of protic ionic liquids (ILs) are compared with those of aprotic analogs. Protic ILs are characterized by strong cation–anion hydrogen bonding and labile protons, enabling proton conduction and highlighting their potential as fuel cell electrolytes.
Masayoshi Watanabe, Seiji Tsuzuki
wiley   +1 more source

Nanomaterials‐Decorated Biomass‐Derived Carbon for Overall Water Splitting: Interfacial Engineering, Mechanistic Insights, and Device Translation

open access: yesThe Chemical Record, EarlyView.
Biomass‐derived carbon provides a sustainable, porous, and conductive scaffold that stabilizes nanomaterials for bifunctional hydrogen evolution reaction/oxygen evolution reaction catalysis. This review summarizes design strategies (defects, heteroatom doping, heterostructures, single atoms), mechanistic/density functional theory insights, degradation ...
Paricha Jebin   +8 more
wiley   +1 more source

Retracted: Nanoparticles for Oral Cancer Diagnosis and Therapy

open access: yesBioinorganic Chemistry and Applications, 2023
Bioinorganic Chemistry and Applications
doaj   +1 more source

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