Results 71 to 80 of about 5,856 (239)

Reacting the Free Radicals ClO2 and [O3]–: One‐Electron Transfer Instead of Bond Formation

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
In the reaction of ClO2 and KO3 in liquid ammonia, [NH4][ClO2] was formed as identified by X‐ray diffraction. These results clearly indicate that a one‐electron transfer accompanied by oxidation of [O3]− took place instead of the expected radical coupling. They also suggest that the reduction potential of chlorine dioxide exceeds that of ozone.
Arnold Ressel, Jonas R. Schmid, Paul Golz, Patrick Voßnacker, Martin Jansen, Sebastian Riedel   +5 more
wiley   +1 more source

100 Years of Element Zero: Andreas von Antropoff's Neutronium and the Naming of the Neutron

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
Congratulations to the 100th Anniversary of the publication of Andreas von Antropoff's element 0, “–“! This contribution provides a historical account of the concept of element zero and the naming of the neutron. The concept of element zero is 100 years old, having a first documented appearance in a 1926 publication by Andreas von Antropoff, while the ...
Holger Kohlmann
wiley   +1 more source

Retracted: Solanum tuberosum Leaf Extract Templated Synthesis of Co3O4 Nanoparticles for Electrochemical Sensor and Antibacterial Applications

Bioinorganic Chemistry and Applications, 2023
Bioinorganic Chemistry and Applications
doaj   +1 more source

RE 4Al13Pt9—New Representatives in the RE–Al–Pt System with the Ho4Ge9Ir13‐Type Structure (RE = Y, La‐Nd, Sm, Gd‐Dy)

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
The RE4Al13Pt9 series has been extended to RE = Y, La‐Nd, Sm, Gd‐Dy. The compounds have been investigated by X‐ray diffraction and magnetic susceptibility measurements. Of the RE4Al13Pt9 series, the RE = Ce, Pr, and Eu representatives were previously reported. In this work we extend the series to RE = Y, La‐Nd, Sm, Gd‐Dy.
Stefan Engel, Lena Ruck, Jasper A. Baldauf, Oliver Janka   +3 more
wiley   +1 more source

Retracted: Fungal- and Algal-Derived Synthesis of Various Nanoparticles and Their Applications

Bioinorganic Chemistry and Applications, 2023
Bioinorganic Chemistry and Applications
doaj   +1 more source

Crystal Structure and Eu2+ Luminescence of the Lithium Alkaline‐Earth Silicate Fluoride LiBa2SiO4F

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
With Li2BaSiO4F, a new lithium alkaline‐earth silicate fluoride could be synthesized via high‐temperature solid‐state reaction. Crystal structure and luminescence properties upon Eu2+ activation were investigated. A high‐temperature solid‐state synthesis in weld‐shut tantalum ampoules yielded a new alkaline‐earth silicate fluoride, LiBa2SiO4F.
Kilian M. Rießbeck, Hannah Holzer, Markus Seibald, Christiane Stoll, Frauke Philipp, Hubert Huppertz   +5 more
wiley   +1 more source

Ionothermal Synthesis of Cu(Sb2Se3)[AlCl4] and Cu5(Bi2Se3)6[AlCl4]5 : Monolayers of Sb2Se3 and Bi2Se3 Stabilized by Cu[AlCl4]

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
Ionothermal synthesis in Lewis‐acidic ionic liquids (ILs) yields two new low‐dimensional pnictogen–selenide networks cocrystallized with Cu[AlCl4]. Both are narrow‐gap semiconductors that exhibit strong absorption throughout the visible range. Topochemical AlCl3 extraction triggers partial delamination, pointing to a viable route toward 2D derivatives.
Oliver Dreimann, Vitaliy Romaka, Michael Ruck   +2 more
wiley   +1 more source

Retracted: Biosynthesis of Iron Oxide Nanoparticles Using Leaf Extract of Ruellia tuberosa: Mechanical and Dynamic Mechanical Behaviour Kevlar-Based Hybrid Epoxy Composites

Bioinorganic Chemistry and Applications, 2023
Bioinorganic Chemistry and Applications
doaj   +1 more source

In Situ X‐Ray Diffraction Study of a Microwave‐Based Hydrothermal Synthesis of Mayenite Ca12Al14O33

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
Microwave‐assisted hydrothermal synthesis enables rapid transformation of aluminium‐ and calcium‐hydroxide into mayenite with high surface area. Optimised synthesis conditions comprise a microwave step at 80°C for 5 min followed by calcination at 800°C. The reactions during calcination were studied via in situ XRD measurements.
Nils L. Kotschote, Franziska Hupe, Gina‐Lee Pitulle, Stefan G. Ebbinghaus   +3 more
wiley   +1 more source

Synthesis and Crystal Structure of Sb2O2[CO3] with Stereochemically Active Lone Electron Pairs at Elevated Pressures

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
Sb2O2[CO3] was synthesized at 20 GPa in a laser‐heated diamond cell and is an antimony oxocarbonate with stereochemically active lone electron pairs on the antimony atoms. Its crystal structure is characterized by the presence of [CO3]2–‐groups and by interconnected “Sb2O5‐units” which form a Sb–O‐network within the b,c lattice plane.
Dominik Spahr, Lkhamsuren Bayarjargal, Lukas Brüning, Elena Bykova, Maxim Bykov, Victor Milman, Nico Giordano, Björn Winkler   +7 more
wiley   +1 more source