Results 61 to 70 of about 5,856 (239)
Bioinorganic Chemistry and Applications
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The unique double monocapped trigonal cupola coordination polyhedra of Te(2) atoms inside the crystal structure of Ca9N4Te3. Green, moisture‐sensitive Ca9N4Te3 was obtained from Ca/Na flux at 1173 K as a by‐product of reddish‐brown Ca6N2Te3 and crystallizes in the trigonal space group R3¯$\overline{3}$ (No. 148, Z = 3).
Guowei Sun, Rainer Niewa
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Bioinorganic Chemistry and Applications
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Synthesis and Thermolysis of Ylidyl‐Substituted Stannylenes
The synthesis of an amino(ylidyl)stannylene is reported. The title compound was characterized via X‐ray diffraction and features a Sn2C2 heterocycle. Thermal treatment of the stannylene leads to the elimination of the amine. The products of the thermolysis are discussed.
Pascal Weisenburger +3 more
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Bioinorganic Chemistry and Applications
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The arrangement of the complex molecules [Ni((4,4′−EtO(CO)2tolaneN3)2(py)2] and pyridine as crystallization solvate in the solid state based on nonbonded intermolecular interactions such CH⋅⋅⋅py, CH⋅⋅⋅O and CH⋅⋅⋅HC contacts is discussed in this work.
Aline Joana Rolina Wohlmuth Alves dos Santos +6 more
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Bioinorganic Chemistry and Applications
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The heterobimetallic amino‐acid dithiocarbamates [M(H2O)n]2[Pt(L)2] (M = Ca, Sr, Ba, Zn, Cd; L = N‐dithioato‐iminodiacetate) are thermally dehydrated to their respective anhydrates M2[Pt(L)2], which further yield metal sulfate or oxide particles decorated with finely distributed metallic platinum upon combustion in air. The thermal decomposition of the
Sebastian Mangelsen +6 more
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Synthesis and Structure Solution of Ba[SeCN]2
The new quasi‐binary selenocyanate Ba[SeCN]2 was synthesized by the reaction of barium hydroxide with ammonium selenocyanate. Its crystal structure was determined from powder X‐ray diffraction (PXRD) data. Additionally, density functional theory (DFT) analysis and Raman spectroscopy were performed.
Alena Shlyaykher +4 more
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Organotitanyl “TiCp” Fragment Capping the Bowl‐Shaped Unit in the Ternary Anion [(Cp)Ti(Sn3Bi3)]2−
A novel ternary anion, [(η5‐Cp)Ti(Sn3Bi3‐κ3)]2− composed of a cyclopentadienyl titanium fragment coordinated by a Sn3Bi3 bowl‐shaped cluster unit, is reproted. Unlike homoatomic nine‐atom clusters of heavier tetrel elements, which retain their identity upon dissolution, intermetalloid clusters are not formed directly from ternary alkali‐metal alloys in
C. E. Fajman +3 more
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