Results 81 to 90 of about 5,856 (239)
Complex Chemistry of a Chiral Terpyridine Ligand Based on (1R)‐(+)‐Camphor
From (1R)‐(+)‐camphor, a chiral terpyridine ligand is accessible in a few steps that coordinates to divalent metal ions of the first and second transition metal row. From structural characterization, the steric repulsion of the two equatorial methyl groups of the tetrahydromethanoquinoline units becomes evident, which causes cyclometalation of the ...
Julia Ehrhard +2 more
wiley +1 more source
Bioinorganic Chemistry and Applications
doaj +1 more source
The reaction of the tetrahedral [Pb4]4− with Mo(CO)4(tmeda) yields two different Mo(CO)3‐functionalized clusters which can both be related to known clusters by the same substitution pattern following the isolobal principle. The crystal structures of [Na([2.2.2]crypt)]2Na2[(η4‐Pb4)Mo(CO)3] · 8.7NH3 and Na6[Pb4{Mo(CO)3}3] · 22NH3 are reported.
Michael Witzmann, Nikolaus Korber
wiley +1 more source
Bioinorganic Chemistry and Applications
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Yb[N(CN)2]2Cl·5H2O: The First Mixed‐Anionic Dicyanamide‐Based Chloride Hydrate
The title compound Yb[N(CN)2]2Cl·5H2O crystallizes in the triclinic space group P 1¯$\overline{1}$ with the lattice parameters as a = 926.57(5) pm, b = 1111.65(6) pm, c = 1252.08(7) pm, α = 97.239(2)°, β = 94.641(2)°, γ = 103.038(2)° for Z = 4. Partial metathesis reactions of ytterbium trichloride hexahydrate (YbCl3·6H2O) with silver(I) dicyanamide (Ag[
Ralf J. C. Locke +2 more
wiley +1 more source
Bioinorganic Chemistry and Applications
doaj +1 more source
The here presented compounds Rb3Ln[AsS4]2 with Ln = Gd–Ho represent an extension of the nonisotypic Rb3Ln[AsS4]2 series (Ln = La–Nd, Sm, Gd–Ho). The crystal structures of all representatives of this series contain one‐dimensional chains separated by Rb+ cations.
Katja Engel, Thomas Schleid
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Pore‐size‐controlled nanoconfinement of rubrene within UiO‐66 and UiO‐67 suppresses aggregation‐caused quenching and restores bright solid‐state emission. Geometric exclusion and energetic destabilization prevent parallel stacking, yielding solution‐like absorption and fluorescence quantum yields up to 25%.
Julia Larcher +6 more
wiley +1 more source

