Results 61 to 70 of about 5,856 (239)

Unveiling Ca9N4Te3: A New Motif in Alkaline‐Earth Metal Chalcogenide Nitrides: A Combined Experimental and Computational Study

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
The unique double monocapped trigonal cupola coordination polyhedra of Te(2) atoms inside the crystal structure of Ca9N4Te3. Green, moisture‐sensitive Ca9N4Te3 was obtained from Ca/Na flux at 1173 K as a by‐product of reddish‐brown Ca6N2Te3 and crystallizes in the trigonal space group R3¯$\overline{3}$ (No. 148, Z = 3).
Guowei Sun, Rainer Niewa
wiley   +1 more source

Synthesis and Thermolysis of Ylidyl‐Substituted Stannylenes

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
The synthesis of an amino(ylidyl)stannylene is reported. The title compound was characterized via X‐ray diffraction and features a Sn2C2 heterocycle. Thermal treatment of the stannylene leads to the elimination of the amine. The products of the thermolysis are discussed.
Pascal Weisenburger   +3 more
wiley   +1 more source

A Macrocyclic Bistriazene: Stabilization of the [Ni(Py)2]2+ Complex Cation with 6,15,23,32−Tetraethoxycarbonyl−bis(tolanetriazenediide) Ion as Ligand

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
The arrangement of the complex molecules [Ni((4,4′−EtO(CO)2tolaneN3)2(py)2] and pyridine as crystallization solvate in the solid state based on nonbonded intermolecular interactions such CH⋅⋅⋅py, CH⋅⋅⋅O and CH⋅⋅⋅HC contacts is discussed in this work.
Aline Joana Rolina Wohlmuth Alves dos Santos   +6 more
wiley   +1 more source

Thermal Transformations of Platinum‐Heterobimetallic Iminodiacetate Dithiocarbamates Comprising Group 2 and Group 12 Metal Ions

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
The heterobimetallic amino‐acid dithiocarbamates [M(H2O)n]2[Pt(L)2] (M = Ca, Sr, Ba, Zn, Cd; L = N‐dithioato‐iminodiacetate) are thermally dehydrated to their respective anhydrates M2[Pt(L)2], which further yield metal sulfate or oxide particles decorated with finely distributed metallic platinum upon combustion in air. The thermal decomposition of the
Sebastian Mangelsen   +6 more
wiley   +1 more source

Synthesis and Structure Solution of Ba[SeCN]2

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
The new quasi‐binary selenocyanate Ba[SeCN]2 was synthesized by the reaction of barium hydroxide with ammonium selenocyanate. Its crystal structure was determined from powder X‐ray diffraction (PXRD) data. Additionally, density functional theory (DFT) analysis and Raman spectroscopy were performed.
Alena Shlyaykher   +4 more
wiley   +1 more source

Organotitanyl “TiCp” Fragment Capping the Bowl‐Shaped Unit in the Ternary Anion [(Cp)Ti(Sn3Bi3)]2−

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
A novel ternary anion, [(η5‐Cp)Ti(Sn3Bi3‐κ3)]2− composed of a cyclopentadienyl titanium fragment coordinated by a Sn3Bi3 bowl‐shaped cluster unit, is reproted. Unlike homoatomic nine‐atom clusters of heavier tetrel elements, which retain their identity upon dissolution, intermetalloid clusters are not formed directly from ternary alkali‐metal alloys in
C. E. Fajman   +3 more
wiley   +1 more source

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